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a) \(PT:CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2\uparrow\)
\(HCl+NaOH\rightarrow NaOH+H_2O\)
b) \(m_{HCl}=\frac{200.10,95\%}{100\%}=21,9\left(g\right)\)
\(n_{HCl}=\frac{21,9}{36,5}=0,6\left(mol\right)\)
c) \(n_{NaOH}=2.0,05=0,1\left(mol\right)\Rightarrow n_{HCl\left(pưNaOH\right)}=0,1\left(mol\right)\)
\(\Rightarrow n_{HCl\left(pưCaCO_3\right)}=0,6-0,1=0,5\left(mol\right)\)
d) \(n_{CaCO_3}=\frac{1}{2}n_{HCl\left(pưCaCO_3\right)}=0,5.\frac{1}{2}=0,25\left(mol\right)\)
\(m_{CaCO_3}=0,25.100=25\left(g\right)\)
e) \(n_{CO_2}=n_{CaCO_3}=0,25\left(mol\right)\)
\(V_{CO_2}=0,25.22,4=5,6\left(l\right)\)
f) \(n_{CaCl_2}=n_{CaCO_3}=0,25\left(mol\right)\)
\(m_{ddA}=25+200-0,25.44=214\left(g\right)\)
\(C\%_{ddCaCl_2}=\frac{0,25.111}{214}.100\%=12,97\%\)
\(C\%_{ddHCldư}=\frac{0,1.36,5}{214}.100\%=1,71\%\)
CaCO3 + 2HCl -> CaCl2 + CO2 + H2O (1)
2NaOH + CO2 -> Na2CO3 + H2O (2)
nCaCO3=0,15(mol)
nHCl=0,2(mol)
Vì \(\dfrac{0,2}{2}< 0,15\) nên CaCO3 dư
Theo PTHH 1 ta có:
nCO2=\(\dfrac{1}{2}\)nHCl=0,1(mol)
Theo PTHH 2 ta có:
nCO2=nNa2CO3=0,1(mol)
mNa2CO3=106.0,1=10,6(g)
Pt: Ba+2H2O -> Ba(OH)2+H2 (1)
Ba(OH)2+CuSO4 ->Cu(OH)2 \(\downarrow\) +BaSO4 \(\downarrow\)(2)
Ba(OH)2+(NH4)2SO4 ->BaSO4 \(\downarrow\)+2NH3+2H2O (3)
Cu(OH)2\(\underrightarrow{t^0}\)CuO+H2O (4)
BaSO4 \(\underrightarrow{t^0}\) ko xảy ra phản ứng
Theo (1) ta có \(n_{H_2}=n_{Ba\left(OH\right)_2}=n_{Ba}=\frac{27,4}{137}=0,2\left(mol\right)\)
\(n_{\left(NH_4\right)_2SO_4}=\frac{1,32\cdot500}{132\cdot100}=0,05\left(mol\right)\)
\(n_{CuSO_4}=\frac{2\cdot500}{100\cdot160}=0,0625\left(mol\right)\)
Ta thấy: \(n_{Ba\left(OH\right)_2}>n_{\left(NH_4\right)_2SO_4}+n_{CuSO4\:}\) nên Ba(OH)2 dư và 2 muối đều phản ứng hết
Theo (2) ta có: \(n_{Ba\left(OH\right)_2}=n_{Cu\left(OH\right)_2}=n_{BaSO_4}=n_{CuSO_4}=0,0625\left(mol\right)\)
Theo (3) ta có: \(n_{Ba\left(OH\right)_2}=n_{BaSO_4}=n_{\left(NH_4\right)_2SO_4}=0,05\left(mol\right)\)
và \(n_{NH_3}=2n_{\left(NH_4\right)_2SO_4}=0,05\cdot2=0,1\left(mol\right)\)
\(\Rightarrow n_{Ba\left(OH_2\right)}\text{dư}=0,2-\left(0,05+0,0625\right)=0,0875\left(mol\right)\)
a)\(V_{A\left(ĐKTC\right)}=V_{H_2}+V_{NH_3}=\left(0,2+0,1\right)\cdot22,4=6,72\left(l\right)\)
b)Theo (4) ta có: \(n_{CuO}=n_{Cu\left(OH\right)_2}=0,0625\left(mol\right)\)
\(m_{\text{chất rắn}}=m_{BaSO_4}+m_{CuO}=\left(0,0625+0,05\right)\cdot233+0,0625\cdot80=31,2125\left(g\right)\)
a, Ta có PTHH :
\(CuO+H_2\rightarrow Cu+H_2O\) ( I )
\(Fe_2O_3+3H_2\rightarrow2Fe+H_2O\) ( II )
\(Fe_3O_4+4H_2\rightarrow3Fe+4H_2O\) ( III )
b, \(n_{H2O}=\frac{m_{H2O}}{M_{H2O}}=\frac{14,4}{1.2+16}=\frac{14,4}{18}=0,8\left(mol\right)\)
Mà \(n_{\left(H\right)}=2.n_{H2O}=2.0,8=1,6\left(mol\right)\)
=> \(n_{H2}=\frac{1}{2}.n_{\left(H\right)}=\frac{1,6}{2}=0,8\left(mol\right)\)
-> \(V_{H2}=n_{H2}.22,4=0,8.22,4=17,92\left(l\right)\)
Câu 1:
\(n_{Al}=\dfrac{m}{M}=\dfrac{8,1}{27}=0,3mol\)
\(n_{H_2SO_4}=\dfrac{200.14,7}{98.100}=0,3mol\)
2Al+3H2SO4\(\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
-Tỉ lệ: \(\dfrac{0,3}{2}>\dfrac{0,3}{3}\rightarrow\)Al dư, H2SO4 hết
\(n_{Al\left(pu\right)}=\dfrac{2}{3}n_{H_2SO_4}=\dfrac{2}{3}.0,3=0,2mol\)
\(n_{Al\left(dư\right)}=0,3-0,2=0,1mol\)
\(n_{H_2}=n_{H_2SO_4}=0,3mol\)
\(V_{H_2}=0,3.22,4=6,72l\)
\(n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{3}n_{H_2SO_4}=\dfrac{1}{3}.0,3=0,1mol\)
\(m_{Al_2\left(SO_4\right)_3}=0,1.342=34,2gam\)
\(m_{dd}=8,1+200-0,1.27-0,3.2=204,8gam\)
C%Al2(SO4)3=\(\dfrac{34,2}{204,8}.100\approx16,7\%\)
Câu 2:
\(n_{MgO}=\dfrac{4}{40}=0,1mol\)
\(n_{H_2SO_4}=\dfrac{200.19,6}{98.100}=0,4mol\)
MgO+H2SO4\(\rightarrow\)MgSO4+H2O
-Tỉ lệ: \(\dfrac{0,1}{1}< \dfrac{0,4}{1}\rightarrow\)H2SO4 dư
\(n_{H_2SO_4\left(pu\right)}=n_{MgO}=0,1mol\)\(\rightarrow\)\(n_{H_2SO_4\left(dư\right)}=0,4-0,1=0,3mol\)
\(m_{H_2SO_4}=0,1.98=9,8gam\)
\(n_{MgSO_4}=n_{MgO}=0,1mol\)
\(m_{dd}=4+200=204gam\)
C%H2SO4(dư)=\(\dfrac{0,3.98}{204}.100\approx14,4\%\)
C%MgSO4=\(\dfrac{0,1.120}{204}.100\approx5,9\%\)
Câu 1)
a) 2HgO\(-t^0\rightarrow2Hg+O_2\)
b)Theo gt: \(n_{HgO}=\frac{2,17}{96}\approx0,023\left(mol\right)\\ \)
theo PTHH : \(n_{O2}=\frac{1}{2}n_{HgO}=\frac{1}{2}\cdot0,023=0,0115\left(mol\right)\\ \Rightarrow m_{O2}=0,0115\cdot32=0,368\left(g\right)\)
c)theo gt:\(n_{HgO}=0,5\left(mol\right)\)
theo PTHH : \(n_{Hg}=n_{HgO}=0,5\left(mol\right)\\ \Rightarrow m_{Hg}=0,5\cdot80=40\left(g\right)\)
Câu 2)
a)PTHH : \(S+O_2-t^0\rightarrow SO_2\)
b)theo gt: \(n_{SO2}=\frac{2,24}{22,4}=0,1\left(mol\right)\)
theo PTHH \(n_S=n_{SO2}=0,1\left(mol\right)\\ \Rightarrow m_S=0,1\cdot32=3,2\left(g\right)\)
Ta có khối lượng S tham gia là 3,25 g , khối lượng S phản ứng là 3,2 g
Độ tinh khiết của mẫu lưu huỳnh là \(\frac{3,2}{3,25}\cdot100\%\approx98,4\%\)
c)the PTHH \(n_{O2}=n_{SO2}=0,1\left(mol\right)\Rightarrow m_{O2}=0,1\cdot32=3,2\left(g\right)\)
Bài 1:
\(n_{C_4H_{10}}=\frac{m}{M}=\frac{11,6}{58}=0,2mol\)
PTHH: \(2C_4H_{10}+13O_2\rightarrow^{t^o}8CO_2\uparrow+10H_2O\)
0,2 1,3 0,8 1 mol
\(\rightarrow n_{O_2}=n_{C_4H_{10}}=\frac{13.0,2}{2}=1,3mol\)
\(V_{O_2\left(ĐKTC\right)}=n.22,4=1,3.22,4=29,12l\)
\(\rightarrow n_{CO_2}=n_{C_4H_{10}}=\frac{8.0,2}{2}=0,8mol\)
\(m_{CO_2}=n.M=0,8.44=35,2g\)
\(\rightarrow n_{H_2O}=n_{C_4H_{10}}=\frac{10.0,2}{2}=1mol\)
\(m_{H_2O}=n.M=1.18=18g\)
Theo định luật BTKL ta có :
\(m_{C_2H_2}+m_{H_2}=m+m_y\)
\(\Rightarrow0,06.26+0,04.2=m+0,02.0,5.32\)
\(\Rightarrow m=1,32g\)
Bài 1:
Ta có: \(n_{HCl}=0,2.0,5=0,1\left(mol\right)\)
BTNT H, có: \(n_{HCl}=2n_{H_2O}\Rightarrow n_{H_2O}=0,05\left(mol\right)\)
Theo ĐL BTKL, có: m oxit + mHCl = mmuối + mH2O
⇒ mmuối = 2,8 + 0,1.36,5 - 0,05.18 = 5,55 (g)
Bài 2:
\(m_{KOH}=200.5,6\%=11,2\left(g\right)\Rightarrow n_{KOH}=\dfrac{11,2}{56}=0,2\left(mol\right)\)
PT: \(2KOH+CuCl_2\rightarrow2KCl+Cu\left(OH\right)_2\)
Theo PT: \(n_{Cu\left(OH\right)_2}=\dfrac{1}{2}n_{KOH}=0,1\left(mol\right)\)
\(\Rightarrow m_{Cu\left(OH\right)_2}=0,1.98=9,8\left(g\right)\)