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a, \(Na_2O+H_2SO_4\rightarrow Na_2SO_4+H_2O\)
b, Số mol \(H_2SO_4\) là: \(n_1=V.C_M=0,5.0,5=0,25\) (mol)
Số mol \(Na_2SO_4\) là \(n_2=\dfrac{28,4}{142}=0,2\) (mol)
Do \(n_2< n_1\) nên \(H_2SO_4\) còn dư
Suy ra số mol \(Na_2O\) tham gia phản ứng là: \(n=n_2=0,2\) (mol)
Khối lượng là: \(m_{Na_2O}=0,2.62=12,4g\)
nZn=0,4mol
nH2SO4=0,5mol
PTHH: Zn+H2SO4=>ZnSO4+H2
0,4:0,5=> nH2SO4 dư theo nZn
p/ư: 0,4->0,4----->0m4---->0,4
=> VH2=0,4.22,4=8,96ml
b) mZnSO4 tạo thành : m=0,4.161=64,4g
c) ta có mđ H2SO4=1,12.500=560g
mddZnSO4=26+560-0,4.2=585,2g
=> C%(ZnSO4)=64,4:585,2.100=11%
\(a,PTHH:Na_2O+H_2O\rightarrow2NaOH\\ \Rightarrow n_{NaOH}=2n_{Na_2O}=2\cdot\dfrac{37,2}{62}=0,6\cdot2=1,2\left(mol\right)\\ \Rightarrow C_{M_{NaOH}}=\dfrac{1,2}{0,5}=2,4M\\ b,PTHH:2NaOH+H_2SO_4\rightarrow Na_2SO_4+H_2O\\ \Rightarrow n_{H_2SO_4}=\dfrac{1}{2}n_{NaOH}=0,6\left(mol\right)\\ \Rightarrow m_{H_2SO_4}=0,6\cdot98=58,8\left(g\right)\\ \Rightarrow m_{dd_{H_2SO_4}}=\dfrac{58,8\cdot100\%}{20\%}=294\left(g\right)\\ \Rightarrow V_{dd}=\dfrac{294}{1,14}\approx257,9\left(ml\right)\)
a, \(n_{Na_2O}=\dfrac{7,75}{62}=0,125\left(mol\right)\)
PTHH: Na2O + H2O → 2NaOH
Mol: 0,125 0,25
b, \(C_{M_{ddNaOH}}=\dfrac{0,25}{0,25}=1M\)
c,
PTHH: 2NaOH + H2SO4 → Na2SO4 + 2H2O
Mol: 0,25 0,125
\(m_{ddH_2SO_4}=\dfrac{0,125.98.100}{20}=61,25\left(g\right)\)
\(\Rightarrow V_{ddH_2SO_4}=\dfrac{61,25}{1,14}=53,728\left(ml\right)\)
Lần sau bạn đăng tách từng bài ra nhé.
Câu 1:
a, \(Na_2O+H_2O\rightarrow2NaOH\)
\(n_{Na_2O}=\dfrac{15,5}{62}=0,25\left(mol\right)\)
Theo PT: \(n_{NaOH}=2n_{Na_2O}=0,5\left(mol\right)\Rightarrow C_{M_{NaOH}}=\dfrac{0,5}{0,5}=1\left(M\right)\)
b, \(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)
Theo PT: \(n_{H_2SO_4}=\dfrac{1}{2}n_{NaOH}=0,25\left(mol\right)\)
\(\Rightarrow m_{H_2SO_4}=0,25.98=24,5\left(g\right)\)
\(\Rightarrow m_{ddH_2SO_4}=\dfrac{24,5}{20\%}=122,5\left(g\right)\)
\(\Rightarrow V_{ddH_2SO_4}=\dfrac{122,5}{1,14}\approx107,46\left(ml\right)\)
Câu 3: \(n_{CO_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)
PT: \(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_{3\downarrow}+H_2O\)
\(n_{CaCO_3}=n_{CO_2}=0,4\left(mol\right)\Rightarrow m_{CaCO_3}=0,4.100=40\left(g\right)\)
Câu 4: \(n_{CuSO_4}=\dfrac{32}{160}=0,2\left(mol\right)\)
\(n_{BaCl_2}=\dfrac{20,8}{208}=0,1\left(mol\right)\)
PT: \(CuSO_4+BaCl_2\rightarrow BaSO_{4\downarrow}+CuCl_2\)
Xét tỉ lệ: \(\dfrac{0,2}{1}>\dfrac{0,1}{1}\), ta được CuSO4 dư.
Theo PT: \(n_{BaSO_4}=n_{BaCl_2}=0,1\left(mol\right)\Rightarrow m_{BaSO_4}=0,1.233=23,3\left(g\right)\)
nFe = 11.2/56 = 0.2 (mol)
Fe + H2SO4 => FeSO4 + H2
0.2____0.2_______0.2___0.2
mH2SO4 = 0.2*98 = 19.6 (g)
mdd H2SO4 = 19.6*100/10 = 196 (g)
m dd sau phản ứng = 11.2 + 196 - 0.4 = 206.8 (g)
mFeSO4 = 0.2*152 = 30.4 (g)
C% FeSO4 = 30.4/206.8 * 100% = 14.7%
Vdd H2SO4 = mdd H2SO4 / D = 196 / 1.14 = 171.9 (ml)
CM FeSO4 = 0.2 / 0.1719 = 1.16 M
nFe = 11.2/56 = 0.2 (mol)
Fe + H2SO4 => FeSO4 + H2
0.2____0.2_______0.2___0.2
mH2SO4 = 0.2*98 = 19.6 (g)
mdd H2SO4 = 19.6*100/10 = 196 (g)
m dd sau phản ứng = 11.2 + 196 - 0.4 = 206.8 (g)
mFeSO4 = 0.2*152 = 30.4 (g)
C% FeSO4 = 30.4/206.8 * 100% = 14.7%
Vdd H2SO4 = mdd H2SO4 / D = 196 / 1.14 = 171.9 (ml)
CM FeSO4 = 0.2 / 0.1719 = 1.16 M
a) PTHH: \(KOH+HCl\rightarrow KCl+H_2O\)
b) Ta có: \(n_{KCl}=0,15\cdot0,5=0,075\left(mol\right)=n_{KOH}\) \(\Rightarrow m_{KOH}=0,075\cdot56=4,2\left(g\right)\)
c) PTHH: \(KCl+AgNO_3\rightarrow KNO_3+AgCl\downarrow\)
Theo PTHH: \(n_{KCl}=0,075\left(mol\right)=n_{AgNO_3\left(p.ứ\right)}=n_{KNO_3}=n_{AgCl}\)
\(\Rightarrow n_{AgNO_3\left(dư\right)}=0,075\cdot120\%-0,075=0,015\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}m_{AgCl}=0,075\cdot143,5=10,7625\left(g\right)\\C_{M_{KNO_3}}=\dfrac{0,075}{0,5+2}=0,03\left(M\right)\\C_{M_{AgNO_3\left(dư\right)}}=\dfrac{0,015}{2,5}=0,006\left(M\right)\end{matrix}\right.\)
d) Coi như khi cô cạn không bị hao hụt muối
Ta có: \(m_{muối.khan}=m_{KNO_3}+m_{AgNO_3\left(dư\right)}=0,075\cdot101+0,015\cdot170=10,125\left(g\right)\)
