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Bài 1:
a) 2CuFeS2 + \(\dfrac{13}{2}\)O2 --to--> 2CuO + Fe2O3 + 4SO2
b) \(n_{CuFeS_2}=\dfrac{3,68}{184}=0,02\left(mol\right)\)
\(n_{O_2}=\dfrac{1,68}{22,4}=0,075\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,02}{2}< \dfrac{0,075}{\dfrac{13}{2}}\) => CuFeS2 hết, O2 dư
PTHH: 2CuFeS2 + \(\dfrac{13}{2}\)O2 --to--> 2CuO + Fe2O3 + 4SO2
0,02----->0,065------->0,02---->0,01---->0,04
=> \(\left\{{}\begin{matrix}n_{O_2\left(dư\right)}=0,075-0,065=0,01\left(mol\right)\\n_{SO_2}=0,04\left(mol\right)\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}\%V_{O_2}=\dfrac{0,01}{0,01+0,04}.100\%=20\%\\\%V_{SO_2}=\dfrac{0,04}{0,01+0,04}.100\%=80\%\end{matrix}\right.\)
- \(\left\{{}\begin{matrix}m_{CuO}=0,02.80=1,6\left(g\right)\\m_{Fe_2O_3}=0,01.160=1,6\left(g\right)\end{matrix}\right.\)
=> mrắn = 1,6 + 1,6 = 3,2 (g)
Bài 2:
a)
2CuS + 3O2 --to--> 2CuO + 2SO2
4FeS + 7O2 --to--> 2Fe2O3 + 4SO2
b) Gọi số mol CuS, FeS là a, b (mol)
=> 96a + 88b = 22,8 (1)
\(n_{SO_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
=> a + b = 0,25 (2)
(1)(2) => a = 0,1; b = 0,15
=> \(\left\{{}\begin{matrix}n_{CuO}=0,1\left(mol\right)\\n_{Fe_2O_3}=0,075\left(mol\right)\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}\%m_{CuO}=\dfrac{0,1.80}{0,1.80+0,075.160}.100\%=40\%\\\%m_{Fe_2O_3}=\dfrac{0,075.160}{0,1.80+0,075.160}.100\%=60\%\end{matrix}\right.\)
a, \(2CuFeS_2+\frac{13}{2}O_2\underrightarrow{^{to}}2CuO+Fe_2O_3+4SO_2\)
\(\)b, Câu b mình đổi thành "% khối lượng chất rắn và V khí" nha.
\(n_{O2}=0,075\left(mol\right)\)
\(\Rightarrow n_{SO2}=\frac{3}{65}\left(mol\right)\)
\(\Rightarrow V_{SO2}=1,034\left(l\right)\)
\(n_{CuO}=\frac{3}{130}\left(mol\right)\Rightarrow m_{CuO}=1,85\left(g\right)\)
\(n_{Fe2O3}=\frac{3}{260}\left(mol\right)\Rightarrow m_{Fe2O3}=1,85\left(g\right)\)
\(\Rightarrow\%m_{CuO}=\%m_{Fe2O3}=50\%\)
\(n_P=\dfrac{6.2}{31}=0.2\left(mol\right)\)
\(n_{O_2}=\dfrac{8.96}{22.4}=0.4\left(mol\right)\)
\(4P+5O_2\underrightarrow{^{^{t^0}}}2P_2O_5\)
\(4........5\)
\(0.2.........0.4\)
Lập tỉ lệ : \(\dfrac{0.2}{4}< \dfrac{0.4}{5}\Rightarrow O_2dư\)
\(n_{P_2O_5}=0.2\cdot\dfrac{2}{4}=0.1\left(mol\right)\)
\(m_{P_2O_5}=0.1\cdot142=14.2\left(g\right)\)
\(m_{P_2O_5\left(tt\right)}=14.2\cdot80\%=11.36\left(g\right)\)
a, Theo giả thiết ta có: \(n_P=\dfrac{3,1}{31}=0,1\left(mol\right)\)
\(4P+5O_2--t^o->2P_2O_5\)
Ta có: \(n_{O_2}=\dfrac{5}{4}.n_P=0,125\left(mol\right)\Rightarrow V_{O_2\left(đktc\right)}=0,125.22,4=2,8\left(l\right)\)
b, Theo giả thiết ta có: \(n_{CH_4}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)
\(CH_4+2O_2--t^o->CO_2+2H_2O\)
Ta có: \(n_{O_2}=2.n_{CH_4}=0,1\left(mol\right)\Rightarrow V_{O_2\left(đktc\right)}=2,24\left(l\right)\)
\(n_{CuO}=2a\left(mol\right)\Rightarrow n_{Fe_2O_3}=a\left(mol\right)\)
\(m_X=80\cdot2a+160a=80\left(g\right)\)
\(\Rightarrow a=0.25\left(mol\right)\)
\(CuO+H_2\underrightarrow{^{^{t^0}}}Cu+H_2O\)
\(Fe_2O_3+3H_2\underrightarrow{^{^{t^0}}}2Fe+3H_2O\)
\(n_{H_2}=0.5+0.25\cdot3=1.25\left(mol\right)\)
\(V_{H_2}=1.25\cdot22.4=28\left(l\right)\)
\(m_{cr}=0.5\cdot64+0.5\cdot56=60\left(g\right)\)
nFe = 33,6 : 56 = 0,6 (mol)
pthh : 3Fe + 2O2 -t--> Fe3O4
0,6--> 0,4------->0,2 (mol)
=> vO2 = 0,4.22,4 = 8,96 (mol)
=> mFe3O4 = 0,2.232 = 46,4 (g)
pthh : 2KClO3 -t--> 2KClO3 + 3O2
0,267<-----------------------0,4(mol)
mKClO3= 0,267 .122,5 = 32,67 (g)
a, \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
b, Ta có: \(n_{Fe}=\dfrac{50,4}{56}=0,9\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{2}{3}n_{Fe}=0,6\left(mol\right)\Rightarrow V_{O_2}=0,6.22,4=13,44\left(l\right)\)
c, \(n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=0,3\left(mol\right)\Rightarrow m_{Fe_3O_4}=0,3.232=69,6\left(g\right)\)
d, \(2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
Theo PT: \(n_{KClO_3}=\dfrac{2}{3}n_{O_2}=0,4\left(mol\right)\Rightarrow m_{KClO_3}=0,4.122,5=49\left(g\right)\)
\(n_{Fe}=\dfrac{m}{M}=\dfrac{50,4}{56}=0,9\left(mol\right)\)
\(a.PTHH:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
3 2 1
0,9 0,6 0,3
\(b.V_{O_2}=n.24,79=0,6.24,79=14,874\left(l\right)\)
\(c.m_{Fe_3O_4}=n.M=0,3.\left(56.3+16.4\right)=69,6\left(g\right)\)
\(d.V_{O_2}=14,874\left(l\right)\\ \Rightarrow n_{O_2}=\dfrac{V}{24,79}=\dfrac{14,874}{24,79}=0,6\left(mol\right)\\ PTHH:2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
2 2 3
0,6 0,6 0,9
\(m_{KClO_3}=n.M=0,6.\left(39+35,5+16.3\right)=55,5\left(g\right).\)
\(n_P=\dfrac{7,44}{31}=0,24mol\)
\(4P+5O_2\underrightarrow{t^o}2P_2O_5\)
0,24 0,3 0,12
\(V_{O_2}=0,3\cdot22,4=6,72l\)
\(2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
0,2 0,3
\(m_{KClO_3}=0,2\cdot122,5=24,5g\)
nFe = 16.8/56 = 0.3 (mol)
3Fe + 2O2 -to-> Fe3O4
0.3......0.2...........0.1
VO2 = 0.2*22.4 = 4.48 (l)
mFe3O4 = 0.1*232 = 23.2 (g)
a) \(4CuFeS_2+13O_2\xrightarrow[]{t^o}4CuO+2Fe_2O_3+8SO_2\)
(mol) 0,02...........0,065........0,02........0,01.........0,04
b) \(n_{CuFeS_2}=\dfrac{3,68}{184}=0,02\left(mol\right)\)
\(n_{O_2}=\dfrac{1,68}{22,4}=0,075\left(mol\right)\)
Tỉ lệ: \(\dfrac{0,02}{4}< \dfrac{0,075}{13}\)
⇒ \(O_2\) dư. Đưa số mol \(CuFeS_2\) vào pt để tính
\(n_{O_2dư}=0,075-0,065=0,01\left(mol\right)\)
\(V_{O_2\left(đktc\right)}=0,01.22,4=0,224\left(l\right)\)
\(V_{SO_2\left(đktc\right)}=0,08.22,4=1,792\left(l\right)\)
\(m_{rắn}=0,02.80+0,01.160=3,2\left(g\right)\)
câu b đã thành phần số mol còn đktc là sao