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1, a, + 8.2=16 => CH4
+ 8,5 . 2 = 17 => NH3
+ 16 . 2 =32 => O2
+ 22 . 2 = 44 => CO2
b, + 0,138 . 29 \(\approx4\) => He
+ 1,172 . 29 \(\approx34\) => H2S
+ 2,448 . 29 \(\approx71\Rightarrow Cl_2\)
+ 0,965 . 29 \(\approx28\) => N
3/ nhỗn hợp = 8,4.1023 : 6.1023 = 1,4 (mol)
nO = 230,4 : 16 = 14,4 (mol)
Gọi nCa3(PO4)2 = x (mol) \(\rightarrow\) nO = 8x (mol)
\(\rightarrow\) nAl2(SO4)3 = 1,4-x (mol) \(\rightarrow\) nO = 12.(1,4-x) (mol)
\(\rightarrow\) 8x + 12.(1,4-x) = 14,4 \(\rightarrow\) x = 0,6 (mol)
nCa3(PO4)2= 0,6 (mol) \(\rightarrow Ca_3\left(PO_4\right)_2=\) 0,6.310 = 186 (g)
nAl2(SO4)3= 1,4-x = 0,8 (mol) \(\rightarrow^mAl_2\left(SO_4\right)_3\) = 0,8 . 342 = 273,6 (g)
\(Đặt:n_{hh}=1\left(mol\right)\)
\(n_{NO_2}=a\left(mol\right),n_{NO}=b\left(mol\right)\)
\(\Leftrightarrow a+b=1\left(1\right)\)
\(\overline{M}=\dfrac{46a+30b}{a+b}=18.2\cdot2=36.4\)
\(\Leftrightarrow46a+30b=36.4\left(2\right)\)
\(\left(1\right),\left(2\right):a=0.4,b=0.6\)
Tới đây tự tính tiếp nhé !!
Ta có: \(\overline{M}_{hh}=18,2\cdot2=36,4\left(đvC\right)\)
Theo sơ đồ đường chéo: \(\dfrac{n_{NO_2}}{n_{NO}}=\dfrac{6,4}{9,6}=\dfrac{2}{3}\)
\(\Rightarrow\left\{{}\begin{matrix}\%V_{NO_2}=\dfrac{2}{5}\cdot100\%=40\%\\\%V_{NO}=60\%\end{matrix}\right.\)
Giả sử \(n_{NO_2}=2\left(mol\right)\) \(\Rightarrow n_{NO}=3\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{NO_2}=\dfrac{2\cdot46}{2\cdot46+3\cdot30}\cdot100\%\approx50,55\%\\\%m_{NO}=49,45\%\end{matrix}\right.\)
a) Gọi nO2 =a (mol); nO3 = b(mol)
Có: \(\dfrac{32a+48b}{a+b}=20.2=40\)
=> 32a + 48b = 40a + 40b
=> 8a = 8b => a = b
=> \(\left\{{}\begin{matrix}\%V_{O_2}=\dfrac{a}{a+b}.100\%=\dfrac{a}{a+a}.100\%=50\%\\\%V_{O_3}=100\%-50\%=50\%\end{matrix}\right.\)
b) Gọi nN2 =a (mol); nNO = b(mol)
Có: \(\dfrac{28a+30b}{a+b}=14,75.2=29,5\)
=> 28a + 30b = 29,5a + 29,5b
=> 1,5a = 0,5b
=> 3a = b
=> \(\left\{{}\begin{matrix}\%V_{N_2}=\dfrac{a}{a+b}.100\%=\dfrac{a}{a+3a}.100\%=25\%\\\%V_{NO}=100\%-25\%=75\%\end{matrix}\right.\)