Cho 2,74g hỗn hợp gồm nhôm hidroxit và đồng (II) hidroxit tác dụng vừa đủ với 100g dung dịch HNO3 4,41%. Tính thành phần phần trăm theo khối lượng của mỗi hidroxit ban đầu.
Hãy nhập câu hỏi của bạn vào đây, nếu là tài khoản VIP, bạn sẽ được ưu tiên trả lời.
\(n_{HCl}=0,2.3,5=0,7\left(mol\right)\\ n_{CuO}=a;n_{Fe_2O_3}=b\\ CuO+2HCl\xrightarrow[]{}\Rightarrow CuCl_2+H_2O\\ Fe_2O_3+6HCl\xrightarrow[]{}2FeCl_3+H_2O\\ \left\{{}\begin{matrix}2a+6b=0,7\\80a+160b=20\end{matrix}\right.\\\Rightarrow a=0,05;b=0,1\\ \%_{CuO}=\dfrac{0,05.80}{20}\cdot100=20\%\\ \%_{Fe_2O_3}=\dfrac{0,1.160}{20}\cdot100=80\%\)
\(n_{NaOH}=0,4.0,5=0,2\left(mol\right)\)
PT: \(CH_3COOH+NaOH\rightarrow CH_3COONa+H_2O\)
Theo PT: \(n_{CH_3COOH}=n_{NaOH}=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{CH_3COOH}=\dfrac{0,2.60}{15,2}.100\%\approx78,95\%\\\%m_{C_2H_5OH}\approx21,05\%\end{matrix}\right.\)
\(\text{Đặt }\left\{{}\begin{matrix}n_{Al}=x\left(mol\right)\\n_{Fe}=y\left(mol\right)\end{matrix}\right.\\ n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\\ a,PTHH:\left\{{}\begin{matrix}2Al+6HCl\rightarrow2AlCl_3+3H_2\\Fe+2HCl\rightarrow FeCl_2+H_2\end{matrix}\right.\\ b,\text{Theo đề ta có HPT: }\left\{{}\begin{matrix}27x+56y=8,3\\\dfrac{3}{2}x+y=0,25\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,1\left(mol\right)\\y=0,1\left(mol\right)\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}\%_{Al}=\dfrac{0,1\cdot27}{8,3}\approx32,53\%\\\%_{Fe}\approx67,47\%\end{matrix}\right.\)
\(c,\left\{{}\begin{matrix}n_{AlCl_3}=0,1\left(mol\right)\\n_{FeCl_2}=0,1\left(mol\right)\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}m_{AlCl_3}=0,1\cdot133,5=13,35\left(g\right)\\m_{FeCl_2}=0,1\cdot127=12,7\left(g\right)\end{matrix}\right.\\ \Rightarrow\sum m_{muối}=13,35+12,7=26,05\left(g\right)\)
\(n_{CH_3COOH}=0,25.1=0,25\left(mol\right)\)
PT: \(2CH_3COOH+Zn\rightarrow\left(CH_3COO\right)_2Zn+H_2\)
Theo PT: \(n_{Zn}=\dfrac{1}{2}n_{CH_3COOH}=0,125\left(mol\right)\)
\(\Rightarrow\%m_{Zn}=\dfrac{0,125.65}{10}.100\%=81,25\%\)
\(\%m_{Cu}=100-81,25=18,75\%\)
a) PTHH: 2Al + 3H2SO4 --> Al2(SO4)3 + 3H2
b) \(n_{H_2}=\dfrac{0,672}{22,4}=0,03\left(mol\right)\)
PTHH: 2Al + 3H2SO4 --> Al2(SO4)3 + 3H2
_____0,02<---0,03<---------------------0,03
=> \(\left\{{}\begin{matrix}\%Al=\dfrac{0,02.27}{2,16}.100\%=25\%\\\%Cu=100\%-25\%=75\%\end{matrix}\right.\)
c) mH2SO4 = 0,03.98 = 2,94 (g)
=> \(C\%\left(H_2SO_4\right)=\dfrac{2,94}{200}.100\%=1,47\%\)
\(Đặt:\left\{{}\begin{matrix}n_{Fe}=x\left(mol\right)\\n_{Cu}=y\left(mol\right)\end{matrix}\right.\\ Fe\rightarrow Fe^{3+}+3e\\ Cu\rightarrow Cu^{2+}+2e\\ 4H^++NO_3^-+3e\rightarrow NO+2H_2O\\ Bảotoàne:3x+2y=0,4.3\\ Tacó:56x+64y=30,4\\ \Rightarrow\left\{{}\begin{matrix}x=0,2\\y=0,3\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}\%m_{Fe}=36,84\%\\\%m_{Cu}=63,16\%\end{matrix}\right.\\ n_{HNO_3}=4n_{NO}=0,4.4=1,6\left(mol\right)\\ \Rightarrow V_{HNO_3}=\dfrac{1,6}{1}=1,6\left(l\right)\\ m_{muối}=m_{Fe\left(NO_3\right)_3}+m_{Cu\left(NO_3\right)_2}=0,2.242+0,3.188=104,8\left(g\right)\)
a) 2Al + 2NaOH + 2H2O --> 2NaAlO2 + 3H2
b) \(\left\{{}\begin{matrix}\%Fe=\dfrac{8}{15}.100\%=53,33\%\\\%Al=\dfrac{15-8}{15}.100\%=46,67\%\end{matrix}\right.\)