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a)
$Fe_2(SO_4)_3 + 6KOH \to 2Fe(OH)_3 + 3K_2SO_4$
b)
$n_{Fe_2(SO_4)_3} = 0,3.1 = 0,3(mol)$
$n_{KOH} = \dfrac{16,8}{56} =0,3(mol)$
Ta thấy :
$n_{KOH} : 3 < n_{Fe_2(SO_4)_3} : 1$ nên $Fe_2(SO_4)_3$ dư
$n_{Fe(OH)_3} = \dfrac{1}{3}n_{KOH} = 0,1(mol)$
$n_{Fe_2O_3} = \dfrac{1}{2}n_{Fe(OH)_3} = 0,05(mol)$
$m_{Fe_2O_3} = 0,05.160 = 8(gam)$
\(\begin{array}{l} a,\\ PTHH:\\ AlCl_3+3KOH\to Al(OH)_3\downarrow+3KCl\ (1)\\ 2Al(OH)_3\xrightarrow{t^o} Al_2O_3+3H_2O\ (2)\\ b,\\ n_{KOH}=\dfrac{3,36}{56}=0,06\ (mol)\\ Theo\ pt\ (1):\ n_{AlCl_3}=\dfrac{1}{3}n_{KOH}=0,02\ (mol)\\ \Rightarrow m_{AlCl_3}=0,02\times 133,5=2,67\ (g)\\ c,\\ Theo\ pt\ (1):\ n_{Al(OH)_3}=\dfrac{1}{3}n_{KOH}=0,02\ (mol)\\ Theo\ pt\ (2):\ n_{Al_2O_3}=\dfrac{1}{2}n_{Al(OH)_3}=0,01\ (mol)\\ \Rightarrow m_{Al_2O_3}=0,01\times 102=1,02\ (g)\end{array}\)
\(n_{KOH}=\dfrac{22,4}{56}=0,4(mol)\\ a,PTHH:MgCl_2+2KOH\to Mg(OH)_2\downarrow+2KCl\\ Mg(OH)_2\buildrel{{t^o}}\over\to MgO+H_2O\\ b,\text {Vì } \dfrac{n_{MgCl_2}}{1}<\dfrac{n_{KOH}}{2} \Rightarrow \text {KOH dư}\\ \Rightarrow n_{MgO}=n_{Mg(OH)_2}=n_{MgCl_2}=0,15(mol)\\ \Rightarrow m_{MgO}=0,15.40=6(g)\\ c,\text {Chất tan trong nước lọc là KCl}\\ \text {Theo PT: }n_{KCl}=2n_{MgCl_2}=0,3(mol)\\ \Rightarrow m_{KCl}=0,3.74,5=22,35(g)\)
\(n_{CuCl_2}=0,1.0,3=0,03mol\)
PTHH: \(CuCl_2+2KOH\rightarrow2KCl+Cu\left(OH\right)_2\)
\(Cu\left(OH\right)_2\rightarrow^{t^o}CuO+H_2O\)
\(m_{CuO}=0,03.80=2,4g\)
Phản ứng này không tạo khí bạn nhé :
200ml = 0,2l
300ml = 0,3l
\(n_{MgCl2}=\dfrac{19}{95}=0,2\left(mol\right)\)
a) Pt : \(MgCl_2+2NaOH\rightarrow Mg\left(OH\right)_2+2NaCl|\)
1 2 1 2
0,2 0,2 0,4
\(n_{Mg\left(OH\right)2}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)
⇒ \(m_{Mg\left(OH\right)2}=0,2.58=11,6\left(g\right)\)
Pt : \(Mg\left(OH\right)_2\underrightarrow{t^o}MgO+H_2O|\)
1 1 1
0,2 0,2
\(n_{MgO}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)
⇒ \(m_{MgO}=0,2.40=8\left(g\right)\)
c) \(n_{NaCl}=\dfrac{0,2.2}{1}=0,4\left(mol\right)\)
\(V_{ddspu}=0,2+0,3=0,5\left(l\right)\)
\(C_{M_{NaCl}}=\dfrac{0,4}{0,5}=0,8\left(M\right)\)
Chúc bạn học tốt
\(n_{CuCl_2}=\dfrac{1,35}{135}=0,01(mol)\\ n_{KOH}=\dfrac{28.10}{100.56}=0,05(mol)\\ a,CuCl_2+2KOH\to Cu(OH)_2\downarrow+2KCl\\ Cu(OH)_2\xrightarrow{t^o}CuO+H_2O\\ \dfrac{n_{CuCl_2}}{1}<\dfrac{n_{KOH}}{2}\Rightarrow KOH\text{ dư}\\ b,n_{CuO}=n_{Cu(OH)_2}=0,01(mol)\\ \Rightarrow m_{CuO}=0,01.80=0,8(g)\)
\(c,n_{KCl}=0,02(mol);n_{KOH(dư)}=0,05-0,01.2=0,03(mol)\\ \Rightarrow m_{Cu(OH)_2}=0,01.98=0,98(g);m_{KCl}=0,02.74,9=1,49(g)\\ \Rightarrow \begin{cases} C\%_{KCl}=\dfrac{1,49}{1,35+28-0,98}.100\%=5,25\%\\ C\%_{KOH(dư)}=\dfrac{0,03.56}{1,35+28-0,98}.100=5,92\% \end{cases}\)
nMgCl2 = 0,1 nKOH = 0,3=> KOH dư MgCl2 hết
MgCl2 + 2KOH => 2KCl + Mg(OH)2
0,1--------0,2------------0,2-----> 0,1
Mg(OH)2 => MgO + H2O
0,1-------------> 0,1
=> mcr = 0,1.40=4
Vdd = 80 + 320 = 400ml = 0,4l
CM KCl= 0,2/ 0,4 = 0,5M
CM KOH dư = (0,3-0,2)/ 0,4 = 0,25M