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a) PTTH: \(2H_2+O_2\rightarrow2H_2O\)
\(C_2H_2+\dfrac{5}{2}O_2\underrightarrow{t^o}2CO_2+H_2O\)
b) Ta có: \(\left\{{}\begin{matrix}\overline{M}_{hhkhí}=0,5\cdot28=14\\n_{hhkhí}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\end{matrix}\right.\)
Theo phương pháp đường chéo, ta có: \(\dfrac{n_{H_2}}{n_{C_2H_2}}=\dfrac{12}{12}=1\)
\(\Rightarrow n_{H_2}=n_{C_2H_2}=0,3\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%V_{H_2}=\dfrac{0,3}{0,6}\cdot100\%=50\%\\\%V_{C_2H_2}=50\%\\\%m_{H_2}=\dfrac{0,3\cdot2}{5,6}\cdot100\%\approx10,71\%\\\%m_{C_2H_4}=89,29\%\end{matrix}\right.\)
nSO2= 0,5(mol)
nO2=0,2(mol)
PTHH: 2 SO2 + O2 -to-> 2 SO3
Ta có: 0,5/2 > 0,2/1
=> O2 hết, SO2 dư, tính theo nO2
-> nSO3=nO2.2=0,2.2=0,4(mol)
nSO2(dư)= 0,5-0,2.2=0,1(mol)
=>V(sau p.ứ)= V(SO2,dư,đktc)+V(SO3,đktc)=0,1.22,4+0,4.22,4=11,2(l)
\(\dfrac{mH2}{mO2}\)=\(\dfrac{3}{8}\)=x
=>;mH2=x=>nH2=\(\dfrac{3x}{2}\)mol
m02=\(\dfrac{8x}{32}\)=\(\dfrac{x}{4}\)mol
PTHH: 2H2 + O2 to→ 2H2O
xét: \(\dfrac{3x}{2}\);\(\dfrac{3x}{12}\)
h2 dư, o2 hết
nh2dư=\(\dfrac{3x}{2}-\dfrac{3x}{12}\)\(=\dfrac{15x}{12}\)=\(\dfrac{1,792}{22,4}\)=0,08(mol)
=>x=\(\dfrac{0,08.12}{15}\)=0,064
nO2=\(\dfrac{0,064}{4}\)=0,016(mol)
nH2=\(\dfrac{0,064.3}{2}\)=0,096(mol)
VQ(đktc)=22,4(0,016+0,096)=2,5088(lít)
Gọi số mol H2, O2 là a, b (mol)
Ta có: \(\dfrac{m_{H_2}}{m_{O_2}}=\dfrac{3}{8}\)
=> \(\dfrac{2a}{32b}=\dfrac{3}{8}\Rightarrow\dfrac{a}{b}=\dfrac{6}{1}\) hay a = 6b
PTHH: 2H2 + O2 --to--> 2H2O
Xét tỉ lệ: \(\dfrac{6b}{2}>\dfrac{b}{1}\) => H2 dư, O2 hết
PTHH: 2H2 + O2 --to--> 2H2O
2b<---b
=> \(n_{H_2\left(dư\right)}=6b-2b=4b=\dfrac{1,792}{22,4}=0,08\left(mol\right)\)
=> b = 0,02 (mol)
=> a = 0,12 (mol)
=> VQ = (0,02 + 0,12).22,4 = 3,136 (l)
a) \(n_{CH_4}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)
PTHH: CH4 + 2O2 --to--> CO2 + 2H2O
0,4---------------->0,4
=> \(V_{CO_2}=0,4.22,4=8,96\left(l\right)\)
b) \(n_{O_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)
Xét tỉ lệ \(\dfrac{0,4}{1}>\dfrac{0,4}{2}\) => CH4 dư, O2 hết
PTHH: CH4 + 2O2 --to--> CO2 + 2H2O
0,4-------->0,2
=> \(V_{CO_2}=0,2.22,4=4,48\left(l\right)\)
\(a.2H_2+O_2-^{t^o}\rightarrow2H_2O\\ b.n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\\ n_{O_2}=\dfrac{1}{2}n_{H_2}=0,2\left(mol\right)\\ \Rightarrow V_{O_2}=0,2.22,4=4,48\left(l\right)\\ TrongkhôngkhíO_2chiếm20\%\\ \Rightarrow V_{kk}=\dfrac{4,48}{20\%}=22,4\left(l\right)\)
a)
\(n_{H_2} = \dfrac{6,72}{22,4} = 0,3(mol)\\ n_{O_2} = \dfrac{2,24}{22,4} = 0,1(mol)\\ 2H_2 + O_2 \xrightarrow{t^o} 2H_2O\)
Ta thấy :
\(\dfrac{n_{H_2}}{2} = 0,15 > \dfrac{n_{O_2}}{1} = 0,1\) nên H2 dư
Theo PTHH : \(n_{H_2O} = 2n_{O_2} = 0,2(mol) \Rightarrow m_{H_2O} = 0,2.18 = 3,6(gam)\)
b)
Ta có : \(n_{H_2\ pư} = 2n_{O_2} = 0,2(mol)\\ \Rightarrow n_{H_2\ dư} = 0,3 - 0,2 = 0,1(mol)\\ \Rightarrow V_{H_2\ dư} = 0,1.22,4 = 2,24(lít)\)