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\(\left\{{}\begin{matrix}n_{NaOH}=0,3.2=0,6\left(mol\right)\\n_{Fe_2\left(SO_4\right)_3}=0,2.0,5=0,1\left(mol\right)\\n_{H_2SO_4}=0,2.0,5=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\left\{{}\begin{matrix}n_{Na^+}=0,6\left(mol\right)\\n_{Fe^{3+}}=0,1.2=0,2\left(mol\right)\\n_{H^+}=0,1.2=0,2\left(mol\right)\end{matrix}\right.\\\left\{{}\begin{matrix}n_{SO_4^{2-}}=0,1.3+0,1=0,4\left(mol\right)\\n_{OH^-}=0,6\left(mol\right)\end{matrix}\right.\end{matrix}\right.\)
PT ion rút gọn:
\(H^++OH^-\rightarrow H_2O\)
0,2-->0,2
\(Fe^{3+}+3OH^-\rightarrow Fe\left(OH\right)_3\downarrow\)
\(\dfrac{2}{15}\)<----0,4--------->\(\dfrac{2}{15}\)
\(\Rightarrow m=\dfrac{2}{15}.107=\dfrac{214}{15}\left(g\right)\)
dd sau phản ứng có: \(\left\{{}\begin{matrix}n_{Na^+}=0,6\left(mol\right)\\n_{Fe^{3+}\left(d\text{ư}\right)}=0,2-\dfrac{2}{15}=\dfrac{1}{15}\left(mol\right)\\n_{SO_4^{2-}}=0,4\left(mol\right)\end{matrix}\right.\)
\(V_{\text{dd}}=0,3+0,2=0,5\left(l\right)\)
\(\Rightarrow\left\{{}\begin{matrix}C_{Na^+}=\dfrac{0,6}{0,5}=1,2M\\C_{Fe^{3+}}=\dfrac{\dfrac{1}{15}}{0,5}=\dfrac{2}{15}M\\C_{SO_4^{2-}}=\dfrac{0,4}{0,5}=0,8M\end{matrix}\right.\)
\(C_{M_{HCl}}=a\left(M\right),C_{M_{H_2SO_4}}=b\left(M\right)\)
\(n_{HCl}=a\left(mol\right),n_{H_2SO_4}=b\left(mol\right)\)
\(n_{NaOH}=0.4\cdot0.5=0.2\left(mol\right)\)
\(NaOH+HCl\rightarrow NaCl+H_2O\)
\(a..........a.........a\)
\(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)
\(2b............b..........b\)
\(n_{NaOH}=a+2b=0.2\left(mol\right)\left(1\right)\)
\(m_{muối}=58.5a+142b=12.95\left(g\right)\left(2\right)\)
\(\left(1\right),\left(2\right):a=0.1,b=0.05\)
\(\left[H^+\right]=0.1+0.05\cdot2=0.2\left(M\right)\)
\(\left[Cl^-\right]=0.1\left(M\right)\)
\(\left[SO_4^{2-}\right]=0.05\left(M\right)\)
\(b.\)
\(pH=-log\left(0.2\right)=0.7\)
Bài 1:
Ta có: \(n_{OH^-}=n_{Na^+}=n_{NaOH}=0,2.0,4=0,08\left(mol\right)\)
\(n_{H^+}=n_{Cl^-}=n_{HCl}=0,4.0,3=0,12\left(mol\right)\)
PT ion: \(OH^-+H^+\rightarrow H_2O\)
_____0,08_____0,12 (mol)
⇒ nOH- (dư) = 0,04 (mol)
\(\Rightarrow\left\{{}\begin{matrix}\left[Na^+\right]=\frac{0,08}{0,6}\approx0,133M\\\left[Cl^-\right]=\frac{0,12}{0,6}=0,2M\\\left[OH^-\right]=\frac{0,04}{0,6}\approx0,066M\end{matrix}\right.\)
Câu 2:
Ta có: \(\Sigma n_{K^+}=n_{KCl}+2n_{K_2SO_4}=0,2.1,5+0,3.2.2=1,5\left(mol\right)\)
\(n_{Cl^-}=n_{KCl}=0,2.1,5=0,3\left(mol\right)\)
\(n_{SO_4^{2-}}=0,3.2=0,6\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\left[K^+\right]=\frac{1,5}{0,5}=3M\\\left[Cl^-\right]=\frac{0,3}{0,5}=0,6M\\\left[SO_4^{2-}\right]=\frac{0,6}{0,5}=1,2M\end{matrix}\right.\)
Bạn tham khảo nhé!
a, Ta có: \(n_{H_2SO_4}=0,3.0,5=0,15\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{H^+}=2n_{H_2SO_4}=0,3\left(mol\right)\\n_{SO_4^{2-}}=n_{H_2SO_4}=0,15\left(mol\right)\end{matrix}\right.\)
\(n_{K^+}=n_{OH^-}=n_{KOH}=0,2.1=0,2\left(mol\right)\)
\(H^++OH^-\rightarrow H_2O\)
0,3 ___ 0,2 __________ (mol)
\(\Rightarrow n_{H^+\left(dư\right)}=0,1\left(mol\right)\)
⇒ Dung dịch A gồm: H+; SO42- và K+
\(\Rightarrow\left\{{}\begin{matrix}\left[H^+\right]=\frac{0,1}{0,5}=0,2M\\\left[SO_4^{2-}\right]=\frac{0,15}{0,5}=0,3M\\\left[K^+\right]=\frac{0,2}{0,5}=0,4M\end{matrix}\right.\)
b, \(H^++OH^-\rightarrow H_2O\)
__0,1 → 0,1 ___________ (mol)
\(\Rightarrow n_{NaOH}=n_{OH^-}=0,1\left(mol\right)\)
\(\Rightarrow V_{NaOH}=\frac{0,1}{0,5}=0,2\left(l\right)\)
Bạn tham khảo nhé!
Hoang Duong
a, \(H_2SO_4+2KOH\rightarrow K_2SO_4+2H_2O\)
b, \(H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\)
a, \(NaHCO_3+NaOH\rightarrow Na_2CO_3+H_2O\)
\(HCO_3^-+OH^-\rightarrow CO_3^{2-}+H_2O\)
b, \(\left[Na^+\right]=\dfrac{0,2.1,5+0,12.1,6}{0,2+0,12}=1,5376M\)
\(\left[CO_3^{2-}\right]=\dfrac{0,2.1,5}{0,2+0,12}=0,9375M\)
\(n_{H^+}=0,3\left(mol\right)\)
\(n_{OH^-}=0,192\left(mol\right)\)
\(\Rightarrow n_{H^+dư}=0,108\left(mol\right)\)
\(\Rightarrow\left[H^+\right]=\dfrac{0,108}{0,2+0,12}=0,3375M\)
\(\Rightarrow pH\approx0,47\)
a) Ta có: \(\left\{{}\begin{matrix}n_{CuCl_2}=0,3\left(mol\right)\\n_{BaCl_2}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left[Cu\right]=\dfrac{0,3}{0,5}=0,6\left(M\right)\\ \Rightarrow\left[Ba\right]=\dfrac{0,1}{0,5}=0,2\left(M\right)\\ \Rightarrow\left[Cl\right]=\dfrac{0,3.2+0,1.2}{0,5}=1,6\left(M\right)\)
\(n_{OH^-}=n_{NaOH}=0,3.1,5=0,45\left(mol\right)\\ n_{H^+}=n_{HCl}+2n_{H_2SO_4}=0,2x+0,5.0,2.2=0,2x+0,2\left(mol\right)\)
PT ion rút gọn: \(H^++OH^-\rightarrow H_2O\)
0,45<---0,45
\(\Rightarrow0,2x+0,2=0,45\Leftrightarrow x=1,25M\)
Ta có: \(V_{dd}=0,3+0,2=0,5\left(l\right)\) và \(\left\{{}\begin{matrix}n_{Na^+}=0,45\left(mol\right)\\n_{Cl^-}=0,2.1,25=0,25\left(mol\right)\\n_{SO_4^{2-}}=0,2.0,5=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}C_{Na^+}=\dfrac{0,45}{0,5}=0,9M\\C_{Cl^-}=\dfrac{0,25}{0,5}=0,5M\\C_{SO_4^{2-}}=\dfrac{0,1}{0,5}=0,2M\end{matrix}\right.\)