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gọi số mol Fe là x
pthh : 3Fe + 2O2 --t---> Fe3O4
x---->\(\dfrac{2}{3}\)x----------> \(\dfrac{x}{3}\)
=> mFe3O4= \(\dfrac{x}{3}\) . 232 = \(\dfrac{232x}{3}\) (G)
=> VO2 = \(\dfrac{2x}{3}\) . 22,4 = \(\dfrac{224x}{15}\) (L)
a. \(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\)
PTHH : 3Fe + 2O2 -to> Fe3O4
0,3 0,2 0,1
b. \(m_{Fe_3O_4}=0,1.232=23,2\left(g\right)\)
c. \(V_{O_2}=0,2.22,4=4,48\left(l\right)\)
a \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
b \(\Rightarrow n_{Fe}=\dfrac{16,8}{56}=0,3mol\) \(\Rightarrow n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=0,1mol\Rightarrow m_{Fe_3O_4}=0,1\cdot232=2,32g\)
c \(\Rightarrow n_{O_2}=\dfrac{2}{3}n_{Fe}=0,2mol\Rightarrow V_{O_2}=0,2\cdot22,4=4,48l\)
\(a,BTKL:m_{Fe}+m_{O_2}=m_{Fe_3O_4}\\ \Rightarrow m_{O_2}=m_{Fe_3O_4}-m_{Fe}=23,2-16,8=6,4(g)\)
nFe = 16.8/56 = 0.3 (mol)
nO2 = 6.72/22.4 = 0.3 (mol)
2Fe + 3O2 -to-> Fe3O4
0.2___0.3________0.1
mFe dư = ( 0.3 - 0.2 ) * 56 = 5.6 (g)
mFe3O4 = 0.1*232 = 23.2 (g)
a)
3Fe+2O2→Fe3O4
b)
nFe=16,8/56=0,3mol
nO2=6,72/22,4=0,3mol
Ta có: 0,3/3<0,3/2=> O2 dư tính theo Fe
nFe3O4=0,3/3=0,1
mFe3O4=0,1.232=23,2g
\(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\\ pthh:3Fe+2O_2\underrightarrow{t^o}Fe_3O_{\text{4}}\)
0,15 0,1 0,05
\(m_{Fe_2O_4}=0,05.232=11,6\left(g\right)\\
V_{O_2}=0,1.11,4=2,24\left(l\right)\\
pthh:2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\uparrow\)
0,2 0,1
\(m_{KMnO_4}=0,2.158=31,6\left(g\right)\)
\(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\\ pthh:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
0,15 0,1 0,05
\(m_{Fe_3O_{\text{ 4}}}=0,05.232=11,6\left(g\right)\\ V_{O_2}=0,1.22,4=2,24\left(l\right)\\ pthh:2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
0,1 0,05
\(m_{KMnO_4}=0,1.158=15,8\left(g\right)\)
a)
\(n_{P_2O_5} = \dfrac{42,6}{142} = 0,3(mol)\\ \)
4P + 5O2 \(\xrightarrow{t^o}\) 2P2O5
0,6.............0,75.................0,3..........(mol)
mP = 0,6.31 = 18,6(gam)
b)
2KClO3 \(\xrightarrow{t^o}\) 2KCl + 3O2
0,5....................................0,75.....(mol)
\(m_{KClO_3} = 0,5.122,5 = 61,25(gam)\)
c)
\(3Fe + 2O_2 \xrightarrow{t^o} Fe_3O_4\)
\(n_{Fe} = \dfrac{16,8}{56} = 0,3(mol)\\ \dfrac{n_{Fe}}{3} = 0,1 < \dfrac{n_{O_2}}{2} = 0,375\)
nên hiệu suất tính theo số mol Fe.
\(n_{Fe\ pư} = 0,3.90\% = 0,27(mol)\\ n_{Fe_3O_4} =\dfrac{1}{3}n_{Fe\ pư} = 0,09(mol)\\ \Rightarrow m_{Fe_3O_4} = 0,09.232 = 20,88(gam)\)
nFe = 16.8/56 = 0.3 mol
3Fe + 2O2 -to-> Fe3O4
0.3___0.2________0.1
VO2 = 4.48 (l)
mFe3O4 = 0.1*232 = 23.2 g