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a) 2KClO3 (7/75 mol) \(\underrightarrow{t^o}\) 2KCl (7/75 mol) + 3O2\(\uparrow\) (0,14 mol).
b) Số mol khí oxi là 4,48/32=0,14 (mol).
Khối lượng kali clorat cần dùng là 7/75.122,5=343/30 (g).
Khối lượng chất rắn thu được là 7/75.74,5=1043/150 (g).
\(a,PTHH:2KClO_3\underrightarrow{t^o,MnO_2}2KCl+3O_2\uparrow\\ b,n_{O_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\ Theo.pt:n_{KClO_3}=\dfrac{2}{3}n_{O_2}=\dfrac{2}{3}.0,2=\dfrac{2}{15}\left(mol\right)\\ m_{KClO_3}=\dfrac{2}{15}.122,5=\dfrac{49}{3}\left(g\right)\)
\(a.\)
\(n_{KClO_3}=\dfrac{3.675}{122.5}=0.03\left(mol\right)\)
\(2KClO_3\underrightarrow{t^0}2KCl+3O_2\)
\(0.03........................0.045\)
\(V_{O_2}=0.045\cdot22.4=1.008\left(l\right)\)
\(n_{O_2}=\dfrac{11.2}{22.4}=0.5\left(mol\right)\)
\(\Rightarrow n_{KClO_3}=\dfrac{0.5\cdot2}{3}=\dfrac{1}{3}mol\)
\(\Rightarrow m_{KClO_3}=\dfrac{1}{3}\cdot122.5=40.83\left(g\right)\)
a.\(n_{KClO_3}=\dfrac{m_{KClO_3}}{M_{KClO_3}}=\dfrac{12,25}{122,5}=0,1mol\)
\(2KClO_3\rightarrow\left(t^o\right)2KCl+3O_2\)
2 2 3 ( mol )
0,1 0,15
\(V_{O_2}=n_{O_2}.22,4=0,15.22,4=3,36l\)
b.\(V_{kk}=V_{O_2}.5=3,36.5=16,8l\)
c.\(n_{Fe}=\dfrac{m_{Fe}}{M_{Fe}}=\dfrac{28}{56}=0,5mol\)
\(3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\)
3 2 1 ( mol )
0,5 > 0,15 ( mol )
0,225 0,15 ( mol )
\(m_{Fe\left(du\right)}=n_{Fe\left(du\right)}.M_{Fe}=\left(0,5-0,225\right).56=15,4g\)
Câu 3.
a.b.\(n_{KClO_3}=\dfrac{24,5}{122,5}=0,2mol\)
\(2KClO_3\rightarrow\left(t^o,MnO_2\right)2KCl+3O_2\)
0,2 0,3 ( mol )
\(V_{O_2}=0,3.22,4=6,72l\)
c.\(n_{Al}=\dfrac{5,4}{27}=0,2mol\)
\(4Al+3O_2\rightarrow\left(t^o\right)2Al_2O_3\)
0,2 < 0,3 ( mol )
0,2 0,1 ( mol )
\(m_{Al_2O_3}=0,1.102=10,2g\)
Câu 4.
a.b.
\(n_{KClO_3}=\dfrac{12,25}{122,5}=0,1mol\)
\(2KClO_3\rightarrow\left(t^o,MnO_2\right)2KCl+3O_2\)
0,1 0,15 ( mol )
\(V_{O_2}=0,15.22,4=3,36l\)
c.\(n_{Fe}=\dfrac{8,4}{56}=0,15mol\)
\(3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\)
0,15 < 0,15 ( mol )
0,15 0,05 ( mol )
\(m_{Fe_3O_4}=0,05.232=11,6g\)
a) \(n_{O_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
PTHH: 2KClO3 --to--> 2KCl + 3O2
0,2<-------------------0,3
=> \(m_{KClO_3}=0,2.122,5=24,5\left(g\right)\)
b) \(n_{KClO_3}=\dfrac{490}{122,5}=4\left(mol\right)\)
PTHH: 2KClO3 --to--> 2KCl + 3O2
4-------------->4---->6
=> \(m_{KCl}=4.74,5=298\left(g\right)\)
=> \(m_{O_2}=6.32=192\left(g\right)\)
2KClO3 \(\underrightarrow{t^o}\) 2KCl + 3O2
a, \(n_{O_2}=\dfrac{6,72}{22,4}=0,3mol\\ n_{KClO_3}=\dfrac{0,3.2}{3}=0,2mol\\ m_{KClO_3}=0,2.122,5=24,5g\)
b, \(n_{KClO_3}=\dfrac{490}{122,5}=4mol\)
\(\Rightarrow m_{KCl}=4.74,5=298g\)
\(n_{O_2}=\dfrac{4.3}{2}=6mol\\ m_{O_2}=6.32=192g\)