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PTHH: \(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)
Ta có: \(\left\{{}\begin{matrix}n_{NaOH}=\dfrac{200\cdot4\%}{40}=0,2\left(mol\right)\\n_{H_2SO_4}=\dfrac{150\cdot9,8\%}{98}=0,15\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,2}{2}< \dfrac{0,15}{1}\) \(\Rightarrow\) Axit còn dư, tính theo Bazơ
\(\Rightarrow\left\{{}\begin{matrix}n_{Na_2SO_4}=0,1\left(mol\right)\\n_{H_2SO_4\left(dư\right)}=0,05\left(mol\right)\Rightarrow m_{H_2SO_4\left(dư\right)}=0,05\cdot98=4,9\left(g\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}C\%_{Na_2SO_4}=\dfrac{0,1\cdot142}{200+150}\cdot100\%\approx4,06\%\\C\%_{H_2SO_4\left(dư\right)}=\dfrac{4,9}{200+150}\cdot100\%=1,4\%\end{matrix}\right.\)
Ta có: \(n_{CuO}=\dfrac{16}{80}=0,2mol\)
PTHH: \(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)
Theo PTHH: \(n_{H2}so_4=^nCuO=0,2mol\)
\(\rightarrow m_{H_2SO_4}=0,2.98=19,6g\)
\(+)^mddH_2SO_4=\dfrac{^mH_2SO_4}{C\%}.100=196g\)
Đến đây thì bn bt lm chx ạ?
\(m_{CH_3COOH}=12\%.100=12\left(g\right)\\ n_{CH_3COOH}=\dfrac{12}{60}=0,2\left(mol\right)\)
PTHH: CH3COOH + NaOH ---> CH3COONa + H2O
0,2--------->0,2------------>0,2
\(m_{NaOH}=0,2.40=8\left(g\right)\\ m_{ddNaOH}=\dfrac{8}{8,4\%}=\dfrac{2000}{21}\left(g\right)\\ m_{ddCH_3COONa}=\dfrac{2000}{21}+100=\dfrac{4100}{21}\left(g\right)\\ m_{CH_3COONa}=0,2.82=16,4\left(g\right)\\ C\%_{CH_3COONa}=\dfrac{16,4}{\dfrac{4100}{21}}.100\%=8,4\%\)
`=>` Gợi ý:
`CH3COOH + NaHCO3 => CH3COONa + CO2 + H2O`
`mCH3COOH = 100x12/100 = 12` (g)
`==> nCH3COOH = m/M = 12/60 = 0.2` (mol)
Theo pt: `=> nNaHCO3 = 0.2` (mol)
`==> mNaHCO3 = n.M = 0.2x84 =16.8` (g)
`==> mdd NaHCO3 = 16.8x100/8.4 = 200` (g)
Ta có: `nCH3COONa = 0.2` (mol)
Ta có: \(n_{Fe_2O_3}=\dfrac{9,6}{160}=0,06\left(mol\right)\)
a. PTHH: Fe2O3 + 3H2SO4 ---> Fe2(SO4)3 + 3H2O (1)
Theo PT(1): \(n_{H_2SO_4}=3.n_{Fe_2O_3}=3.0,06=0,18\left(mol\right)\)
=> \(m_{H_2SO_4}=0,18.98=17,64\left(g\right)\)
Ta có: \(C_{\%_{H_2SO_4}}=\dfrac{17,64}{m_{dd_{H_2SO_4}}}.100\%=9,8\%\)
=> \(m_{dd_{H_2SO_4}}=180\left(g\right)\)
b. Ta có: \(m_{dd_{Fe_2\left(SO_4\right)_3}}=9,6+180=189,6\left(g\right)\)
Theo PT(1): \(n_{Fe_2\left(SO_4\right)_3}=n_{Fe_2O_3}=0,06\left(mol\right)\)
=> \(m_{Fe_2\left(SO_4\right)_3}=0,06.400=24\left(g\right)\)
=> \(C_{\%_{Fe_2\left(SO_4\right)_3}}=\dfrac{24}{189,6}.100\%=12,66\%\)
c. PTHH: Fe2(SO4)3 + 3BaCl2 ---> 3BaSO4↓ + 2FeCl3 (2)
Theo PT(2): \(n_{BaSO_4}=3.n_{Fe_2\left(SO_4\right)_3}=3.0,06=0,18\left(mol\right)\)
=> \(m_{BaSO_4}=0,18.233=41,94\left(g\right)\)
Theo PT(2): \(n_{BaCl_2}=n_{BaSO_4}=0,18\left(mol\right)\)
=> \(m_{BaCl_2}=0,18.208=37,44\left(g\right)\)
Ta có: \(C_{\%_{BaCl_2}}=\dfrac{37,44}{m_{dd_{BaCl_2}}}.100\%=10,4\%\)
=> \(m_{dd_{BaCl_2}}=360\left(g\right)\)
a)
$CuO + H_2SO_4 \to CuSO_4 + H_2O$
$n_{H_2SO_4} = n_{CuO} = \dfrac{1,6}{80} = 0,02(mol)$
$C\%_{H_2SO_4} = \dfrac{0,02.98}{100}.100\% = 1,96\%$
b)
$2NaOH + H_2SO_4 \to Na_2SO_4 + 2H_2O$
$n_{NaOH} = 2n_{H_2SO_4} = 0,04(mol)$
$m_{NaOH} = 0,04.40 = 1,6(gam)$
c)
$Cu + 2H_2SO_4 \to CuSO_4 + SO_2 + 2H_2O$
Cu dư nên $n_{SO_2} = \dfrac{1}{2}n_{H_2SO_4} = 0,05(mol)$
$V_{SO_2} = 0,05.22,4 = 1,12(lít)$
a) Na2CO3 + 2CH3COOH --> 2CH3COONa + CO2 + H2O
b) \(n_{CH_3COOH}=\dfrac{25.6\%}{60}=0,025\left(mol\right)\)
PTHH: Na2CO3 + 2CH3COOH --> 2CH3COONa + CO2 + H2O
0,0125<-----0,025------------>0,025------>0,0125
=> \(m_{Na_2CO_3}=0,0125.106=1,325\left(g\right)\)
c) \(m_{dd.sau.pư}=1,325+25-0,0125.44=25,775\left(g\right)\)
\(C\%_{dd.CH_3COONa}=\dfrac{0,025.82}{25,775}.100\%=7,95\%\)
\(n_{Fe_2O_3}=\dfrac{8}{160}=0,05\left(mol\right)\)
PTHH: Fe2O3 + 3H2SO4 --> Fe2(SO4)3 + 3H2O
______0,05------>0,15--------->0,05
=> mH2SO4 = 0,15.98 = 14,7(g)
=> \(C\%\left(H_2SO_4\right)=\dfrac{14,7}{100}.100\%=14,7\%\)
\(C\%\left(Fe_2\left(SO_4\right)_3\right)=\dfrac{0,05.400}{8+100}.100\%=18,52\%\)
PTHH: Fe2(SO4)3 + 6NaOH --> 2Fe(OH)3\(\downarrow\) + 3Na2SO4
________0,05----------------------->0,1
=> mFe(OH)3 = 0,1.107=10,7(g)
PTHH: \(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)
Ta có: \(n_{Na_2SO_4}=n_{H_2SO_4}=\dfrac{1}{2}n_{NaOH}=\dfrac{1}{2}\cdot\dfrac{10}{40}=0,125\left(mol\right)\) \(\Rightarrow\left\{{}\begin{matrix}m_{ddH_2SO_4}=\dfrac{0,125\cdot98}{10\%}=122,5\left(g\right)\\m_{Na_2SO_4}=0,125\cdot142=17,75\left(g\right)\end{matrix}\right.\)
\(\Rightarrow C\%_{Na_2SO_4}=\dfrac{17,75}{10+122,5}\cdot100\%\approx13,4\%\)
BTKL: mD + mNaHCO3 = mCO2 + mE
mD + 179,88 = 44.0,2 + 492 => mD = 320,92
BTKL: mMg + mddHCl = mH2 + mD
=> 24 . 0,4 + mddHCl = 2 . 0,4 + 320,92 => mddHCl = 312,12
=> C%HCl = 11,69%
PTHH: 2NaOH + H2SO4 ➝ Na2SO4 + 2H2O
TPT: 2 mol 1 mol 1 mol
TĐB: 0,2 mol 0,1 mol 0,1 mol
mNaOH = \(\dfrac{m_{dd}}{100\%}.C\% = \dfrac{200}{100\%}.4\% = 8 (g)\)
nNaOH = \(\dfrac{m}{M} = \dfrac{8}{40} = 0,2 (mol)\)
\(m_{H_2SO_4} = n.M = 0,1.98 = 9,8 (g)\)
\(m_{ddH_2SO_4} = \dfrac{m_{ct}.100\%}{C\%} = \dfrac{9,8.100\%}{9,8\%} = 100(g)\)
\(m_{ddNa_2SO_4} = m_{ddNaOH} + m_{ddH_2SO_4} = 200 + 100 = 300(g)\)
\(m_{Na_2SO_4} = n.M = 0,1.142 =14,2(g)\)
\(C\%_{Na_2SO_4} = \dfrac{m_{ct}}{m_{dd}}.100\% = \dfrac{14,2}{300}.100\% \) ≈ 4,7%