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\(a) CuO + H_2 \xrightarrow{t^o} Cu + H_2O\\ Fe_2O_3 + 3H_2 \xrightarrow{t^o} 2Fe + 3H_2O\\ b) n_{CuO} = \dfrac{32.25\%}{80} = 0,1(mol)\\ n_{Fe_2O_3} = \dfrac{32-0,1.80}{160} = 0,15(mol)\\ n_{Cu} = n_{CuO} = 0,1(mol) \Rightarrow m_{Cu} = 0,1.64 = 6,4(gam)\\ n_{Fe} = 2n_{Fe_2O_3} = 0,3(mol) \Rightarrow m_{Fe} = 0,3.56 = 16,8(gam)\)
Bài 11:
\(a,n_{Fe_2O_3}=\dfrac{1,6}{160}=0,01\left(mol\right)\\ n_{Cu}=\dfrac{4}{80}=0,05\left(mol\right)\\ PTHH:\\ Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
0,01 -----> 0,03 ---> 0,02
\(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
0,05 ---> 0,05 -> 0,05
\(b,m_{Fe}=0,02.56=1,12\left(g\right)\\ m_{Cu}=0,05.64=3,2\left(g\right)\\ V_{H_2}=\left(0,03+0,05\right).22,4=1,792\left(l\right)\)
Bài 12:
\(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\\ n_{O\left(trong.oxit\right)}=n_{H_2}=0,15\left(mol\right)\\ n_{Fe\left(trong.oxit\right)}=\dfrac{8-0,15,16}{56}=0,1\left(mol\right)\\ CTHH:Fe_xO_y\\ \Rightarrow x:y=0,1:0,15=2:3\\ CTHH:Fe_2O_3\)
\(Fe_2O_3+3H_2\rightarrow\left(t^o\right)2Fe+3H_2O\\ CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\\ Đặt:n_{Fe}=a\left(mol\right);n_{Cu}=0,5a\left(mol\right)\\ m_{hhB}=17,6\\ \Leftrightarrow56a+64.0,5a=17,6\\ \Leftrightarrow a=0,2\left(mol\right)\\ \Rightarrow n_{Fe}=0,2\left(mol\right);n_{Cu}=0,1\left(mol\right)\\ a,n_{H_2}=\dfrac{3}{2}.n_{Fe}+n_{Cu}=\dfrac{3}{2}.0,2+0,1=0,4\left(mol\right)\\ \Rightarrow V_{H_2\left(đktc\right)}=0,4.22,4=8,96\left(l\right)\\ b,Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\\ Vì:\dfrac{0,2}{1}< \dfrac{0,5}{2}\Rightarrow HCldư\\ \Rightarrow ddC:FeCl_2,HCldư\\ n_{FeCl_2}=n_{Fe}=0,2\left(mol\right)\Rightarrow m_{FeCl_2}=0,2.127=25,4\left(g\right)\\ n_{HCl\left(dư\right)}=0,5-0,2.2=0,1\left(mol\right)\)
\(\Rightarrow m_{HCl\left(dư\right)}=0,1.36,5=3,65\left(g\right)\)
a)
CuO + H2 --to--> Cu + H2O
Fe2O3 + 3H2 --to--> 2Fe + 3H2O
b) \(n_{Fe_2O_3}=\dfrac{32.20\%}{160}=0,04\left(mol\right)\)
\(n_{CuO}=\dfrac{32-0,04.160}{80}=0,32\left(mol\right)\)
PTHH: CuO + H2 --to--> Cu + H2O
0,32-->0,32---->0,32
Fe2O3 + 3H2 --to--> 2Fe + 3H2O
0,04-->0,12-------->0,08
=> VH2 = (0,32 + 0,12).22,4 = 9,856 (l)
c)
mCu = 0,32.64 = 20,48 (g)
mFe = 0,08.56 = 4,48 (g)
\(n_{CuO}=2a\left(mol\right)\Rightarrow n_{Fe_2O_3}=a\left(mol\right)\)
\(m_X=80\cdot2a+160a=80\left(g\right)\)
\(\Rightarrow a=0.25\left(mol\right)\)
\(CuO+H_2\underrightarrow{^{^{t^0}}}Cu+H_2O\)
\(Fe_2O_3+3H_2\underrightarrow{^{^{t^0}}}2Fe+3H_2O\)
\(n_{H_2}=0.5+0.25\cdot3=1.25\left(mol\right)\)
\(V_{H_2}=1.25\cdot22.4=28\left(l\right)\)
\(m_{cr}=0.5\cdot64+0.5\cdot56=60\left(g\right)\)
\(n_{Fe_2O_3}=\dfrac{3,2}{160}=0,02mol\)
\(n_{Cu}=\dfrac{8}{80}=0,1mol\)
\(Fe_2O_3+3H_2\rightarrow\left(t^o\right)2Fe+3H_2O\)
0,02 0,06 0,04 ( mol )
\(CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\)
0,1 0,1 0,1 ( mol )
\(m_{Fe}=0,04.56=2,24g\)
\(m_{Cu}=0,1.64=6,4g\)
\(n_{H_2}=0,06+0,1=0,16mol\)
\(n_{Fe_2O_3}=\dfrac{3,2}{160}=0,02mol\)
\(m_{CuO}=\dfrac{8}{80}=0,1mol\)
\(Fe_2O_3+3H_2\rightarrow2Fe+3H_2O\)
\(CuO+H_2\rightarrow Cu+H_2O\)
\(m_{Fe}=0,02\cdot2\cdot56=2,24g\)
\(m_{Cu}=0,1\cdot64=6,4g\)
\(\Sigma n_{H_2}=0,02\cdot3+0,1=0,16mol\Rightarrow V_{H_2}=3,584l\)
a)
\(m_{CuO}=\dfrac{32.40}{100}=12,8\left(g\right)\) => \(n_{CuO}=\dfrac{12,8}{80}=0,16\left(mol\right)\)
\(n_{Fe_2O_3}=\dfrac{32-12,8}{160}=0,12\left(mol\right)\)
PTHH: CuO + H2 --to--> Cu + H2O
0,16->0,16---->0,16
Fe2O3 + 3H2 --to--> 2Fe + 3H2O
0,12-->0,36----->0,24
=> \(V_{H_2}=\left(0,16+0,36\right).22,4=11,648\left(l\right)\)
b)
mCu = 0,16.64 =10,24 (g)
mFe = 0,24.56 = 13,44 (g)
c)
\(n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\)
PTHH: Fe + 2HCl --> FeCl2 + H2
Xét tỉ lệ: \(\dfrac{0,24}{1}< \dfrac{0,5}{2}\) => HCl dư, Fe hết
PTHH: Fe + 2HCl --> FeCl2 + H2
0,24------------------->0,24
=> \(V_{H_2}=0,24.22,4=5,376\left(l\right)\)
Đáp án:
8,96 l
Giải thích các bước giải:
a)
Fe2O3+3H2->2Fe+3H2O
CuO+H2->Cu+H2O
gọi a là số mol Fe2O3 b là số mol CuO
Ta có
160a=2x80b=>a=b
ta có
112a+64b=17,6
a=b
=>a=0,1 b=0,1
nH2=0,1x3+0,1=0,4(mol)
VH2=0,4x22,4=8,96 l
a) PTHH:
CuO + H\(_2\)\(\rightarrow\)(t\(^0\)) Cu + H\(_2\)O
Mol: 0, 05 : 0,05 \(\rightarrow\) 0,05: 0,05
Fe\(_2\)O\(_3\)+ 3H\(_2\)\(\rightarrow\)(t\(^0\)) 2Fe + 3H\(_2\)O
Mol: 0,1 : 0,3 \(\rightarrow\) 0,2: 0,3
b)Ta có: %m\(_{CuO}\)= 20%
=> m\(_{CuO}\)= 4 (g)
=> m\(_{Fe_2O_3}\) = m\(_{hh}\) - m\(_{CuO}\) = 20 - 4 = 16(g)
Ta lại có: n\(_{CuO}\) = 4 : 80 = 0,05 (mol)
n\(_{Fe_2O_3}\)= 16: 160= 0,1(mol)
V\(_{H_2}\)= (0,05+0,3).22,4= 7,84(l)