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2Fe(OH)3 -----to---> Fe2O3 + 3H2O
Mg(OH)2 ----to---> MgO + H2O
Gọi x, y lần lượt là số mol Fe(OH)3 và Mg(OH)2
\(\left\{{}\begin{matrix}107x+58y=16,5\\\dfrac{1}{2}.160x+y.40=12\end{matrix}\right.\)
=> x=0,1 ; y=0,1
\(\%m_{Fe\left(OH\right)_3}=\dfrac{107.0,1}{16,5}.100=64,85\%\)
%Mg(OH)2 = 35,15%
b) \(2Fe\left(OH\right)_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+6H_2O\)
0,1----------------------------------->0,05
\(Mg\left(OH\right)_2+H_2SO_4\rightarrow MgSO_4+2H_2O\)
0,1------------------------------------>0,1
\(m_{ddsaupu}=16,5+200=216,5\left(g\right)\)
\(C\%_{Fe_2\left(SO_4\right)_3}=\dfrac{0,05.400}{216,5}.100=9,24\%\)
\(C\%_{MgSO_4}=\dfrac{0,1.12}{216,5}.100=5,54\%\)
a) 2Al + 6HCl -> 2AlCl3 + 3H2
Al2O3 + 6HCl -> 2AlCl3 + 3H2O
nH2 = 0,15mol => nAl=0,1mol => mAl=2,7g; mAl2O3 = 10,2g => nAl2O3 = 0,1mol
=>%mAl=20,93% =>%mAl2O3 = 79,07%
b) nHCl = 0,1.3+0,1.6=0,9 mol=>mHCl(dd)=100g
mddY=12,9+100-0,15.2=112,6g
mAlCl3=22,5g=>C%=19,98%
a)
$n_{HCl} = \dfrac{3,65}{36,5} = 0,1(mol)$
$CaCO_3 + 2HCl \to CaCl_2 + CO_2 + H_2O$
$n_{CaCO_3} = n_{CaCl_2} = n_{CO_2} = \dfrac{1}{2}n_{HCl} = 0,05(mol)$
$\%m_{CaCO_3} = \dfrac{0,05.100]{31,1}.100\% = 16,08\%$
$\%m_{Ba(NO_3)_2} = 100\% -16,08\% = 83,92\%$
b)
$m_{dd\ sau\ pư} = 31,1 + 96,1 - 0,05.44 = 125(gam)$
$C\%_{Ba(NO_3)_2} = \dfrac{31,1 - 0,05.100}{125}.100\% = 20,88\%$
$C\%_{CaCl_2} = \dfrac{0,05.111}{125}.100\% = 4,44\%$
a) PTHH :\(Mg+2HCl-->MgCl_2+H_2\) (1)
\(Fe+2HCl-->FeCl_2+H_2\) (2)
b) \(n_{HCl}=\dfrac{600\cdot3,65}{100\cdot36,5}=0,6\left(mol\right)\)
Đặt \(\left\{{}\begin{matrix}n_{Mg}=x\left(mol\right)\\n_{Fe}=y\left(mol\right)\end{matrix}\right.\) => 24x + 56y = 13,6 (*)
Theo PTHH (1) và (2) : \(\Sigma n_{HCl}=2n_{Mg}+2n_{Fe}\)
=> \(0,6=2x+2y\) (**)
Từ (*) và (**) suy ra : \(\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\)
=> \(\Rightarrow\left\{{}\begin{matrix}\%m_{Mg}=\dfrac{0,1\cdot24}{0,1\cdot24+0,2\cdot56}\cdot100\%\approx17,65\%\\\%m_{Fe}=100\%-17,65\%=82,35\%\end{matrix}\right.\)
c) Theo PTHH (1) và (2) :
\(n_{MgCl_2}=n_{Mg}=0,1\left(mol\right)\)
\(n_{FeCl_2}=n_{Fe}=0,2\left(mol\right)\)
Theo ĐLBTKL :
\(m_A+m_{ddHCl}=m_{dd.spu}\)
=> 13,6 + 600 = m(dd.spu)
=> m(dd.spu) = 613,6 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{MgCl_2}=\dfrac{0,1\cdot95}{613,6}\cdot100\%\approx1,55\%\\C\%_{FeCl_2}=\dfrac{0,2\cdot127}{613,6}\cdot100\%\approx4,14\%\end{matrix}\right.\)
a.\(Fe+S\rightarrow\left(t^o\right)FeS\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(FeS+2HCl\rightarrow FeCl_2+H_2S\)
b.\(n_{hhk}=\dfrac{4,48}{22,4}=0,2mol\)
\(Fe+S\rightarrow\left(t^o\right)FeS\)
Ta thu được hh khí --> S hết, Fe dư
Gọi \(\left\{{}\begin{matrix}n_{Fe}=x\\n_S=y\end{matrix}\right.\)
\(\rightarrow n_{FeS}=n_{Fe}=n_S\rightarrow n_{Fe\left(dư\right)}=x-y\) ( mol )
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(x-y\) \(x-y\) ( mol )
\(FeS+2HCl\rightarrow FeCl_2+H_2S\)
y y ( mol )
Ta có: \(\left(x-y\right)+y=0,2\)
\(\Leftrightarrow x=0,2\)
Ta có:\(56x+32y=14,4\)
\(\Leftrightarrow56.0,2+32y=14,4\)
\(\Leftrightarrow y=0,1\)
\(\rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{0,2.56}{14,4}.100=77,77\%\\\%m_S=100\%-77,77\%=22,23\%\end{matrix}\right.\)
Đặt \(n_{Ca}=x(mol);n_{Al}=y(mol)\)
\(\Rightarrow 40x+27y=12,05(1)\\ Ca+2HCl\to CaCl_2+H_2\\ 2Al+6HCl\to 2AlCl_3+3H_2\\ \Rightarrow n_{CaCl_2}=x;n_{AlCl_3}=y\\ \Rightarrow 111x+133,5y=42,225(2)\\ (1)(2)\Rightarrow x=0,2(mol);y=0,15(mol)\\ \Rightarrow \%_{Ca}=\dfrac{0,2.40}{12,05}.100\%=66,39\%\\ \Rightarrow \%_{Al}=100\%-66,39\%=33,61\%\\ b,\Sigma n_{HCl}=2x+3y=0,85(mol)\\ \Rightarrow C\%_{HCl}=\dfrac{0,85.36,5}{120}.100\%=25,85\%\)
cảm ơn bạn nhé 3>