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a) PTHH: \(BaCO_3+2HCl\rightarrow BaCl_2+H_2O+CO_2\uparrow\)
Ta có: \(\left\{{}\begin{matrix}n_{BaCO_3}=\dfrac{68,95}{197}=0,35\left(mol\right)\\n_{HCl}=0,25\cdot3,2=0,8\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,35}{1}< \dfrac{0,8}{2}\) \(\Rightarrow\) Axit còn dư
\(\Rightarrow n_{HCl\left(dư\right)}=0,8-0,35\cdot2=0,1\left(mol\right)\) \(\Rightarrow m_{HCl\left(dư\right)}=0,1\cdot36,5=3,65\left(g\right)\)
b+c) Theo PTHH: \(\left\{{}\begin{matrix}n_{CO_2}=n_{BaCl_2}=0,35\left(mol\right)\\n_{HCl\left(dư\right)}=0,1\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{CO_2}=0,35\cdot22,4=7,84\left(l\right)\\C_{M_{BaCl_2}}=\dfrac{0,35}{0,25}=1,4\left(M\right)\\C_{M_{HCl\left(dư\right)}}=\dfrac{0,1}{0,25}=0,4\left(M\right)\end{matrix}\right.\)
Bài 1:
PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)
Ta có: \(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,4\left(mol\right)\\n_{H_2}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{ddHCl}=\dfrac{0,4\cdot36,5}{14,6\%}=100\left(g\right)\\V_{H_2}=0,2\cdot22,4=4,48\left(l\right)\end{matrix}\right.\)
Bài 2:
PTHH: \(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\)
Ta có: \(\left\{{}\begin{matrix}n_{KOH}=\dfrac{100\cdot11,2\%}{56}=0,2\left(mol\right)\\n_{H_2SO_4}=\dfrac{150\cdot9,8\%}{98}=0,15\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,2}{2}< \dfrac{0,15}{1}\) \(\Rightarrow\) H2SO4 còn dư, KOH p/ứ hết
\(\Rightarrow\left\{{}\begin{matrix}n_{K_2SO_4}=0,1\left(mol\right)\\n_{H_2SO_4\left(dư\right)}=0,05\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{K_2SO_4}=0,1\cdot174=17,4\left(g\right)\\m_{H_2SO_4\left(dư\right)}=0,05\cdot98=4,9\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd}=m_{ddKOH}+m_{ddH_2SO_4}=250\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{K_2SO_4}=\dfrac{17,4}{250}\cdot100\%=6,96\%\\C\%_{H_2SO_4\left(dư\right)}=\dfrac{4,9}{250}\cdot100\%=1,96\%\end{matrix}\right.\)
nFe = 5.6/56 = 0.1 (mol)
nHCl = 0.2*2 = 0.4 (mol)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
LTL : 0.1/1 < 0.4/2 => HCl dư
mHCl dư = ( 0.4 - 0.2 ) * 36.5 = 7.3 (g)
VH2 = 0.2*22.4 = 4.48 (l)
CM FeCl2 = 0.1/0.2 = 0.5(M)
CM HCl dư = 0.2 / 0.2 = 1(M)
\(a,Na_2O+H_2O\rightarrow2NaOH\\ BaO+H_2O\rightarrow Ba\left(OH\right)_2\\ Đặt:n_{Na_2O}=a\left(mol\right);n_{BaO}=b\left(mol\right)\left(a,b>0\right)\\ \Rightarrow\left\{{}\begin{matrix}62a+153b=27,7\\40.2a+171b=33,1\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,2\\b=0,1\end{matrix}\right.\\ b,\%m_{BaO}=\dfrac{0,1.153}{27,7}.100\approx55,235\%\\ \%m_{Na_2O}\approx100\%-55,235\%\approx44,765\%\\ c,m_{ddbazo}=27,7+200=227,7\left(g\right)\\ C\%_{ddNaOH}=\dfrac{0,2.2.40}{227,7}.100\approx7,027\%\\ C\%_{ddBa\left(OH\right)_2}=\dfrac{0,1.171}{227,7}.100\approx7,51\%\)
a, \(n_{Fe}=\frac{5,6}{56}=0,1\left(mol\right)\)
\(Fe+2HCl->FeCl_2+H_2\left(1\right)\)
theo (1) \(n_{H_2}=n_{Fe}=0,1\left(mol\right)\)
=> \(V_{H_2}=0,1.22,4=2,24\left(l\right)\)
b, \(Fe+2HCl->FeCl_2+H_2\) (1)
theo (1) \(n_{HCl}=2n_{Fe}=0,2\left(mol\right)\)
200 ml =0,2 l
nồng độ mol của dung dịch HCl là
\(\frac{0,2}{0,2}=1M\)
Câu 1 :
\(n_{Mg}=\dfrac{8.4}{24}=0.35\left(mol\right)\)
\(Mg+2HCl\rightarrow MgCl_2+H_2\)
\(0.35.......0.7.........0.35..........0.35\)
\(C\%_{HCl}=\dfrac{0.7\cdot36.5}{146}\cdot100\%=17.5\%\)
\(m_{\text{dung dịch sau phản ứng}}=8.4+146-0.35\cdot2=153.7\left(g\right)\)
\(C\%_{MgCl_2}=\dfrac{0.35\cdot95}{153.7}\cdot100\%=21.6\%\)
Câu 2 :
\(n_{CaCO_3}=\dfrac{10}{100}=0.1\left(mol\right)\)
\(n_{HCl}=\dfrac{114.1\cdot8\%}{36.5}=0.25\left(mol\right)\)
\(CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O\)
\(1................2\)
\(0.1.............0.25\)
\(LTL:\dfrac{0.1}{1}< \dfrac{0.25}{2}\Rightarrow HCldư\)
\(m_{\text{dung dịch sau phản ứng}}=10+114.1-0.1\cdot44=119.7\left(g\right)\)
\(C\%_{HCl\left(dư\right)}=\dfrac{\left(0.25-0.2\right)\cdot36.5}{119.7}\cdot100\%=1.52\%\)
\(C\%_{CaCl_2}=\dfrac{0.2\cdot111}{119.7}\cdot100\%=18.54\%\)
Bài 1:
Ta có: \(n_{HCl}=0,2.0,5=0,1\left(mol\right)\)
BTNT H, có: \(n_{HCl}=2n_{H_2O}\Rightarrow n_{H_2O}=0,05\left(mol\right)\)
Theo ĐL BTKL, có: m oxit + mHCl = mmuối + mH2O
⇒ mmuối = 2,8 + 0,1.36,5 - 0,05.18 = 5,55 (g)
Bài 2:
\(m_{KOH}=200.5,6\%=11,2\left(g\right)\Rightarrow n_{KOH}=\dfrac{11,2}{56}=0,2\left(mol\right)\)
PT: \(2KOH+CuCl_2\rightarrow2KCl+Cu\left(OH\right)_2\)
Theo PT: \(n_{Cu\left(OH\right)_2}=\dfrac{1}{2}n_{KOH}=0,1\left(mol\right)\)
\(\Rightarrow m_{Cu\left(OH\right)_2}=0,1.98=9,8\left(g\right)\)
Ta có: \(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)
PT: \(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)
a, \(n_{H_2SO_4}=3n_{Fe_2O_3}=0,3\left(mol\right)\)
\(\Rightarrow m_{H_2SO_4}=0,3.98=29,4\left(g\right)\)
\(\Rightarrow m_{ddH_2SO_4}=\dfrac{29,4}{9,8\%}=300\left(g\right)\)
b, \(n_{Fe_2\left(SO_4\right)_3}=n_{Fe_2O_3}=0,1\left(mol\right)\)
Ta có: m dd sau pư = 16 + 300 = 316 (g)
\(\Rightarrow C\%_{Fe_2\left(SO_4\right)_3}=\dfrac{0,1.400}{316}.100\%\approx12,66\%\)
1. \(BaCO_3+H_2SO_4\rightarrow BaSO_4\downarrow+H_2O+CO_2\)
\(n_{BaCO_3}=\dfrac{15,76}{197}=0,08\left(mol\right)\)
\(m_{H_2SO_4}=490.0,098=48,02\left(g\right)\)
\(\Rightarrow n_{H_2SO_4}=\dfrac{48,02}{98}=0,49\left(mol\right)\)
=> Sau pư, BaCO3 hết, H2SO4 dư
a) \(m_{BaSO_4}=0,08.233=18,64\left(g\right)\)
b) \(m_{ddsaupư}=15,76+490-18,64=487,12\left(g\right)\)
\(m_{H_2SO_4dư}=98\left(0,49-0,08\right)=40,18\left(g\right)\)
\(\Rightarrow C\%ddH_2SO_4=\dfrac{40,18}{487,12}.100\%\approx8,2\%\)