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Gọi số mol NO, NO2 lần lượt là a, b
=> \(\dfrac{30a+46b}{a+b}=17.2=34\)
=> 30a + 46b = 34a + 34b
=> 4a = 12b
=> a = 3b
=> \(\left\{{}\begin{matrix}\%V_{NO}=\dfrac{a}{a+b}.100\%=\dfrac{3b}{3b+b}.100\%=\dfrac{3}{4}.100\%=75\%\\V_{NO_2}=100\%-75\%=25\%\end{matrix}\right.\)
\(a.\)
\(GS:\)
\(n_{hh}=1\left(mol\right)\)
\(Đặt:n_{N_2}=a\left(mol\right),n_{CO_2}=b\left(mol\right)\)
\(\Rightarrow a+b=1\left(1\right)\)
\(m_A=28a+44b=18\cdot2=36\left(2\right)\)
\(\left(1\right),\left(2\right):\)
\(a=b=0.5\)
\(\%m_{N_2}=\dfrac{0.5\cdot28}{0.5\cdot28+0.5\cdot44}\cdot100\%=38.89\%\)
\(\%m_{CO_2}=61.11\%\)
\(b.\)
\(\dfrac{n_{N_2}}{n_{CO_2}}=\dfrac{0.5}{0.5}=\dfrac{1}{1}\)
\(n_{N_2}=n_{CO_2}=\dfrac{1}{2}\cdot n_A=\dfrac{0.2}{2}=0.1\left(mol\right)\)
\(Đặt:n_{CO_2}=x\left(mol\right)\)
\(\overline{M}=\dfrac{0.1\cdot28+0.1\cdot44+44x}{0.2+x}=20\cdot2=40\left(\dfrac{g}{mol}\right)\)
\(\Rightarrow x=0.2\)
\(m_{CO_2\left(cầnthêm\right)}=0.2\cdot44=8.8\left(g\right)\)
a)
Dựa vào màu sắc:
+ NO: Chất khí không màu
+ NO2: Chất khí màu nâu
b)
Gọi số mol NO2, O2 là a, b (mol)
\(M=\dfrac{46a+32b}{a+b}=17,75.2=35,5\left(g/mol\right)\)
=> 10,5a = 3,5b
=> 3a = b
\(\left\{{}\begin{matrix}\%V_{NO_2}=\dfrac{a}{a+b}.100\%=\dfrac{a}{a+3a}.100\%=25\%\\\%V_{O_2}=100\%-25\%=75\%\end{matrix}\right.\)
a) \(M_X=19.2=38\left(g/mol\right)\)
`=>` \(d_{X/kk}=\dfrac{38}{29}=1,310345\)
b) \(m_X=0,4.38=15,2\left(g\right)\)
Gọi \(\left\{{}\begin{matrix}n_{O_2}=x\left(mol\right)\\n_{CO_2}=y\left(mol\right)\end{matrix}\right.\)
`=>` \(\left\{{}\begin{matrix}32x+44y=15,2\\x+y=0,4\end{matrix}\right.\Leftrightarrow x=y=0,2\)
\(m_Y=0,1.28+15,2=18\left(g\right)\)
`=>` \(\left\{{}\begin{matrix}\%m_{N_2}=\dfrac{0,1.28}{18}.100\%=15,56\%\\\%m_{O_2}=\dfrac{0,2.32}{18}.100\%=35,56\%\\\%m_{CO_2}=100\%-15,56\%-35,56\%=48,88\%\end{matrix}\right.\)
b) \(M_{hh}=4.10=40\left(g/mol\right)\)
Gọi \(n_{NO_2}=a\left(mol\right)\)
`=>` \(\left\{{}\begin{matrix}m_{hh}=18+46a\left(g\right)\\n_{hh}=0,5+0,1+a=0,6+a\left(mol\right)\end{matrix}\right.\)
`=>` \(M_{hh}=\dfrac{m_{hh}}{n_{hh}}=\dfrac{18+46a}{0,6+a}=40\)
`=> a = 1`
`=> V_{NO_2(đktc)} = 1.22,4 = 22,4 (l)`
a) \(\overline{M}_A=5,875.2=11,75\left(g/mol\right)\)
b) Gọi số mol N2, H2 là a, b (mol)
\(\overline{M}_A=\dfrac{28a+2b}{a+b}=11,75\left(g/mol\right)\)
=> 16,25a = 9,75b
=> a = 0,6b
\(\left\{{}\begin{matrix}\%n_{N_2}=\dfrac{a}{a+b}.100\%=\dfrac{0,6b}{0,6b+b}.100\%=37,5\%\\\%n_{H_2}=\dfrac{b}{a+b}.100\%=\dfrac{b}{0,6b+b}.100\%=62,5\%\end{matrix}\right.\)
c)
1 mol hỗn hợp A chứa \(\left\{{}\begin{matrix}n_{N_2}=\dfrac{1.37,5}{100}=0,375\left(mol\right)\\n_{H_2}=\dfrac{1.62,5}{100}=0,625\left(mol\right)\end{matrix}\right.\)
\(\overline{M}_B=\dfrac{0,375.28+0,625.2+17x}{1+x}=6,4.2=12,8\left(g/mol\right)\)
=> x = 0,25 (mol)
a) \(\left\{{}\begin{matrix}n_{Cl_2}+n_{O_2}=\dfrac{6,72}{22,4}=0,3\\\overline{M}=\dfrac{71.n_{Cl_2}+32.n_{O_2}}{n_{Cl_2}+n_{O_2}}=2.29=58\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}n_{Cl_2}=0,2\left(mol\right)\\n_{O_2}=0,1\left(mol\right)\end{matrix}\right.\)
\(\left\{{}\begin{matrix}\%V_{Cl_2}=\dfrac{0,2}{0,3}.100\%=66,67\%\\\%V_{O_2}=\dfrac{0,1}{0,3}.100\%=33,33\%\end{matrix}\right.\)
b) \(\left\{{}\begin{matrix}m_{Cl_2}=0,2.71=14,2\left(g\right)\\m_{O_2}=0,1.32=3,2\left(g\right)\end{matrix}\right.\)
\(Đặt:n_{hh}=1\left(mol\right)\)
\(n_{NO_2}=a\left(mol\right),n_{NO}=b\left(mol\right)\)
\(\Leftrightarrow a+b=1\left(1\right)\)
\(\overline{M}=\dfrac{46a+30b}{a+b}=18.2\cdot2=36.4\)
\(\Leftrightarrow46a+30b=36.4\left(2\right)\)
\(\left(1\right),\left(2\right):a=0.4,b=0.6\)
Tới đây tự tính tiếp nhé !!
Ta có: \(\overline{M}_{hh}=18,2\cdot2=36,4\left(đvC\right)\)
Theo sơ đồ đường chéo: \(\dfrac{n_{NO_2}}{n_{NO}}=\dfrac{6,4}{9,6}=\dfrac{2}{3}\)
\(\Rightarrow\left\{{}\begin{matrix}\%V_{NO_2}=\dfrac{2}{5}\cdot100\%=40\%\\\%V_{NO}=60\%\end{matrix}\right.\)
Giả sử \(n_{NO_2}=2\left(mol\right)\) \(\Rightarrow n_{NO}=3\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{NO_2}=\dfrac{2\cdot46}{2\cdot46+3\cdot30}\cdot100\%\approx50,55\%\\\%m_{NO}=49,45\%\end{matrix}\right.\)
a) Gọi nO2 =a (mol); nO3 = b(mol)
Có: \(\dfrac{32a+48b}{a+b}=20.2=40\)
=> 32a + 48b = 40a + 40b
=> 8a = 8b => a = b
=> \(\left\{{}\begin{matrix}\%V_{O_2}=\dfrac{a}{a+b}.100\%=\dfrac{a}{a+a}.100\%=50\%\\\%V_{O_3}=100\%-50\%=50\%\end{matrix}\right.\)
b) Gọi nN2 =a (mol); nNO = b(mol)
Có: \(\dfrac{28a+30b}{a+b}=14,75.2=29,5\)
=> 28a + 30b = 29,5a + 29,5b
=> 1,5a = 0,5b
=> 3a = b
=> \(\left\{{}\begin{matrix}\%V_{N_2}=\dfrac{a}{a+b}.100\%=\dfrac{a}{a+3a}.100\%=25\%\\\%V_{NO}=100\%-25\%=75\%\end{matrix}\right.\)