Cho 11,2 gam sắt vào 200g dung dịch HCl 9,125%
a. Chất nào còn dư? Dư bao nhiêu gam?
b. Tính nồng độ % các chất thu được trong dung dịch sau phản ứng
Hãy nhập câu hỏi của bạn vào đây, nếu là tài khoản VIP, bạn sẽ được ưu tiên trả lời.
\(n_{Fe}=\dfrac{11,2}{56}=0,2mol\)
\(n_{HCl}=2,5.0,2=0,5mol\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
0,2 < 0,5 ( mol )
0,2 0,4 0,2 0,2 ( mol )
Chất dư là HCl
\(m_{HCl\left(dư\right)}=\left(0,5-0,4\right).36,5=3,65g\)
\(V_{H_2}=0,2.22,4=4,48l\)
\(C_{M_{FeCl_2}}=\dfrac{0,2}{0,2}=1M\)
`n_[Fe]=[11,2]/56=0,2(mol)`
`n_[HCl]=0,3.2=0,6(mol)`
`Fe + 2HCl -> FeCl_2 + H_2 \uparrow`
`0,2` `0,4` `0,2` `0,2` `(mol)`
`a)` Ta có:`[0,2]/1 < [0,6]/2`
`=>HCl` dư
`=>V_[H_2]=0,2.22,4=4,48(l)`
`b)HCl` còn dư sau p/ứ
`=>m_[HCl(dư)]=(0,6-0,4).36,5=7,3(g)`
`c)C_[M_[FeCl_2]]=[0,2]/[0,3]~~0,67(M)`
`C_[M_[HCl(dư)]=[0,6-0,4]/[0,3]~~0,67(M)`
\(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)
\(n_{HCl}=0,3.2=0,6\left(mol\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
0,2 < 0,6 ( mol )
0,2 0,4 0,2 0,2 ( mol )
\(V_{H_2}=0,2.22,4=4,48\left(l\right)\)
Chất dư là HCl
\(m_{HCl\left(dư\right)}=\left(0,6-0,4\right).36,5=7,3\left(g\right)\)
\(C_{M_{FeCl_2}}=\dfrac{0,2}{0,3}=0,66\left(M\right)\)
\(C_{M_{HCl\left(dư\right)}}=\dfrac{0,2}{0,3}=0,66\left(M\right)\)
1.
nAl=\(\dfrac{5,4}{27}\)=0,2 mol
mHCl=\(\dfrac{175.14,6}{100}\)=25,55g
nHCl=\(\dfrac{25,55}{36,5}\)=0,7
2Al + 6HCl → 2AlCl3 + 3H2↑
n trước pứ 0,2 0,7
n pứ 0,2 →0,6 → 0,2 → 0,3 mol
n sau pứ hết dư 0,1
Sau pứ HCl dư.
mHCl (dư)= 36,5.0,1=3,65g
mcác chất sau pư= 5,4 +175 - 0,3.2= 179,8g
mAlCl3= 133,5.0,2=26,7g
C%ddHCl (dư)= \(\dfrac{3,65.100}{179,8}=2,03%\)%
C%ddAlCl3 = \(\dfrac{26,7.100}{179,8}\)= 14,85%
2.
200ml= 0,2l
mMg= \(\dfrac{4,2}{24}=0,175mol\)
Mg + 2HCl → MgCl2 + H2↑
0,175→ 0,35 → 0,175→0,175 mol
a) VH2= 0,175.22,4=3,92l.
b)C%dHCl= \(\dfrac{0,35}{0,2}=1,75\)M
a) PTHH: \(BaCO_3+2HCl\rightarrow BaCl_2+H_2O+CO_2\uparrow\)
Ta có: \(\left\{{}\begin{matrix}n_{BaCO_3}=\dfrac{68,95}{197}=0,35\left(mol\right)\\n_{HCl}=0,25\cdot3,2=0,8\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,35}{1}< \dfrac{0,8}{2}\) \(\Rightarrow\) Axit còn dư
\(\Rightarrow n_{HCl\left(dư\right)}=0,8-0,35\cdot2=0,1\left(mol\right)\) \(\Rightarrow m_{HCl\left(dư\right)}=0,1\cdot36,5=3,65\left(g\right)\)
b+c) Theo PTHH: \(\left\{{}\begin{matrix}n_{CO_2}=n_{BaCl_2}=0,35\left(mol\right)\\n_{HCl\left(dư\right)}=0,1\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{CO_2}=0,35\cdot22,4=7,84\left(l\right)\\C_{M_{BaCl_2}}=\dfrac{0,35}{0,25}=1,4\left(M\right)\\C_{M_{HCl\left(dư\right)}}=\dfrac{0,1}{0,25}=0,4\left(M\right)\end{matrix}\right.\)
\(300(ml)=0,3(l)\\ n_{HCl}=1.0,3=0,3(mol);n_{Fe}=\dfrac{5,6}{56}=0,1(mol)\\ a,PTHH:Fe+2HCl\to FeCl_2+H_2\\ \text{LTL: }\dfrac{n_{Fe}}{1}<\dfrac{n_{HCl}}{2}\Rightarrow HCl\text{ dư}\\ \Rightarrow n_{HCl(dư)}=0,3-0,1.2=0,1(mol)\\ \Rightarrow m_{HCl(dư)}=0,1.36,5=3,65(g)\\ b,n_{FeCl_2}=n_{Fe}=0,1(mol)\\ \Rightarrow \begin{cases} C_{M_{FeCl_2}}=\dfrac{0,1}{0,3}=0,33M\\ C_{M_{HCl(dư)}}=\dfrac{0,1}{0,3}=0,33M \end{cases}\)
Ta có: \(n_{MgO}=\dfrac{4}{40}=0,1\left(mol\right)\)
\(n_{HCl}=4.100:1000=0,4\left(mol\right)\)
a. PTHH: MgO + 2HCl ---> MgCl2 + H2O
Ta thấy: \(\dfrac{0,1}{1}< \dfrac{0,4}{2}\)
Vậy HCl dư.
=> \(n_{dư}=\dfrac{0,1.2}{0,4}=0,5\left(mol\right)\)
=> \(m_{dư}=0,5.36,5=18,2\left(g\right)\)
b. Ta có: \(V_{dd_{MgCl_2}}=V_{HCl}=\dfrac{100}{1000}=0,1\left(lít\right)\)
Theo PT: \(n_{MgCl_2}=n_{MgO}=0,1\left(mol\right)\)
=> \(C_{M_{MgCl_2}}=\dfrac{0,1}{0,1}=1M\)
\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
\(n_{HCl}=0,1.1=0,1\left(mol\right)\)
PTHH :
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
Trc p/u: 0,1 0,1
p/u : 0,05 0,1 0,05 0,05
Sau p/u : 0,05 0 0,05 0,05
-> Fe dư sau p/u
a) \(m_{H_2}=0,05.2=0,1\left(g\right)\)
b) sau p/ư Fe dư
\(m_{Fedư}=0,05.2,8\left(g\right)\)
c) \(m_{FeCl_2}=0,05.\left(56+35,5.2\right)=6,35\left(g\right)\)
PTHH: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\uparrow\)
a) Ta có: \(\left\{{}\begin{matrix}n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\\n_{H_2SO_4}=\dfrac{200\cdot4,9\%}{98}=0,1\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) Cả 2 chất p/ứ hết
b+c) Theo PTHH: \(n_{ZnSO_4}=n_{H_2}=n_{Zn}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}m_{ZnSO_4}=0,1\cdot161=16,1\left(g\right)\\m_{H_2}=0,1\cdot2=0,2\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd}=m_{Zn}+m_{ddH_2SO_4}-m_{H_2}=206,3\left(g\right)\)
\(\Rightarrow C\%_{ZnSO_4}=\dfrac{16,1}{206,3}\cdot100\%\approx7,8\%\)
a, \(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)
\(n_{H_2SO_4}=0,2.2=0,4\left(mol\right)\)
PT: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
Xét tỉ lệ: \(\dfrac{0,2}{1}< \dfrac{0,4}{1}\), ta được H2SO4 dư.
Theo PT: \(n_{H_2}=n_{Fe}=0,2\left(mol\right)\Rightarrow V_{H_2}=0,2.22,4=4,48\left(l\right)\)
b, - H2SO4 dư.
\(n_{H_2SO_4\left(pư\right)}=n_{Fe}=0,2\left(mol\right)\Rightarrow n_{H_2SO_4\left(dư\right)}=0,4-0,2=0,2\left(mol\right)\)
\(\Rightarrow m_{H_2SO_4\left(dư\right)}=0,2.98=19,6\left(g\right)\)
c, \(C_{M_{H_2SO_4\left(dư\right)}}=\dfrac{0,2}{0,2}=1\left(M\right)\)
Theo PT: \(n_{FeSO_4}=n_{Fe}=0,2\left(mol\right)\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,2}{0,2}=1\left(M\right)\)
a. \(nFe=\dfrac{11,2}{56}=0,2\left(mol\right)\)
\(mHCl=\dfrac{200.9,125}{100}=18,25\left(g\right)\)
\(nHCl=\dfrac{18,25}{36,5}=0,5\left(mol\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
1 2 1 1 (mol)
0,2 0,4 0,2 0,2
LTL : \(\dfrac{0,2}{1}< \dfrac{0,5}{2}\)
=> Fe đủ , HCl dư
mHCl ( dư ) = 0,1 . 36,5 = 3,65(g)
b.
mFeCl2 = 0,2 . 127 = 25,4 (g)
mH2 = 0,2 . 2 = 0,4 (g)
mdd = mFe + mdd HCl + mFeCl2 - mH2
mdd = 11,2 + 200 + 25,4 - 0,4 = 236,2(g)
\(C\%_{ddHCl}=\dfrac{3,65.100}{236,2}=1,55\%\)
\(C\%_{FeCl_2}=\dfrac{25,4.100}{236,2}=10,75\%\)
\(C\%_{H_2}=\dfrac{0,4.100}{236,2}=0,17\%\)
C%H2 ??