đốt cháy hoàn toàn 12,4 g Photpho trong bình đựng chứa oxi
a, viết PTHH xảy ra
b, tính Vo2 cần dùng
c, tính khối lượng KClO3 cần thiết để điều chế lượng oxi trên
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PTHH: \(4P+5O_2\underrightarrow{t^o}2P_2O_5\)
Ta có: \(n_P=\dfrac{12,4}{31}=0,4\left(mol\right)\)
\(\Rightarrow n_{O_2}=0,5\left(mol\right)\) \(\Rightarrow V_{O_2}0,5\cdot22,4=11,2\left(l\right)\)
a) \(4P+5O_2\underrightarrow{t\text{°}}P_2O_5\)
b)\(n_P=\dfrac{12,4}{31}=0,4\left(mol\right)\)
Từ PTHH: \(n_{O_2}=\dfrac{5}{4}n_P=\dfrac{5}{4}.0,4=0,5\left(mol\right)\)
\(\Rightarrow\)\(V_{O_2}=0,5.22,4=11,2\left(l\right)\)
a.b.\(n_{Mg}=\dfrac{m}{M}=\dfrac{6,4}{24}=\dfrac{4}{15}mol\)
\(2Mg+O_2\rightarrow\left(t^o\right)2MgO\)
4/15 2/15 ( mol )
\(V_{O_2}=n.22,4=\dfrac{2}{15}.22,4=\dfrac{224}{75}l\)
c.\(2KMnO_4\rightarrow\left(t^o\right)K_2MnO_4+MnO_2+O_2\)
4/15 2/15 ( mol )
\(m_{KMnO_4}=n.M=\dfrac{4}{15}.158=\dfrac{632}{15}g\)
nMg = 6,4 : 24= 0,26(mol)
pthh : 2Mg+O2 -t--> 2MgO
0,26 --> 0,13 (mol )
=> VO2(đktc) = 0,13.22,4=2,912(l)
pthh : 2KMnO4-t--> K2MnO4 + MnO2+ O2
0,26<------------------------------0,13(mol)
=> mKMnO4 = 0,26.158= 41,08(g)
4P+5O2-to>2P2O5
0,04----0,05----0,02
n P=0,04 mol
=>m P2O5=0,02.142=2,84g
=>VO2=0,05.22,4=1,12l
c)
2KMnO4-to>K2MnO4+MnO2+O2
0,1----------------------------------------0,05
H=10%
m KMnO4=0,1.158.110%=17,28g
\(n_P=\dfrac{1,24}{31}=0,04\left(mol\right)\\ pthh:4P+5O_2\underrightarrow{T^O}2P_2O_5\)
0,04 0,05 0,02
=> \(\left\{{}\begin{matrix}m_{P_2O_5}=0,02.142=2,84\left(g\right)\\V_{O_2}=0,05.22,4=1,12\left(l\right)\end{matrix}\right.\)
\(pthh:2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
0,1 0,05
=> \(m_{KMnO_4}=0,1.158=15,8\left(g\right)\)
\(m_{KMnO_4\left(d\text{ùng}\right)}=15,8.110\%=17,38\left(g\right)\)
nP = 18,6/31 = 0,6 (mol)
PTHH: 4P + 5O2 -> (t°) 2P2O5
Mol: 0,6 ---> 0,75 ---> 0,3
VO2 = 0,75 . 22,4 = 16,8 (l)
mP2O5 = 0,3 . 142 = 42,6 (g)
PTHH: 2KClO3 -> (t°, MnO2) 2KCl + 3O2
nKClO3 = 0,75 : 3 . 2 = 0,5 (mol)
mKClO3 = 122,5 . 0,5 = 61,25 (g)
a, PT: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
b, Ta có: \(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
Theo PT: \(n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=\dfrac{1}{30}\left(mol\right)\Rightarrow m_{Fe_3O_4}=\dfrac{1}{30}.232\approx7,733\left(g\right)\)
c, Theo PT: \(n_{O_2}=\dfrac{2}{3}n_{Fe}=\dfrac{1}{15}\left(mol\right)\)
PT: \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
\(n_{KMnO_4\left(LT\right)}=2n_{O_2}=\dfrac{2}{15}\left(mol\right)\)
\(\Rightarrow m_{KMnO_4\left(LT\right)}=\dfrac{2}{15}.158=\dfrac{316}{15}\left(g\right)\)
Mà: H% = 85%
\(\Rightarrow m_{KMnO_4\left(TT\right)}=\dfrac{\dfrac{316}{15}}{85\%}\approx24,78\left(g\right)\)
a, \(4P+5O_2\underrightarrow{t^o}2P_2O_5\)
b, \(n_P=\dfrac{12,4}{31}=0,4\left(mol\right)\)
Theo PT: \(n_{P_2O_5}=\dfrac{1}{2}n_P=0,2\left(mol\right)\Rightarrow m_{P_2O_5}=0,2.142=28,4\left(g\right)\)
c, \(n_{O_2}=\dfrac{5}{4}n_P=0,5\left(mol\right)\)
\(\Rightarrow V_{O_2}=0,5.22,4=11,2\left(l\right)\)
d, \(2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
Theo PT: \(n_{KClO_3}=\dfrac{2}{3}n_{O_2}=\dfrac{1}{3}\left(mol\right)\Rightarrow m_{KClO_3}=\dfrac{1}{3}.122,5=\dfrac{245}{6}\left(g\right)\)
nP = 12,4/31 = 0,4 (mol)
PTHH: 4P + 5O2 -> (t°) 2P2O5
Mol: 0,4 ---> 0,5 ---> 0,2
mP2O5 = 0,2 . 142 = 28,4 (g)
VO2 = 0,5 . 22,4 = 11,2 (l)
PTHH: 2KMnO4 -> (t°) K2MnO4 + MnO2 + O2
nKMnO4 = 0,5 . 2 = 1 (mol)
mKMnO4 = 1 . 158 = 158 (g)
a) \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
PTHH: \(4Al+3O_2\xrightarrow[]{t^o}2Al_2O_3\)
0,2--->0,15
b) \(V_{O_2}=0,15.22,4=3,36\left(l\right)\)
c) PTHH: \(2KMnO_4\xrightarrow[]{t^o}K_2MnO_4+MnO_2+O_2\)
0,3<-----------------------------------0,15
\(\Rightarrow m_{KMnO_4}=0,3.158=47,4\left(g\right)\)
a)\(n_{Fe}=\dfrac{22,4}{56}=0,4mol\)
\(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
0,4 \(\dfrac{4}{15}\) \(\dfrac{2}{15}\)
\(V_{O_2}=\dfrac{4}{15}\cdot22,4=5,973l\)
b)\(2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
\(\dfrac{8}{45}\) \(\dfrac{4}{15}\)
\(m_{KClO_3}=\dfrac{8}{45}\cdot122,5=21,78g\)
\(a) 4P + 5O_2 \xrightarrow{t^o} 2P_2O_5\\ b) n_P = \dfrac{12,4}{31} = 0,4(mol)\\ n_{O_2} = \dfrac{5}{4}n_P = 0,5(mol)\\ V_{O_2} = 0,5.11,2 = 11,2(lít)\\\ c) 2KClO_3 \xrightarrow{t^o} 2KCl + 3O_2\\ n_{KClO_3} = \dfrac{2}{3}n_{O_2} = \dfrac{1}{3}(mol)\\ m_{KClO_3}= \dfrac{1}{3}.122,5 = 40,83(gam)\)
\(n_P=\dfrac{12.4}{31}=0.4\left(mol\right)\)
\(4P+5O_2\underrightarrow{t^0}2P_2O_5\)
\(0.4........0.5\)
\(V_{O_2}=0.5\cdot22.4=11.2\left(l\right)\)
\(2KClO_3\underrightarrow{t^0}2KCl+3O_2\)
\(\dfrac{1}{3}.................0.5\)
\(m_{KClO_3}=\dfrac{1}{3}\cdot122.5=40.83\left(g\right)\)