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a) PTHH: \(MgO+2HCl\rightarrow MgCl_2+H_2O\)
b) Ta có: \(n_{MgO}=\dfrac{8}{40}=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{MgCl_2}=0,2\left(mol\right)\\n_{HCl}=0,4\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{MgCl_2}=0,2\cdot95=19\left(g\right)\\C\%_{HCl}=\dfrac{0,4\cdot36,5}{200}\cdot100\%=7,3\%\end{matrix}\right.\)
Mặt khác: \(m_{dd\left(sau.p/ứ\right)}=m_{MgO}+m_{ddHCl}=208\left(g\right)\)
\(\Rightarrow C\%_{MgCl_2}=\dfrac{19}{208}\cdot100\%\approx9,13\%\)
c) PTHH: \(MgCl_2+2NaOH\rightarrow2NaCl+Mg\left(OH\right)_2\downarrow\)
Ta có: \(\left\{{}\begin{matrix}n_{MgCl_2}=0,2\left(mol\right)\\n_{NaOH}=\dfrac{200\cdot4\%}{40}=0,2\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,2}{1}>\dfrac{0,2}{2}\) \(\Rightarrow\) NaOH p/ứ hết, MgCl2 còn dư
\(\Rightarrow\left\{{}\begin{matrix}n_{NaCl}=0,2\left(mol\right)\\n_{Mg\left(OH\right)_2}=0,1\left(mol\right)=n_{MgCl_2\left(dư\right)}\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{NaCl}=0,2\cdot58,5=11,7\left(g\right)\\m_{MgCl_2\left(dư\right)}=9,5\left(g\right)\\m_{Mg\left(OH\right)_2}=0,1\cdot58=5,8\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd\left(sau.p/ứ\right)}=m_{ddA}+m_{ddNaOH}-m_{Mg\left(OH\right)_2}=402,2\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{NaCl}=\dfrac{11,7}{402,2}\cdot100\%\approx2,91\%\\C\%_{MgCl_2\left(dư\right)}=\dfrac{9,5}{402,2}\cdot100\%\approx2,36\%\end{matrix}\right.\)
Theo gt ta có: $n_{MgO}=0,2(mol)$
a, $MgO+2HCl\rightarrow MgCl_2+H_2O$
b, Ta có: $n_{HCl}=0,4(mol)\Rightarrow x=7,3$
Bảo toàn khối lượng ta có: $m_{ddA}=208(g)$
$\Rightarrow \%C_{MgCl_2}=9,13\%$
c, Ta có: $n_{NaOH}=0,2(mol)$
$\Rightarrow n_{Mg(OH)_2}=0,1(mol)$
Bảo toàn khối lượng ta có: $m_{ddB}=208+200-0,1.58=402,2(g)$
$\Rightarrow \%C_{MgCl_2}=2,36\%$
\(n_{Na}=0.02\left(mol\right)\)
\(Na+H_2O\rightarrow NaOH+\dfrac{1}{2}H_2\)
\(0.02....................0.02........0.01\)
\(V_{H_2}=0.01\cdot22.4=0.224\left(l\right)\)
\(m_{NaOH}=0.02\cdot40=0.8\left(g\right)\)
\(C\%_{NaOH}=\dfrac{0.8}{0.46+200-0.01\cdot2}\cdot100\%=0.4\%\)
\(n_{MgCO_3}=\dfrac{16,8}{84}=0,2mol\\ a.MgCO_3+H_2SO_4->MgSO_4+H_2O+CO_2\\ 2NaOH+H_2SO_{\text{4 }}->Na_2SO_4+2H_2O\\ b.n_{H_2SO_4dư}=\dfrac{1}{2}n_{NaOH}=\dfrac{1}{2}.80.0,1:40=0,1mol\\ n_{H_2SO_4\left(MgCO_3\right)}=0,2mol\\ c.C\%=\dfrac{98.0,3}{200}.100\%=14,7\%\\ V=0,2.22,4=4,48L\\ d.m_{ddsau}=200+16,8-44.0,2+80=288g\\ C\%_{Na_2SO_4}=\dfrac{40.0,1}{288}.100\%=1,39\%\\ C\%_{MgSO_4}=\dfrac{120.0,2}{288}.100\%=8,33\%\)
\(n_{MgCO_3}=\dfrac{16,8}{84}=0,2\left(mol\right)\)
\(n_{NaOH}=\dfrac{80}{40}=2\left(mol\right)\)
PTHH :
\(MgCO_3+H_2SO_4\rightarrow MgSO_4+H_2O+CO_2\uparrow\)
0,2 0,2 0,2
\(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)
2 1 1
Vậy có 0,2 mol H2SO4 phản ứng với MgCO3
có 1 mol H2SO4 phản ứng với NaOH
\(m_{H_2SO_4}=1,2.98=117,6\left(g\right)\)
\(c,C\%_{H_2SO_4}=\dfrac{117,6}{200}.100\%=58,8\%\)
\(V_{CO_2}=0,2.22,4=4,48\left(l\right)\)
\(d,m_{Na_2SO_4}=1.142=142\left(g\right)\)
\(m_{ddNaOH}=\dfrac{80.100}{10}=800\left(g\right)\)
\(m_{ddH_2SO_4dư}=1.98:58,8\%\approx166,67\left(g\right)\)
\(m_{ddNa_2SO_4}=800+166,67=966,67\left(g\right)\)
\(C\%_{Na_2SO_4}=\dfrac{142}{966,67}.100\%\approx14,69\%\)
Bài 1: Từ 60g dd NaOH 20%
=> mct1=\(\dfrac{C\%.m_{dd}}{100}=\dfrac{20.60}{100}=12\left(g\right)\)
Từ 40g dd NaOH 15%
=> mct2=\(\dfrac{C\%.m_{dd}}{100}=\dfrac{15.40}{100}=6\left(g\right)\)
=> mct mới= mct1 +mCt2=12+6=18(g)
md d mới= 60+40=100(g)
\(C\%=\dfrac{m_{ct}.100}{m_{dd}}=\dfrac{18.100}{100}=18\left(\%\right)\)
Bài 1: Từ 15g dd NaNO3 25%
=> mct1=\(\dfrac{C\%.m_{dd}}{100}=\dfrac{25.15}{100}=3,75\left(g\right)\)
Từ 5g dd NaNO3 45%
=> mct2=\(\dfrac{C\%.m_{dd}}{100}=\dfrac{45.5}{100}=2,25\left(g\right)\)
=> mct mới= mct1 +mCt2=3,75+2,25=6(g)
md d mới= 15+5=20(g)
\(C\%=\dfrac{m_{ct}.100}{m_{dd}}=\dfrac{6.100}{20}=30\left(\%\right)\)
1/a/ Xem lại đề. Sao có chuyện hòa tan 20g NaOH vào 200g nước lại thu được 300g dung dịch.
b/ Câu b cũng xem lại đề luôn.
2/ \(m_{HCl}=200.5\%=10\left(g\right)\)
\(\Rightarrow n_{HCl}=\dfrac{10}{36,5}=\dfrac{20}{73}\left(mol\right)\)
\(2HCl\left(\dfrac{20}{73}\right)+Zn\left(\dfrac{10}{73}\right)\rightarrow ZnCl_2+H_2\left(\dfrac{10}{73}\right)\)
\(\Rightarrow m_{Zn}=65.\dfrac{10}{73}=\dfrac{650}{73}\left(g\right)\)
\(\Rightarrow V_{H_2}=\dfrac{10}{73}.22,4=\dfrac{224}{73}\left(l\right)\)
VD1:\(m_{dd}=m_{NaOH}+m_{H_2O}=30+200=230\left(g\right)\)
\(C\%=\dfrac{m_{NaOH}}{m_{dd}}.100\%=\dfrac{30}{230}.100\%\approx13,04\%\)
VD2: \(C\%=\dfrac{m_{NaOH}}{m_{dd}}.100\%=\dfrac{60}{300}.100\%=20\%\)