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áp dụng sơ đồ đường chéo ta có:
50 0 40 40 10
\(\Rightarrow\) \(\frac{m1}{m2}\)= \(\frac{40}{10}\)= \(\frac{4}{1}\)
\(\Rightarrow\) \(\frac{200}{m2}\)= \(\frac{4}{1}\)
\(\Rightarrow\) m2= \(\frac{200}{4}\)= 50( g)
vậy cần thêm 50g nước vào 200g dd CH3COOH 50% để thu được dd CH3COOH 40%
a)
\(n_{CO_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
PTHH: Na2CO3 + 2CH3COOH --> 2CH3COONa + CO2 + H2O
0,15<---------0,3<------------------------0,15
=> \(C\%_{dd.CH_3COOH}=\dfrac{0,3.60}{200}.100\%=9\%\)
b)
\(m_{dd.Na_2CO_3}=\dfrac{0,15.106.100}{15}=106\left(g\right)\)
c)
PTHH: 2CH3COOH + Ba(OH)2 --> (CH3COO)2Ba + 2H2O
0,3--------->0,15
=> \(V_{dd.Ba\left(OH\right)_2}=\dfrac{0,15}{0,5}=0,3\left(l\right)=300\left(ml\right)\)
\(n_{MgCO_3}=\dfrac{12.6}{84}=0.15\left(mol\right)\)
\(Mg+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Mg+CO_2+H_2O\)
\(0.15..........0.3............................................0.15\)
\(V_{CO_2}=0.15\cdot22.4=3.36\left(l\right)\)
\(m_{CH_3COOH}=0.3\cdot60=18\left(g\right)\)
\(C\%_{CH_3COOH}=\dfrac{18}{200}\cdot100\%=9\%\)
\(n_{Fe}=\dfrac{6,5}{56}=\dfrac{13}{112}mol\)
\(m_{CH_3COOH}=\dfrac{90\cdot20\%}{100\%}=18g\Rightarrow n_{CH_3COOH}=0,3mol\)
\(Fe+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Fe+H_2\uparrow\)
\(\dfrac{13}{112}\) 0,3 0 0
\(\dfrac{13}{112}\) \(\dfrac{13}{56}\) \(\dfrac{13}{112}\) \(\dfrac{13}{112}\)
0 \(\dfrac{19}{280}\) \(\dfrac{13}{112}\) \(\dfrac{13}{112}\)
a)\(m_{\left(CH_3COO\right)_2Fe}=\dfrac{13}{112}\cdot174=20,2g\)
\(m_{H_2}=\dfrac{13}{112}\cdot2=\dfrac{13}{56}g\)
\(m_{dd\left(CH_3COO\right)_2Fe}=6,5+90-\dfrac{13}{56}=96,27g\)
\(C\%=\dfrac{20,2}{96,27}\cdot100\%=20,98\%\)
a, \(m_{CH_3COOH}=20.3,75\%=0,75\left(g\right)\Rightarrow n_{CH_3COOH}=\dfrac{0,75}{60}=0,0125\left(mol\right)\)
PT: \(2CH_3COOH+Ca\left(OH\right)_2\rightarrow\left(CH_3COO\right)_2Ca+2H_2O\)
Theo PT: \(n_{Ca\left(OH\right)_2}=\dfrac{1}{2}n_{CH_3COOH}=0,00625\left(mol\right)\)
\(\Rightarrow V_{ddCa\left(OH\right)_2}=\dfrac{0,00625}{0,2}=0,03125\left(l\right)=31,25\left(ml\right)\)
b, \(n_{\left(CH_3COO\right)_2Ca}=\dfrac{1}{2}n_{CH_3COOH}=0,00625\left(mol\right)\)
\(\Rightarrow m_{\left(CH_3COO\right)_2Ca}=0,00625.158=0,9875\left(g\right)\)
PT: \(CH_3COOH+NaOH\rightarrow CH_3COONa+H_2O\)
Ta có: \(n_{CH_3COONa}=\dfrac{9,84}{82}=0,12\left(mol\right)\)
Theo PT: \(n_{CH_3COOH}=n_{NaOH}=n_{CH_3COONa}=0,12\left(mol\right)\)
\(\Rightarrow V_{ddCH_3COOH}=\dfrac{0,12}{0,5}=0,24\left(l\right)\)
\(m_{NaOH}=0,12.40=4,8\left(g\right)\Rightarrow m_{ddNaOH}=\dfrac{4,8}{20\%}=24\left(g\right)\)
áp dụng sơ đồ đường chéo ta có:
50 40
40
0 10
⇒⇒ m1\m2= 40\10= 4\1
⇒⇒ 200\m2= 4\1
⇒⇒ m2= 200\4= 50( g)
vậy cần thêm 50g nước vào 200g dd CH3COOH 50% để thu được dd CH3COOH 40%