cho 150ml dung dịch h2so4 tác dụng hết với 200g dung dịch naoh8% tính cm của h2so4
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\(n_{NaOH}=1.0,5=0,5(mol)\\ 2NaOH+H_2SO_4\to Na_2SO_4+2H_2O\\ \Rightarrow n_{H_2SO_4}=0,25(mol)\\ \Rightarrow m_{dd_{H_2SO_4}}=\dfrac{0,25.98}{9,8\%}=250(g)\)
\(H_2SO_4+2NaOH->Na_2SO_4+2H_2O\\ H_2SO_4+Na_2CO_3->Na_2SO_4+CO_2+H_2O\\ n_{Na_2CO_3}=0,1mol=n_{H_2SO_4dư}\\ n_{H_2SO_4}=\dfrac{1}{2}n_{NaOH}=\dfrac{1}{2}.0,15.2=0,15mol\\ C_{M\left(H_2SO_4\right)}=\dfrac{0,15+0,1}{0,25}=1\left(M\right)\\ m_{Na_2SO_4}=142\left(0,15+0,1\right)=35,5g\)
\(n_{K2O}=\dfrac{23,5}{94}=0,25\left(mol\right)\)
Pt : \(K_2O+H_2O\rightarrow2KOH|\)
1 1 2
0,25 0,5
a) \(n_{KOH}=\dfrac{0,25.2}{1}=0,5\left(mol\right)\)
500ml = 0,5l
\(C_{M_{ddKOH}}=\dfrac{0,5}{0,5}=1\left(M\right)\)
b) Pt : \(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O|\)
2 1 1 2
0,5 0,25
\(n_{H2SO4}=\dfrac{0,5.1}{2}=0,25\left(mol\right)\)
⇒ \(m_{H2SO4}=0,25.98=24,5\left(g\right)\)
\(C_{ddH2SO4}=\dfrac{24,5.100}{200}=12,25\)0/0
Chúc bạn học tốt
\(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\\a, 2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\\ n_{H_2}=n_{H_2SO_4}=\dfrac{3}{2}.0,2=0,3\left(mol\right)\\ b,V_{H_2\left(đktc\right)}=0,3.22,4=6,72\left(l\right)\\ c,n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}.0,2=0,1\left(mol\right)\\ m_{Al_2\left(SO_4\right)_3}=0,1.342=34,2\left(g\right)\\ d,C\%_{ddH_2SO_4}=\dfrac{0,3.98}{200}.100\%=14,7\%\\ e,m_{ddmuoi}=5,4+200-0,3.2=204,8\left(g\right)\\ C\%_{ddAl_2\left(SO_4\right)_3}=\dfrac{34,2}{204,8}.100\%\approx16,699\%\)
\(a)2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\\ b)n_{Al}=\dfrac{5,4}{27}=0,2mol\\ 2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
\(0,2-\rightarrow0,3--\rightarrow0,1--\rightarrow0,3\)
\(m_{H_2}=0,3.2=0,6g\\ c)m_{Al_2\left(SO_4\right)_3}=0,1.342=34,2g\\ d)C_{\%H_2SO_4}=\dfrac{0,3.98}{200}\cdot100=14,7\%\\ e)C_{\%Al_2\left(SO_4\right)_3}=\dfrac{34,2}{5,4+200-0,6}\cdot100=16,7\%\)
a) \(n_{NaOH}=0,2.1=0,2\left(mol\right);n_{H_2SO_4}=0,15.2=0,3\left(mol\right)\)
PTHH: 2NaOH + H2SO4 → Na2SO4 + 2H2O
Mol: 0,2 0,1
Ta có: \(\dfrac{0,2}{2}< \dfrac{0,3}{1}\) ⇒ NaOH hết, H2SO4 dư
\(m_{Na_2SO_4}=0,1.142=14,2\left(g\right)\)
b) Vdd sau pứ = 0,2 + 0,15 = 0,35 (l)
\(C_{M_{ddNa_2SO_4}}=\dfrac{0,1}{0,35}=\dfrac{2}{7}\approx0,2857M\)
\(C_{M_{ddH_2SO_4dư}}=\dfrac{0,3-0,1}{0,35}=\dfrac{4}{7}\approx0,57M\)
mBaCl2=10.4(g)
nBaCl2=0.05(mol)
mH2SO4=11.76(g)
nH2SO4=0.12(mol)
BaCl2+H2SO4->BaSO4+2HCl
Theo pthh:nH2SO4=nBaCl2
theo bài ra,nH2SO4>nBaCl2
->H2SO4 dư
nH2SO4 dư=0.12-0.05=0.07(mol)
mH2SO4 dư=0.07*98=6.86(g)
nBaSO4=0.05(mol)
mBaSO4=11.65(g)
nHCl=0.05*2=0.1(mol)
mHCl=3.65(g)
mdd sau phản ứng:200+58.8-11.65=247.15(g)
C%(HCl)=3.65:247.15*100=1.48%
C%(H2SO4)=6.86:247.15*100=2.78%
nMgO=0,15(mol); nH2SO4=0,4(mol)
PTHH: MgO + H2SO4 -> MgSO4 + H2O
0,15________0,15__________0,15(mol)
Ta có: 0,15/1 < 0,4/1
=> H2SO4 dư, MgO hết, tính theo nMgO
-> nH2SO4(dư)=0,4-0,15=0,25(mol) => mH2SO4(dư)=24,5(g)
nMgSO4=nMg=0,15(mol) => mMgSO4=120.0,15=18(g)
mddsau=6+200=206(g)
=>C%ddH2SO4(dư)=(24,5/206).100=11,893%
C%ddMgSO4=(18/206).100=8,738%
PTHH: \(Mg+H_2SO_4\rightarrow MgSO_4+H_2\uparrow\)
Ta có: \(\left\{{}\begin{matrix}n_{Mg}=\dfrac{6}{24}=0,25\left(mol\right)\\n_{H_2SO_4}=\dfrac{200\cdot19,6\%}{98}=0,4\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) Axit dư
\(\Rightarrow\left\{{}\begin{matrix}n_{MgSO_4}=n_{H_2}=0,25\left(mol\right)\\n_{H_2SO_4\left(dư\right)}=0,15\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{MgSO_4}=0,25\cdot120=30\left(g\right)\\m_{H_2}=0,25\cdot2=0,5\left(g\right)\\m_{H_2SO_4\left(dư\right)}=0,15\cdot98=14,7\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd}=m_{Mg}+m_{ddH_2SO_4}-m_{H_2}=205,5\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{MgSO_4}=\dfrac{30}{205,5}\cdot100\%\approx14,6\%\\C\%_{H_2SO_4\left(dư\right)}=\dfrac{14,7}{205,5}\cdot100\%\approx7,2\%\end{matrix}\right.\)
\(V_{ddH2SO4\left(5M\right)}=\dfrac{200}{1,29}=155\left(ml\right)\)
V dd H2SO4 nhận được = 0,15 + 0,155 = 0,305 lít
\(n_{H2SO4\left(2M\right)}=0,3\left(mol\right)\)
\(n_{H2SO4\left(5M\right)}=0,775\left(mol\right)\)
=> CM dd H2SO4 nhận được = \(\dfrac{0,3+0,775}{0,305}=3,525M\)
\(n_{NaOH}=\dfrac{200.8}{100}:40=0,4mol\\ 2NaOH+H_2O\rightarrow Na_2SO_4+2H_2O\\ n_{H_2SO_4}=0,4:2=0,2mol\\ C_{M\left(H_2SO_4\right)}=\dfrac{0,2}{0,15}=\dfrac{4}{3}M\)