Cho 21,1g hỗn hợp gồm Zn và ZnO tác dụng hết với 200ml dung dịch axit clohidric sau khi phản ứng kết thúc thu được 4,48l khí ở đktc.
a) Viết PTHH
b) Tính kl mỗi chất trong hỗn hơpk
c) Tính nồng độ dung dịch axit đã dùng
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a,
Mg+ 2HCl= MgCl2+ H2
MgO+ 2HCl= MgCl2+ H2O
b,
nH2= 2,24/22,4= 0,1 mol
=> nMg= nMgCl2= 0,5nHCl= 0,1 mol => nHCl= 0,2 mol
=> mMg= 0,1.24= 2,4g
=> mMgO= 2g
c,
nMgO= 2/40= 0,05 mol
=> nMgO= 0,5nHCl= nMgCl2= 0,05 mol
=> nHCl= 0,1 mol
Tổng lượng HCl cần dùng là 0,1+0,2=0,3 mol
=> m dd HCl= 0,3.36,5.100:7,3= 150g
\(n_{H_2}=\dfrac{2,24}{22,4}=0,1mol\)
\(Mg+2HCl\rightarrow MgCl_2+H_2\)
0,1 0,2 0,1 (mol)
\(\Rightarrow m_{Mg}=0,1\cdot24=2,4\left(g\right)\)
\(\Rightarrow m_{MgO}=4,4-2,4=2\left(g\right)\)\(\Rightarrow n_{MgO}=\dfrac{2}{40}=0,05mol\)
\(MgO+2HCl\rightarrow MgCl_2+H_2O\)
0,05 0,1
\(\Rightarrow\Sigma n_{HCl}=0,2+0,1=0,3mol\)\(\Rightarrow m_{HCl}=0,3\cdot36,5=10,95\left(g\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{10,95}{7,3}\cdot100=150\left(g\right)\)
a,\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PTHH: Zn + 2HCl → ZnCl2 + H2
Mol: 0,2 0,4 0,2
\(\Rightarrow\%m_{Zn}=\dfrac{0,2.65.100\%}{21,1}=61,61\%;\%m_{ZnO}=100-61,61=38,39\%\)
b,\(n_{ZnO}=\dfrac{21,1-13}{81}=0,1\left(mol\right)\)
PTHH: ZnO + 2HCl → ZnCl2 + H2O
Mol: 0,1 0,2
\(m_{ddHCl}=\dfrac{\left(0,2+0,4\right).36,5.100\%}{7,3\%}=300\left(g\right)\)
c,
PTHH: Zn + H2SO4 → ZnSO4 + H2
Mol: 0,2 0,2
PTHH: ZnO + H2SO4 → ZnSO4 + H2O
Mol: 0,1 0,1
\(n_{H_2SO_4}=0,2+0,1=0,3\left(mol\right)\Rightarrow V_{ddH_2SO_4}=\dfrac{0,3}{0,5}=0,6\left(l\right)=600\left(ml\right)\)
\(m_{ddH_2SO_4}=600.1,12=672\left(g\right)\)
a) PTHH : \(Zn+H_2SO_4-->ZnSO_4+H_2\uparrow\) (1)
\(ZnO+H_2SO_4-->ZnSO_4+H_2O\) (2)
b) Theo pthh (1) : \(n_{Zn}=n_{H2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
=> \(m_{Zn}=0,1.65=6,5\left(g\right)\)
=> \(m_{ZnO}=22,7-6,5=16,2\left(g\right)\)
c) \(ZnO=\dfrac{16,2}{81}=0,2\left(mol\right)\)
Theo pthh (1) và (2) : \(\Sigma n_{H2SO4}=n_{Zn}+n_{ZnO}=0,1+0,2=0,3\left(mol\right)\)
=> \(C_{M\left(ddH2SO4\right)}=\dfrac{0,3}{0,1}=1,5M\)
a) PTHH : Zn+H2SO4−−>ZnSO4+H2↑Zn+H2SO4−−>ZnSO4+H2↑ (1)
ZnO+H2SO4−−>ZnSO4+H2OZnO+H2SO4−−>ZnSO4+H2O (2)
b) Theo pthh (1) : nZn=nH2=2,2422,4=0,1(mol)nZn=nH2=2,2422,4=0,1(mol)
=> mZn=0,1.65=6,5(g)mZn=0,1.65=6,5(g)
=> mZnO=22,7−6,5=16,2(g)mZnO=22,7−6,5=16,2(g)
c) ZnO=16,281=0,2(mol)ZnO=16,281=0,2(mol)
Theo pthh (1) và (2) : ΣnH2SO4=nZn+nZnO=0,1+0,2=0,3(mol)ΣnH2SO4=nZn+nZnO=0,1+0,2=0,3(mol)
=> CM(ddH2SO4)=0,30,1=1,5M
tích đúng đê
a) PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
\(ZnO+2HCl\rightarrow ZnCl_2+H_2O\)
b) Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)=n_{Zn}\) \(\Rightarrow n_{ZnO}=\dfrac{20-0,1\cdot65}{81}=\dfrac{1}{6}\left(mol\right)\)
\(\Rightarrow n_{ZnCl_2}=n_{Zn}+n_{ZnO}=\dfrac{4}{15}\left(mol\right)\)
Mặt khác: \(m_{H_2}=0,1\cdot2=0,2\left(g\right)\)
\(\Rightarrow m_{dd}=m_{hh}+m_{ddHCl}-m_{H_2}=119,8\left(g\right)\) \(\Rightarrow C\%_{ZnCl_2}=\dfrac{\dfrac{4}{15}\cdot136}{119,8}\cdot100\%\approx30,27\%\)
c) Giả sử khí là SO2
PTHH: \(Zn+H_2SO_{4\left(đ\right)}\xrightarrow[]{t^o}ZnSO_4+SO_2\uparrow+H_2O\)
Theo PTHH: \(n_{SO_2}=n_{Zn}=0,1\left(mol\right)\) \(\Rightarrow V_{SO_2}=0,1\cdot22,4=2,24\left(l\right)\)
$a)PTHH:2Al+6HCl\to 2AlCl_3+3H_2$
$n_{H_2}=\dfrac{5,04}{22,4}=0,225(mol)$
$\Rightarrow n_{Al}=0,15(mol)$
$\Rightarrow \%m_{Al}=\dfrac{0,15.27}{9,45}.100\%\approx 42,86\%$
$\Rightarrow \%m_{Cu}=100-42,86=57,14\%$
$b)$ Theo PT: $n_{HCl}=2n_{H_2}=0,45(mol)$
$\Rightarrow C_{M_{HCl}}=\dfrac{0,45.110\%}{0,5}=0,99M$
\(a.Ca+H_2O\rightarrow Ca\left(OH\right)_2+H_2\\ CaO+H_2O\rightarrow Ca\left(OH\right)_2\\ b.n_{H_2}=n_{Ca}=0,1\left(mol\right)\\ \Rightarrow m_{Ca}=0,1.40=4\left(g\right)\\ \Rightarrow m_{CaO}=9,6-4=5,6\left(g\right)\\ c.n_{CaO}=\dfrac{5,6}{56}=0,1\left(mol\right)\\ \Sigma n_{Ca\left(OH\right)_2}=n_{Ca}+n_{CaO}=0,1+0,1=0,2\left(mol\right)\\ \Rightarrow m_{Ca\left(OH\right)_2}=0,2.74=14,8\left(g\right)\)
\(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\\ pthh:Ca+2H_2O\rightarrow Ca\left(OH\right)_2+H_2\)
0,1 0,1 0,1
\(CaO+H_2O\rightarrow Ca\left(OH\right)_2\)(2)
\(m_{Ca}=0,1.40=4\left(g\right)\\
m_{CaO}=9,6-4=5,6\left(g\right)\)
\(n_{CaO}=\dfrac{5,6}{56}=0,1\left(mol\right)\\
n_{Ca\left(OH\right)_2\left(2\right)}=n_{CaO}=0,1\left(mol\right)\)
\(n_{Ca\left(OH\right)_2}=\left(0,1+0,1\right).74=14,8\left(g\right)\)
a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(ZnO+2HCl\rightarrow ZnCl_2+H_2O\)
b, \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
Theo PT: \(n_{Zn}=n_{H_2}=0,2\left(mol\right)\Rightarrow m_{Zn}=0,2.65=13\left(g\right)\)
\(\Rightarrow m_{ZnO}=21,1-13=8,1\left(g\right)\)
c, \(n_{ZnO}=\dfrac{8,1}{81}=0,1\left(mol\right)\)
Theo PT: \(n_{HCl}=2n_{Zn}+2n_{ZnO}=0,6\left(mol\right)\)
\(\Rightarrow C_{M_{HCl}}=\dfrac{0,6}{0,2}=3\left(M\right)\)
\(n_{H2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
a) Pt : \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,2 0,4 0,2
\(ZnO+2HCl\rightarrow ZnCl_2+H_2O\)
b) \(m_{Zn}=0,2.65=13\left(g\right)\)
→ \(m_{ZnO}=21,1-13=8,1\left(g\right)\)
\(n_{ZnO}=\dfrac{8,1}{81}=0,1\left(mol\right)\)
\(n_{HCl}=2.0,1+2.0,2=0,6\left(mol\right)\)
200ml = 0,2l
c) \(C_{MddH2SO4}=\dfrac{0,6}{0,2}=3\left(M\right)\)
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