Cho 23,2 g hỗn hợp Mg,Fe tác dụng với 200 ml dd HCl thu đc 11,2l khí H2(đktc)
a.Tính khối lượng mỗi kim loại trong hh ban đầu
b.Tính nồng độ % của dd axit đã dùng ,biết DHCl=1,14g/mol
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a, Gọi: \(\left\{{}\begin{matrix}n_{Ca\left(OH\right)_2}=x\left(mol\right)\\n_{KOH}=y\left(mol\right)\end{matrix}\right.\) ⇒ 74x + 56y = 7,62 (1)
PT: \(Ca\left(OH\right)_2+2HCl\rightarrow CaCl_2+2H_2O\)
\(KOH+HCl\rightarrow KCl+H_2O\)
Theo PT: \(n_{HCl}=2n_{Ca\left(OH\right)_2}+n_{KOH}=2x+y=\dfrac{31,025.30\%}{36,5}=0,17\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,05\left(mol\right)\\y=0,07\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Ca\left(OH\right)_2}=0,05.74=3,7\left(g\right)\\m_{KOH}=0,07.56=3,92\left(g\right)\end{matrix}\right.\)
b, \(V_{ddHCl}=\dfrac{31,025}{1,04}\approx29,83\left(ml\right)=0,02983\left(l\right)\)
\(\Rightarrow C_{M_{HCl}}=\dfrac{0,17}{0,02983}\approx5,7\left(M\right)\)
Gọi x, y lần lượt là sô mol của Fe và Mg
Ta có: \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
PTHH:
Fe + H2SO4 ---> FeSO4 + H2 (1)
Mg + H2SO4 ---> MgSO4 + H2 (2)
a. Theo PT(1): \(n_{H_2}=n_{Fe}=x\left(mol\right)\)
Theo PT(2): \(n_{H_2}=n_{Mg}=y\left(mol\right)\)
\(\Rightarrow x+y=0,3\) (*)
Theo đề, ta có: 56x + 24y = 10.4 (**)
Từ (*) và (**), ta có HPT:
\(\left\{{}\begin{matrix}x+y=0,3\\56x+24y=10,4\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\)
\(\Rightarrow m_{Fe}=0,1.56=5,6\left(g\right);m_{Mg}=0,2.24=4,8\left(g\right)\)
b. Ta có: \(n_{hh}=0,1+0,2=0,3\left(mol\right)\)
Theo PT(1,2): \(n_{H_2SO_4}=n_{hh}=0,3\left(mol\right)\)
Đổi 200ml = 0,2 lít
\(\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,3}{0,2}=1,5M\)
a, Ta có: 24nMg + 56nFe = 9,2 (g) (1)
\(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
BT e, có: 2nMg + 2nFe = 2nH2 = 0,5 (2)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{Mg}=0,15\left(mol\right)\\n_{Fe}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Mg}=\dfrac{0,15.24}{9,2}.100\%\approx39,13\%\\\%m_{Fe}\approx60,87\%\end{matrix}\right.\)
b, BTNT H, có: \(n_{HCl}=2n_{H_2}=0,5\left(mol\right)\Rightarrow C_{M_{HCl}}=\dfrac{0,5}{0,2}=2,5\left(M\right)\)
\(n_{H2}=\dfrac{7,84}{22,4}=0,35\left(mol\right)\)
Pt : \(Mg+2HCl\rightarrow MgCl_2+H_2|\)
1 2 1 1
a 0,4 0,2 1a
\(Fe+2HCl\rightarrow FeCl_2+H_2|\)
1 2 1 1
b 0,3 0,15 1b
a) Gọi a là số mol của Mg
b là số mol của Fe
\(m_{Mg}+m_{Fe}=13,2\left(g\right)\)
⇒ \(n_{Mg}.M_{Mg}+n_{Fe}.M_{Fe}=13,2g\)
⇒ 24a + 56b = 13,2g (1)
Theo phương trình : 1a + 1b = 0,35(2)
Từ(1),(2), ta có hệ phương trình :
24a + 56b = 13,2g
1a + 1b = 0,35
⇒ \(\left\{{}\begin{matrix}a=0,2\\b=0,15\end{matrix}\right.\)
\(m_{Mg}=0,2.24=4,8\left(g\right)\)
\(m_{Fe}=0,15.56=8,4\left(g\right)\)
0/0Mg = \(\dfrac{4,8.100}{13,2}=36,36\)0/0
0/0Fe = \(\dfrac{8,4.100}{13,2}=63,64\)0/0
b) \(n_{HCl\left(tổng\right)}=0,4+0,3=0,7\left(mol\right)\)
200ml = 0,2l
\(C_{M_{ddHCl}}=\dfrac{0,7}{0,2}=3,5\left(M\right)\)
c) \(m_{muối.clorua}=\left(0,2.95\right)+\left(0,15.127\right)=38,05\left(g\right)\)
Chúc bạn học tốt
a, PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
Ta có: \(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
Theo PT: \(n_{Fe}=n_{H_2}=0,25\left(mol\right)\)
\(\Rightarrow m_{Fe}=0,25.56=14\left(g\right)\)
mCu = 20,4 - 14 = 6,4 (g)
b, \(\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{14}{20,4}.100\%\approx68,63\%\\\%m_{Cu}\approx31,37\%\end{matrix}\right.\)
c, Theo PT: \(n_{HCl}=2n_{H_2}=0,5\left(mol\right)\)
\(\Rightarrow C\%_{HCl}=\dfrac{0,5.36,5}{200}.100\%=9,125\%\)
\(a.n_{H_2}=\dfrac{2,24}{22,4}=0,1mol\\ Fe+2HCl\rightarrow FeCl_2+H_2\)
0,1 0,2 0,1 0,1
\(m_{Fe}=0,1.56=5,6g\\ m_{FeO}=13,6-5,6=8g\)
\(b.n_{FeO}=\dfrac{8}{72}=\dfrac{1}{9}mol\)
\(FeO+2HCl\rightarrow FeCl_2+H_2O\)
\(\dfrac{1}{9}\) \(\dfrac{2}{9}\) \(\dfrac{1}{9}\)
\(C_{M_{HCl}}=\dfrac{0,2+\dfrac{2}{9}}{0,2}=\dfrac{19}{9}M\)
\(c.m_{FeCl_2}=\left(0,1+\dfrac{1}{9}\right)127=26,81g\)
Gọi \(n_{Fe}=x\left(mol\right)\)\(;n_{Zn}=y\left(mol\right)\)
\(n_{H_2}=\dfrac{6,72}{22,4}=0,3mol\)
Ta có: \(\left\{{}\begin{matrix}56x+65y=18,6\\2x+2y=2n_{H_2}=0,6\end{matrix}\right.\)\(\Rightarrow\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\)
\(\%m_{Fe}=\dfrac{0,1\cdot56}{18,6}\cdot100\%=30,11\%\)
\(\%m_{Zn}=100\%-30,11\%=69,89\%\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
0,1 0,2
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,2 0,4
\(n_{HCl}=0,2+0,4=0,6mol\)
\(C_M=\dfrac{n}{V}=\dfrac{0,6}{0,2}=3M\)
PTHH: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)
a_____3a______________\(\dfrac{3}{2}\)a (mol)
\(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)
b_____2b_____________b (mol)
Ta lập HPT: \(\left\{{}\begin{matrix}27a+24b=7,8\\\dfrac{3}{2}a+b=\dfrac{8,96}{22,4}\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,2\\b=0,1\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,2\cdot27}{7,8}\cdot100\%\approx69,23\%\\\%m_{Mg}=30,77\%\\C_{M_{HCl}}=\dfrac{0,2\cdot3+0,1\cdot2}{0,2}=4\left(M\right)\end{matrix}\right.\)
a, \(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(FeO+2HCl\rightarrow FeCl_2+H_2O\)
Ta có: \(n_{H_2}=\dfrac{0,896}{22,4}=0,04\left(mol\right)\)
Theo PT: \(n_{Fe}=n_{H_2}=0,04\left(mol\right)\)
\(\Rightarrow\%m_{FeO}=\dfrac{5,84-0,04.56}{5,84}.100\%\approx61,64\%\)
b, Ta có: \(n_{FeO}=\dfrac{5,84-0,04.56}{72}=0,05\left(mol\right)\)
Theo PT: \(n_{HCl}=2n_{Fe}+2n_{FeO}=0,18\left(mol\right)\)
\(\Rightarrow V_{ddHCl}=\dfrac{0,18}{1}=0,18\left(l\right)=180\left(ml\right)\)
c, Theo PT: \(n_{FeCl_2}=n_{Fe}+n_{FeO}=0,09\left(mol\right)\)
Có: m dd HCl = 180.1,15 = 207 (g)
⇒ m dd sau pư = 5,84 + 207 - 0,04.2 = 212,76 (g)
\(\Rightarrow C\%_{FeCl_2}=\dfrac{0,09.127}{212,76}.100\%\approx5,37\%\)
\(Mg+2HCl\rightarrow MgCl_2+H_2\)
x 2x x x
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
y 2y y y
\(\left\{{}\begin{matrix}x+y=0,5\\24x+56y=23,2\end{matrix}\right.\)
\(\Leftrightarrow x=0,15;y=0,35\)
\(a,m_{Mg}=0,15.24=3,6\left(g\right)\)
\(m_{Fe}=19,6\left(g\right)\)
\(b,m_{HCl}=\left(0,3+0,7\right).36,5=36,5\left(g\right)\)
\(m_{ddHCl}=1,14.200=228\left(g\right)\)
\(C\%=\dfrac{36,5}{228}.100\%=16\%\)
\(a.n_{H_2}=\dfrac{11,2}{22,4}=0,5mol\\ n_{Mg}=a;n_{Fe}=b\\ Mg+2HCl\rightarrow MgCl_2+H_2\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ \Rightarrow\left\{{}\begin{matrix}24a+56b=23,2\\a+b=0,5\end{matrix}\right.\\ \Rightarrow a=0,15;b=0,35mol\\ m_{Mg}=0,15.24=3,6g\\ m_{Fe}=23,2-3,6=19,6g\\ b.m_{HCl}=\left(0,15+0,35\right).2.36,5=36,5g\\ m_{ddHCl}=1,14.200=228g\\ C_{\%HCl}=\dfrac{36,5}{228}\cdot100=16,01\%\)