cho 12 gam đồng oxit tác dung với dung dịch h2so4 25%
tính khôi lượng muối tạo thành
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\(n_{CuO}=\dfrac{8}{80}=0,1\left(mol\right)\)
a
PTPỨ:
\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)
0,1------>0,1------>0,1
b
\(m_{muối}=m_{CuSO_4}=0,1.160=16\left(g\right)\)
\(V_{dd.H_2SO_4.pứ}=\dfrac{0,1}{0,5}=0,2\left(l\right)\)
Ta có: \(n_{CuO}=\dfrac{40}{80}=0,5\left(mol\right)\)
PT: \(CuO+2HCl\rightarrow CuCl_2+H_2O\)
____0,5____________0,5 (mol)
a, \(m_{CuCl_2}=0,5.135=67,5\left(g\right)\)
b, Có: m dd sau pư = mCuO + m dd HCl = 40 + 200 = 240 (g)
\(\Rightarrow C\%_{CuCl_2}=\dfrac{67,5}{240}.100\%=28,125\%\)
Bạn tham khảo nhé!
\(a) Mg + H_2SO_4 \to MgSO_4 + H_2\\ n_{Mg} = \dfrac{12}{24} = 0,5 < n_{H_2SO_4}= \dfrac{34,3}{98}=0,35\Rightarrow Mg\ dư\\ b) n_{MgSO_4} = n_{H_2SO_4} = 0,35(mol)\\ m_{MgSO_4} = 0,35.120 = 42(gam)\\ c) n_{H_2} = n_{H_2SO_4} = 0,35(mol)\Rightarrow V_{H_2} = 0,35.22,4 = 7,84(lít)\)
\(n_{Mg}=\dfrac{2,4}{24}=0,1\left(mol\right)\\
pthh:Mg+H_2SO_4\rightarrow MgSO_4+H_2\)
0,1 0,1 0,1
\(m_{MgSO_4}=120.0,1=12\left(g\right)\\
n_{CuO}=\dfrac{48}{80}=0,6\left(mol\right)\\
pthh:CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
\(LTL:\dfrac{0,6}{1}>\dfrac{0,1}{1}\)
=> CuO dư
\(n_{CuO\left(P\text{Ư}\right)}=n_{H_2}=0,1\left(mol\right)\\
m_{CuO\left(d\right)}=\left(0,6-0,1\right).80=40\left(g\right)\)
nMg=2,424=0,1(mol)pthh:Mg+H2SO4→MgSO4+H2nMg=2,424=0,1(mol)pthh:Mg+H2SO4→MgSO4+H2
0,1 0,1 0,1
mMgSO4=120.0,1=12(g)nCuO=4880=0,6(mol)pthh:CuO+H2to→Cu+H2OmMgSO4=120.0,1=12(g)nCuO=4880=0,6(mol)pthh:CuO+H2to→Cu+H2O
Bài 2 :
\(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)
PTHH :
\(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)
0,1 0,3 0,1 0,3
\(m_{Fe_2\left(SO_4\right)_3}=0,1.400=40\left(g\right)\)
\(b,V_{ddH_2SO_4}=\dfrac{0,3}{2}=0,15\left(l\right)\)
\(c,C_{M\left(Fe_2\left(SO_4\right)_3\right)}=\dfrac{0,1}{0,15}=\dfrac{2}{3}\left(M\right)\)
Bài 3 :
\(n_{Mg}=\dfrac{4.8}{24}=0,2\left(mol\right)\)
PTHH :
\(Mg+H_2SO_4\rightarrow MgSO_4+H_2O\)
0,2 0,2 0,2 0,2
\(m_{MgSO_4}=0,2.120=24\left(g\right)\)
\(V_{H_2}=0,2.24,79=4,958\left(l\right)\)
\(c,C_{M\left(H_2SO_4\right)}=\dfrac{0,2}{0,2}=1\left(M\right)\)
\(d,C_{M\left(MgSO_4\right)}=\dfrac{0,2}{0,2}=1\left(M\right)\)
Bài 4 :
\(n_{Al}=\dfrac{8,1}{27}=0,3\left(mol\right)\)
PTHH :
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)
0,3 0,45 0,15 0,45
\(V_{H_2}=0,45.24,79=11,1555\left(l\right)\)
\(m_{H_2SO_4}=0,45.98=44,1\left(g\right)\)
\(C\%_{H_2SO_4}=\dfrac{44,1}{300}.100\%=14,7\%\)
\(m_{Al_2\left(SO_4\right)_3}=0,15.342=51,3\left(g\right)\)
\(m_{dd}=8,1+300-\left(0,45.2\right)=307,2\left(g\right)\)
\(C\%_{Al_2\left(SO_4\right)_3}=\dfrac{51,3}{307,2}.100\%\approx16,7\%\)
Bài 5 :
\(n_{H_2}=\dfrac{4,958}{24,79}=0,2\left(mol\right)\)
PTHH:
\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
0,2 0,4 0,2 0,2
\(m_{Fe}=0,2.56=11,2\left(g\right)\)
\(C_{M\left(HCl\right)}=\dfrac{0,4}{0,2}=2\left(M\right)\)
\(C_{M\left(FeCl_2\right)}=\dfrac{0,2}{0,2}=1\left(M\right)\)
n H2SO4=\(\dfrac{10\%.490}{2+32+16.4}=0,5mol\)
n Al2O3 =\(\dfrac{10,2}{27.2+16.3}=0,1mol\)
\(Al_2O_3+3H_2SO_4->Al_2\left(SO_4\right)_3+3H_2O\)
bđ 0,1............0,5
pư 0,1............0,3..................0,1
spu 0 ................0,2................0,1
=> sau pư gồm H2SO4 dư , Al2(S04)3 và H2O
m H2SO4 dư = \(0,2.\left(2+32+16.3\right)=19,6g\)
m Al2(SO4)3 = \(0,1\left(27.2+32.3+16.4.3\right)=34,2g\)
m dd = \(490+10,2=500,2g\)
% Al2(SO4)3 = \(\dfrac{34,2}{500,2}.100\sim6,84\%\)
% H2SO4 dư = \(\dfrac{19,6}{500,2}.100\sim3,92\%\)
\(4.\\ a/n_{Al}=\dfrac{5,4}{27}=0,2mol\\2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
\(0,2......0,3............0,1...............0,3\)
\(V_{H_2}=0,3.24,79=7,437l\\ b.C_{\%H_2SO_4}=\dfrac{0,3.98}{150}\cdot100=19,6\%\\ c.m_{Al_2\left(SO_4\right)_3}=0,1.342=34,2g\)
\(4.a/n_{Al}=\dfrac{5,4}{27}=0,2mol\\ 2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
0,2 0,3 0,1 0,3
\(V_{H_2}=0,3.24,79=7,437l\\ b/C_{\%H_2SO_4}=\dfrac{0,3.98}{150}\cdot100=19,6\%\\ c/m_{Al_2\left(SO_4\right)_3}=0,1.342=34,2g\)
\(5.a/n_{MgO}=\dfrac{4}{40}=0,1mol\\ MgO+2HCl\rightarrow MgCl_2+H_2O\)
0,1 0,2 0,1 0,1
\(C_{\%HCl}=\dfrac{0,2.36,5}{200}\cdot100=3,65\%\\ b/C_{\%MgCl_2}=\dfrac{0,1.95}{200+4}\cdot100=4,66\%\\ c/NaOH+HCl\rightarrow NaCl+H_2O\\ n_{NaOH}=n_{HCl}=0,2mol\\ V_{NaOH}=\dfrac{0,2}{1}=0,2l=200ml\)
\(n_{H_2SO_4}=0.25\cdot2=0.5\left(mol\right)\)
\(Na_2CO_3+H_2SO_4\rightarrow Na_2SO_4+CO_2+H_2O\)
\(0.5..............0.5...............0.5\)
\(m_{Na_2CO_3}=0.5\cdot106=53\left(g\right)\)
\(C_{M_{Na_2SO_4}}=\dfrac{0.5}{0.25}=2\left(M\right)\)
PTHH: CuO + H2SO4 --> CuSO4 + H2O
Ta có: nCuO = 12801280 = 0,15 mol
mH2SO4 = 78,2 . 25% = 19,55g
=> nH2SO4= 19,55/9819,98 ≈≈ 0,2 mol
Vì 0,151<0,210,151<0,21 => H2SO4 dư
Cứ 1 mol CuO -->1 mol H2SO4 --> 1 mol CuSO4 --> 1 mol H2O
0,15 mol --> 0,15 mol --> 0,15 mol --> 0,15 mol
=> mCuSO4mCuSO4 = 0,15 . 160 = 24 (g)
24 g nha