hoà tan aluminium dư bằng 500 (ml) dung dịch H2SO4 thì thu được 7, 437 (l) khí H2
a) tính nồng độ môl của dung dịch acid
b) tính khối lượng aluminium đã phản ứng
c) tính khối lượng muối sinh ra
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\(n_{H_2}=\dfrac{3,7185}{24,79}=0,15\left(mol\right)\)
PTHH: 2Al + 6HCl ---> 2AlCl3 + 3H2
0,1<---------------0,1<-----0,15
\(\Rightarrow\left\{{}\begin{matrix}a,m_{Al}=0,1.27=2,7\left(g\right)\\b,m_{AlCl_3}=0,1.133,5=13,35\left(g\right)\end{matrix}\right.\)
\(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\\ 2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\\ 0,2........0,3...........0,1...........0,3\left(mol\right)\\ a.C_{MddH_2SO_4}=\dfrac{0,3}{0,3}=1\left(M\right)\\ b.m_{Al_2\left(SO_4\right)_3}=342.0,1=34,2\left(g\right)\\ c.V_{H_2\left(đktc\right)}=0,3.22,4=6,72\left(l\right)\)
PTHH: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
a) \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
\(n_{H_2SO_4}=\dfrac{3}{2}n_{Al}=0,3\left(mol\right)\)
\(\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,3}{0,3}=1M\)
b) \(n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}n_{Al}=0,1\left(mol\right)\)
\(\Rightarrow m_{Al_2\left(SO_4\right)_3}=n.M=0,1.342=34,2\left(g\right)\)
c) \(n_{H_2}=n_{H_2SO_4}=0,3\left(mol\right)\)
\(\Rightarrow V_{H_2}=n.22,4=0,3.22,4=6,72\left(l\right)\)
PT: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
Ta có: \(n_{H_2}=\dfrac{3,7185}{24,79}=0,15\left(mol\right)\)
a, \(n_{Al}=\dfrac{2}{3}n_{H_2}=0,1\left(mol\right)\Rightarrow m_{Al}=0,1.27=2,7\left(g\right)\)
b, \(n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{3}n_{H_2}=0,05\left(mol\right)\)
\(\Rightarrow m_{Al_2\left(SO_4\right)_3}=0,05.342=17,1\left(g\right)\)
c, \(n_{H_2SO_4}=n_{H_2}=0,15\left(mol\right)\)
\(\Rightarrow V_{H_2SO_4}=\dfrac{0,15}{1,5}=0,1\left(l\right)=100\left(ml\right)\)
\(4.a/n_{Al}=\dfrac{5,4}{27}=0,2mol\\ 2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
0,2 0,3 0,1 0,3
\(V_{H_2}=0,3.24,79=7,437l\\ b/C_{\%H_2SO_4}=\dfrac{0,3.98}{150}\cdot100=19,6\%\\ c/m_{Al_2\left(SO_4\right)_3}=0,1.342=34,2g\)
\(5.a/n_{MgO}=\dfrac{4}{40}=0,1mol\\ MgO+2HCl\rightarrow MgCl_2+H_2O\)
0,1 0,2 0,1 0,1
\(C_{\%HCl}=\dfrac{0,2.36,5}{200}\cdot100=3,65\%\\ b/C_{\%MgCl_2}=\dfrac{0,1.95}{200+4}\cdot100=4,66\%\\ c/NaOH+HCl\rightarrow NaCl+H_2O\\ n_{NaOH}=n_{HCl}=0,2mol\\ V_{NaOH}=\dfrac{0,2}{1}=0,2l=200ml\)
\(n_{Al}=\dfrac{2,7}{27}=0,1mol\\ a.2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
0,1 0,15 0,05 0,15
\(b.V_{H_2}=0,15.24,79=3,7185l\\ c.m_{Al_2\left(SO_4\right)_3}=0,05.342=17,1g\\ d.C_{M_{H_2SO_4}}=\dfrac{0,15}{0,4}=0,375M\)
a) 2Al+6HCl→→2AlCl3+3H2
b)
nAl=10,8\27=0,4(mol)
nAlCl3=nAl=0,4(mol)
mAlCl3=0,4.133,5=53,4(g)
c)
nH2=3\2nAl=0,6(mol)
VH2=22,4.0,6=13,44(l)
d) n HCl=0,4.6\2=1,2 mol
=>Cm HCl=1,2\0,1=12M
\(n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\)
a) Pt : \(2Al+6HCl\rightarrow2AlCl_3+3H_2|\)
2 6 2 3
0,4 1,2 0,4 0,6
b) \(n_{H2}=\dfrac{0,4.3}{2}=0,6\left(mol\right)\)
\(V_{H2\left(dktc\right)}=0,6.24,79=14,874\left(l\right)\)
c) \(n_{AlCl3}=\dfrac{0,6.2}{3}=0,4\left(mol\right)\)
⇒ \(m_{AlCl3}=0,4.133,5=53,4\left(g\right)\)
d) \(n_{HCl}=\dfrac{0,4.6}{2}=1,2\left(mol\right)\)
100ml = 0,1l
\(C_{M_{ddHCl}}=\dfrac{1,2}{0,1}=12\left(M\right)\)
Chúc bạn học tốt
\(a/2Al+3H_2SO_4\xrightarrow[]{}Al_2\left(SO_4\right)_3+3H_2\)
\(b/30ml=0,03l\\ n_{H_2SO_4}=0,5.0,03=0,0015\left(mol\right)\\ n_{Al}=\dfrac{0,0015.2}{3}=0,001\left(mol\right)\\ m_{Al}=0,001.27=0,027\left(g\right)\\ n_{Al_2\left(SO_4\right)_3}=\dfrac{0,0015}{2}=0,00075\left(mol\right)\\ m_{Al_2\left(SO_4\right)_3}=0,00075.342=0,2565\left(g\right)\)
\(c/n_{H_2}=\dfrac{0,0015.3}{3}=0,0015\left(mol\right)\\ V_{H_2}=0,0015.24,79=0,037185\left(l\right)\)
\(a.2Al+3H_2SO_4->Al_2\left(SO_4\right)_3+3H_2\\ b.n_{Al}=1,5.0,5.0,03=0,0375mol\\ m_{Al}=0,0375.27=1,0125g\\ m_{Al_2\left(SO_4\right)_3}=342\cdot\dfrac{1}{3}\cdot0,03\cdot0,5=1,71g\\V_{H_2}=24,79.0,5.0,03=0,37185L\)
a)
$n_{Al} = 0,3(mol)$
$2Al + 3H_2SO_4 \to Al_2(SO_4)_3 + 3H_2$
Theo PTHH :
$n_{H_2SO_4} = \dfrac{3}{2}n_{Al} = 0,45(mol)$
$m_{dd\ H_2SO_4} = \dfrac{0,45.98}{12,25\%} = 360(gam)$
b)
$n_{H_2} = n_{H_2SO_4} = 0,45(mol)$
$V_{H_2} = 0,45.22,4 = 10,08(lít)$
c)
$n_{Al_2(SO_4)_3} = 0,15(mol)$
$m_{dd\ sau\ pư} = 8,1 + 360 - 0,45.2 = 367,2(gam)$
$C\%_{Al_2(SO_4)_3} = \dfrac{0,15.342}{367,2}.100\% = 14\%$