Hãy nhập câu hỏi của bạn vào đây, nếu là tài khoản VIP, bạn sẽ được ưu tiên trả lời.
\(m_{O_2}=44.6-28.6=16\left(g\right)\)
\(n_{O_2}=\dfrac{16}{32}=0.5\left(mol\right)\)
\(n_{HCl}=2n_{H_2O}=4n_{O_2}=0.5\cdot4=2\left(mol\right)\)
\(m_{Muối}=m_{Kl}+m_{Cl-}=28.6+2\cdot35.5=99.6\left(g\right)\)
a) Gọi số mol Mg, Al, Fe trong m gam hỗn hợp là a, b, c (mol)
\(n_{H_2}=\dfrac{7,84}{22,4}=0,35\left(mol\right)\)
PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)
_______a--------------------->a------->a_______(mol)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)
_b-------------------->b------->1,5b___________(mol)
\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
_c------------------>c------->c_______________(mol)
=> \(\left\{{}\begin{matrix}a+1,5b+c=0,35\left(1\right)\\95a+133,5b+127c=35,55\left(2\right)\end{matrix}\right.\)
Mặt khác:
PTHH: \(Mg+Cl_2\underrightarrow{t^o}MgCl_2\)
_______a--------------->a_________(mol)
\(2Al+3Cl_2\underrightarrow{t^o}2AlCl_3\)
_b----------------->b______________(mol)
\(2Fe+3Cl_2\underrightarrow{t^o}2FeCl_3\)
_c------------------>c______________(mol)
=> 95a + 133,5b + 162,5 = 39,1 (3)
(1)(2)(3) => \(\left\{{}\begin{matrix}a=0,1\left(mol\right)\\b=0,1\left(mol\right)\\c=0,1\left(mol\right)\end{matrix}\right.\)
=> m = 24.0,1 + 27.01 + 56.0,1 = 10,7(g)
b) \(\left\{{}\begin{matrix}m_{Mg}=24.0,1=2,4\left(g\right)\\m_{Al}=27.0,1=2,7\left(g\right)\\m_{Fe}=56.0,1=5,6\left(g\right)\end{matrix}\right.\)
\(n_{H_2}=\dfrac{2,464}{22,4}=0,11mol\)
\(\left\{{}\begin{matrix}Al:x\left(mol\right)\\Fe:y\left(mol\right)\end{matrix}\right.\Rightarrow Muối\left\{{}\begin{matrix}Al_2\left(SO_4\right)_3\\FeSO_4\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}BTe:3x+2y=2n_{H_2}=0,22\\\dfrac{x}{2}\cdot342+y\cdot152=14,44\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,04mol\\y=0,05mol\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Al}=0,04\cdot27=1,08g\\m_{Fe}=0,05\cdot56=2,8g\end{matrix}\right.\)
\(Al_2\left(SO_4\right)_3+3BaCl_2\rightarrow2AlCl_3+3BaSO_4\downarrow\)
0,02 0,06
\(FeSO_4+BaCl_2\rightarrow BaSO_4\downarrow+FeCl_2\)
0,05 0,05
\(\Rightarrow\Sigma n_{\downarrow}=0,06+0,05=0,11\Rightarrow m_{BaSO_4}=x=25,63g\)
\(n_{H_2}=\dfrac{11.2}{22.4}=0.5\left(mol\right)\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(Mg+2HCl\rightarrow MgCl_2+H_2\)
\(n_{HCl}=2n_{H_2}=0.5\cdot2=1\left(mol\right)\)
\(BTKL:\)
\(m_X+m_{HCl}=m_M+m_{H_2}\)
\(\Rightarrow m_M=13.4+1\cdot36.5-0.5\cdot2=48.94\left(g\right)\)
