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\(n_{K2O}=\dfrac{23,5}{94}=0,25\left(mol\right)\)
Pt : \(K_2O+H_2O\rightarrow2KOH|\)
1 1 2
0,25 0,5
a) \(n_{KOH}=\dfrac{0,25.2}{1}=0,5\left(mol\right)\)
500ml = 0,5l
\(C_{M_{ddKOH}}=\dfrac{0,5}{0,5}=1\left(M\right)\)
b) Pt : \(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O|\)
2 1 1 2
0,5 0,25
\(n_{H2SO4}=\dfrac{0,5.1}{2}=0,25\left(mol\right)\)
⇒ \(m_{H2SO4}=0,25.98=24,5\left(g\right)\)
\(C_{ddH2SO4}=\dfrac{24,5.100}{200}=12,25\)0/0
Chúc bạn học tốt
Gọi \(\left\{{}\begin{matrix}C_{M\left(A\right)}=aM\\C_{M\left(B\right)}=bM\end{matrix}\right.\)
Giả sử trộn 50ml dd A với 50ml dd B để thu được 100ml dd C
=> \(\left\{{}\begin{matrix}n_{NaOH}=0,05a\left(mol\right)\\n_{Ba\left(OH\right)_2}=0,05b\left(mol\right)\end{matrix}\right.\)
\(n_{BaSO_4}=\dfrac{9,32}{233}=0,04\left(mol\right)\)
nH2SO4 = 0,035.2 = 0,07 (mol)
PTHH: Ba(OH)2 + H2SO4 --> BaSO4 + 2H2O
0,04<----0,04<-------0,04
2NaOH + H2SO4 --> Na2SO4 + 2H2O
0,06<----0,03
=> \(\left\{{}\begin{matrix}0,05a=0,06\\0,05b=0,04\end{matrix}\right.\)
=> a = 1,2; b = 0,8
20 ml dd A chứa nNaOH = 0,02.1,2 = 0,024 (mol)
\(n_{Al_2O_3}=\dfrac{20,4}{102}=0,2\left(mol\right)\)
PTHH: 2NaOH + Al2O3 --> 2NaAlO2 + H2O
0,024-->0,012
Ba(OH)2 + Al2O3 --> Ba(AlO2)2 + H2O
0,188<---0,188
=> \(V_{dd.B}=\dfrac{0,188}{0,8}=0,235\left(l\right)=235\left(ml\right)\)
a) \(n_{NaOH}=0,2.1=0,2\left(mol\right);n_{H_2SO_4}=0,15.2=0,3\left(mol\right)\)
PTHH: 2NaOH + H2SO4 → Na2SO4 + 2H2O
Mol: 0,2 0,1
Ta có: \(\dfrac{0,2}{2}< \dfrac{0,3}{1}\) ⇒ NaOH hết, H2SO4 dư
\(m_{Na_2SO_4}=0,1.142=14,2\left(g\right)\)
b) Vdd sau pứ = 0,2 + 0,15 = 0,35 (l)
\(C_{M_{ddNa_2SO_4}}=\dfrac{0,1}{0,35}=\dfrac{2}{7}\approx0,2857M\)
\(C_{M_{ddH_2SO_4dư}}=\dfrac{0,3-0,1}{0,35}=\dfrac{4}{7}\approx0,57M\)
\(n_{NaOH}=0,2.1=0,2\left(mol\right)\\ n_{H_2SO_4}=0,3.1,5=0,45\left(mol\right)\)
\(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)
0,2------->0,1--------->0,1
Xét \(\dfrac{0,2}{2}< \dfrac{0,45}{1}\Rightarrow\) \(H_2SO_4\)dư
Trong dung dịch D có:
\(\left\{{}\begin{matrix}n_{H_2SO_4}=0,45-0,1=0,35\left(mol\right)\\n_{Na_2SO_4}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}CM_{H_2SO_4}=\dfrac{0,35}{0,5}=0,7M\\CM_{Na_2SO_4}=\dfrac{0,1}{0,5}=0,2M\end{matrix}\right.\)
b
\(Ca\left(OH\right)_2+H_2SO_4\rightarrow CaSO_4+2H_2O\)
0,35<---------0,35
\(V_{Ca\left(OH\right)_2}=\dfrac{0,35.74}{1,2}=\dfrac{259}{12}\approx21,58\left(ml\right)\\ \Rightarrow V_{dd.Ca\left(OH\right)_2}=\dfrac{\dfrac{259}{12}.100\%}{10\%}=\dfrac{1295}{6}\approx215,83\left(ml\right)\)
1. \(n_{H_2SO_4\left(98\%\right)}=\dfrac{30.1,84.98\%}{98}=0,552\left(mol\right)\)
=>\(V_{H_2SO_4\left(1M\right)}=\dfrac{0,552}{1}=0,552\left(l\right)\)
\(H_2SO_4+2NaOH->Na_2SO_4+2H_2O\\ H_2SO_4+Na_2CO_3->Na_2SO_4+CO_2+H_2O\\ n_{Na_2CO_3}=0,1mol=n_{H_2SO_4dư}\\ n_{H_2SO_4}=\dfrac{1}{2}n_{NaOH}=\dfrac{1}{2}.0,15.2=0,15mol\\ C_{M\left(H_2SO_4\right)}=\dfrac{0,15+0,1}{0,25}=1\left(M\right)\\ m_{Na_2SO_4}=142\left(0,15+0,1\right)=35,5g\)
\(n_{Na_2O}=\dfrac{15,5}{62}=0,25\left(mol\right)\\ PTHH:Na_2O+H_2O\rightarrow2NaOH\\ n_{NaOH}=2.0,25=0,5\left(mol\right)\\ a,C_{MddNaOH}=\dfrac{0,5}{0,5}=1\left(M\right)\\ b,2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\\ n_{H_2SO_4}=n_{Na_2SO_4}=\dfrac{0,5}{2}=0,25\left(mol\right)\\ m_{H_2SO_4}=0,25.98=24,5\left(g\right)\\ m_{ddH_2SO_4}=\dfrac{24,5.100}{20}=122,5\left(g\right)\\ V_{ddH_2SO_4}=\dfrac{122,5}{1,14}\approx107,456\left(ml\right)\\ c,V_{ddsau}=V_{ddNaOH}+V_{ddH_2SO_4}\approx0,5+0,107456=0,607456\left(l\right)\\C_{MddNa_2SO_4}\approx\dfrac{ 0,25}{0,607456}\approx0,411552\left(M\right)\)
\(A.2NaOH+H_2SO_4\rightarrow Na_2SO_4+H_2O\\ n_{NaOH}=0,04.1=0,04mol\\ n_{H_2SO_4}=0,04:2=0,02mol\\ C_{M\left(H_2SO_4\right)}=\dfrac{0,02}{0,05}=0,4M\)
Cho quỳ tím vào dd \(H_2SO_4\) rồi nhỏ từ từ dd \(NaOH\) vào. Đến khi thấy quỳ tím từ màu đỏ trở về màu tím thì đó là thời điểm \(H_2SO_4\) được trung hoà hoàn toàn.
a)\(n_{K_2O}=\dfrac{23,5}{94}=0,25mol\)
\(K_2O+H_2O\rightarrow2KOH\)
0,25 0,25 0,5
\(C_M=\dfrac{0,5}{0,5}=1M\)
b)Để trung hòa: \(n_{H^+}=n_{OH^-}=0,5\)
\(\Rightarrow n_{H_2SO_4}=\dfrac{1}{2}n_{H^+}=0,25mol\)
\(m_{H_2SO_4}=0,25\cdot98=24,5g\)
\(\Rightarrow m_{ddHCl}=\dfrac{24,5\cdot100\%}{60\%}=\dfrac{245}{6}g\)
Thể tích dung dịch:
\(V=\dfrac{m}{D}=\dfrac{\dfrac{245}{6}}{1,5}\approx27,22ml\)
\(n_{K_2O}=\dfrac{23,5}{94}=0,25\left(mol\right)\\ K_2O+H_2O\rightarrow2KOH\\ n_{KOH}=2.0,25=0,5\left(mol\right)\\ a,C_{M\text{dd}A}=C_{M\text{dd}KOH}=\dfrac{0,5}{0,5}=1\left(M\right)\\ b,2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\\ n_{H_2SO_4}=\dfrac{0,5}{2}=0,25\left(mol\right)\\ m_{H_2SO_4}=0,25.98=24,5\left(g\right)\\ m_{\text{dd}H_2SO_4}=\dfrac{24,5.100}{60}=\dfrac{245}{6}\left(g\right)\\ V_{\text{dd}H_2SO_4}=\dfrac{\dfrac{245}{6}}{1,5}=\dfrac{245}{9}\left(ml\right)\approx27,222\left(ml\right)\)
\(V_{ddH2SO4\left(5M\right)}=\dfrac{200}{1,29}=155\left(ml\right)\)
V dd H2SO4 nhận được = 0,15 + 0,155 = 0,305 lít
\(n_{H2SO4\left(2M\right)}=0,3\left(mol\right)\)
\(n_{H2SO4\left(5M\right)}=0,775\left(mol\right)\)
=> CM dd H2SO4 nhận được = \(\dfrac{0,3+0,775}{0,305}=3,525M\)