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\(n_{\left(CH_3COO\right)_2Mg}=\dfrac{0,71}{142}=0,005\left(mol\right)\)
PTHH: 2CH3COOH + Mg ---> (CH3COO)2Mg + H2
0,01<----------------------0,005---------->0,005
\(C_{M\left(CH_3COOH\right)}=\dfrac{0,01}{0,025}=4M\)
PTHH: CH3COOH + NaOH ---> CH3COONa + H2O
0,005--------->0,005
\(V_{ddNaOH}=\dfrac{0,005}{0,75}=\dfrac{1}{150}M\\ V_{H_2}=0,005.22,4=0,0112\left(l\right)\)
a) \(n_{\left(CH_3COO\right)_2Mg}=\dfrac{1,42}{142}=0,01\left(mol\right)\)
PTHH: Mg + 2CH3COOH --> (CH3COO)2Mg + H2
0,02<------------0,01----->0,01
=> \(C_{M\left(dd.CH_3COOH\right)}=\dfrac{0,02}{0,05}=0,4M\)
b) VH2 = 0,01.22,4 = 0,224 (l)
a.\(n_{\left(CH_3COO\right)_2Mg}=\dfrac{14,2}{142}=0,1mol\)
\(2CH_3COOH+Mg\rightarrow\left(CH_3COO\right)_2Mg+H_2\)
0,2 0,1 0,1 ( mol )
\(C_{M_{CH_3COOH}}=\dfrac{0,2}{0,25}=0,8M\)
\(V_{H_2}=0,1.22,4=2,24l\)
b.\(NaOH+CH_3COOH\rightarrow CH_3COONa+H_2O\)
0,2 0,2 ( mol )
\(V_{NaOH}=\dfrac{0,2}{0,5}=0,4l\)
\(n_{\left(CH_3COO\right)_2Mg}=\dfrac{14,2}{142}=0,1\left(mol\right)\)
PTHH: 2CH3COOH + Mg ---> (CH3COO)2Mg + H2
0,2<---------------------------0,1---------->0,1
=> \(\left\{{}\begin{matrix}C_{M\left(CH_3COOH\right)}=\dfrac{0,2}{0,25}=0,8M\\V_{H_2}=0,1.22,4=2,4\left(l\right)\end{matrix}\right.\)
PTHH: CH3COOH + NaOH ---> CH3COONa + H2O
0,2------------->0,2
=> \(V_{ddNaOH}=\dfrac{0,2}{0,5}=0,4\left(l\right)\)
\(n_{\left(CH_3COO\right)_2Mg}=\dfrac{2,84}{142}=0,02\left(mol\right)\)
PTHH :
\(Mg+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Mg+H_2\uparrow\)
0,04 0,02 0,02
\(a,C_M=\dfrac{n}{V}=\dfrac{0,04}{0,1}=0,4M\)
\(b,V_{H_2}=0,02.22,4=0,448\left(l\right)\)
\(c,PTHH:\)
\(CH_3COOH+C_2H_5OH\underrightarrow{t^o,H_2SO_{4\left(đ\right)}}CH_3COOC_2H_5+H_2O\)
0,04 0,04
\(m_{este}=0,04.90\%.88=3,168\left(g\right)\)
a) \(n_{\left(CH_3COO\right)_2Mg}=\dfrac{1,42}{142}=0,01\left(mol\right)\)
PTHH: Mg + 2CH3COOH --> (CH3COO)2Mg + H2
0,02<-----------0,01-------->0,01
=> VH2 = 0,01.22,4 = 0,224 (l)
\(C_{M\left(CH_3COOH\right)}=\dfrac{0,02}{0,2}=0,1M\)
b)
PTHH: CH3COOH + NaOH --> CH3COONa + H2O
0,02------>0,02
=> \(V_{dd.NaOH}=\dfrac{0,02}{0,2}=0,1\left(l\right)=100\left(ml\right)\)
a) \(n_{Fe}=\dfrac{1,12}{56}=0,02\left(mol\right)\)
PTHH: Fe + 2HCl -->FeCl2 + H2
_____0,02->0,04--->0,02--->0,02
=> VH2 = 0,02.22,4 = 0,448(l)
b) mFeCl2 = 0,02.127 = 2,54(g)
c) \(C_{M\left(HCl\right)}=\dfrac{0,04}{0,2}=0,2M\)
Fe + 2HCl → FeCl2 + H2
1 2 1 1
0,02 0,04 0,02 0,02
nFe=\(\dfrac{1,12}{56}\)= 0,02(mol)
a). nH2=\(\dfrac{0,02.1}{1}\)= 0,02(mol)
→VH2= n . 22,4 = 0,02 . 22,4 = 0,448(l)
b). nFeCl2= \(\dfrac{0,02.1}{1}\)= 0,02(mol)
→mFeCl2= n . M = 0,02 . 127 = 2,54(g)
c). 200ml = 0,2l
nHCl= \(\dfrac{0,02.2}{1}\)=0,04(mol)
→CM= \(\dfrac{n}{V}\)= \(\dfrac{0,04}{0,2}\)= 0,2M
a) 2Al + 6HCl --> 2AlCl3 + 3H2
b) \(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\); nHCl = 0,5.2 = 1 (mol)
Xét tỉ lệ: \(\dfrac{0,1}{2}< \dfrac{1}{6}\) => Al hết, HCl dư
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
0,1->0,3---->0,1---->0,15
=> VH2 = 0,15.22,4 = 3,36 (l)
c) \(\left\{{}\begin{matrix}C_{M\left(AlCl_3\right)}=\dfrac{0,1}{0,5}=0,2M\\C_{M\left(HCl.dư\right)}=\dfrac{1-0,3}{0,5}=1,4M\end{matrix}\right.\)
a, \(2CH_3COOH+Ca\rightarrow\left(CH_3COO\right)_2Ca+H_2\)
\(n_{\left(CH_3COO\right)_2Ca}=\dfrac{3,95}{158}=0,025\left(mol\right)\)
Theo PT: \(n_{CH_3COOH}=2n_{\left(CH_3COO\right)_2Ca}=0,05\left(mol\right)\)
\(\Rightarrow C_{M_{CH_3COOH}}=\dfrac{0,05}{0,25}=0,2\left(M\right)\)
b, \(n_{H_2}=n_{\left(CH_3COO\right)_2Ca}=0,025\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,025.22,4=0,56\left(l\right)\)
c, \(CH_3COOH+NaOH\rightarrow CH_3COONa+H_2O\)
\(n_{NaOH}=n_{CH_3COOH}=0,05\left(mol\right)\)
\(\Rightarrow V_{NaOH}=\dfrac{0,05}{0,5}=0,1\left(l\right)=100\left(ml\right)\)
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