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\(n_{CuO\ pư} = a ; n_{CuO\ dư} = b\\ \Rightarrow 80a + 80b = 20(1)\\ CuO + H_2 \xrightarrow{t^o} Cu + H_2O\\ n_{Cu} = n_{CuO\ pư} = a(mol)\\ \Rightarrow m_{chất\ rắn} = 64a + 80b = 16,8(2)\\ (1)(2) \Rightarrow a = 0,2 ; b = 0,05\\ \Rightarrow H = \dfrac{0,2.80}{20}.100\% = 80\%\)
Ta có :
\(n_{Cu}=\frac{3,2}{64}=0,05\left(mol\right)\)
Theo PT:
\(\Rightarrow n_{Cu}=n_{H2}=0,05\left(mol\right)\)
\(\Rightarrow V_{H2}=0,05.22,4=1,12\left(l\right)\)
a)\(CuO+H2-->Cu+H2O\)
b) \(n_{Cu}=\frac{3,2}{64}=0,05\left(mol\right)\)
\(n_{H2}=n_{Cu}=0,05\left(mol\right)\)
\(VH2=0,05.22,4=1,12\left(l\right)\)
\(n_{H2O}=n_{Cu}=0,05\left(mol\right)\)
\(m_{H2O}=0,05.18=0,9\left(g\right)\)
\(n_{H_2}=\dfrac{4,032}{22,4}=0,18\left(mol\right)\)
PTHH: Fe + H2SO4 ---> FeSO4 + H2
0,18 <------------------------ 0,18
\(\rightarrow n_O=\dfrac{13,92-0,18.56}{16}=0,24\left(mol\right)\)
CTHH: FexOy
=> x : y = 0,18 : 0,24 = 3 : 4
CTHH Fe3O4
PT: \(CuO+H_2\rightarrow Cu+H_2O\)
Gọi \(n_{H_2}=x\left(mol\right)\)
Theo PT: \(n_{H_2O}=n_{H_2}=x\left(mol\right)\)
Theo ĐLBT KL, có: mCuO + mH2 = m chất rắn + mH2O
⇒ 12 + 2x = 10,4 + 18x ⇒ x = 0,1 (mol)
a, \(V_{H_2}=0,1.22,4=2,24\left(l\right)\)
b, \(m_{H_2O}=0,1.18=1,8\left(g\right)\)
\(V_{H_2\left(đktc\right)}=\dfrac{4,032}{22,4}=0,18\left(mol\right)\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\uparrow\)
1 : 1 (mol)
0,18 : 0,18 (mol)
\(yCO+Fe_xO_y\rightarrow^{t^0}xFe+yCO_2\uparrow\)
1 : x (mol)
\(\dfrac{0,18}{x}\) 0,18 (mol)
\(M_{Fe_xO_y}=\dfrac{m}{n}=\dfrac{13,92}{\dfrac{0,18}{x}}=\dfrac{232}{3}x\)
\(\Rightarrow56x+16y=\dfrac{232}{3}x\)
\(\Rightarrow16y=\dfrac{64}{3}x\)
\(\Rightarrow\dfrac{x}{y}=\dfrac{16}{\dfrac{64}{3}}=\dfrac{3}{4}\Rightarrow x=3;y=4\)
-Vậy CTHH của oxit sắt là Fe3O4
\(n_{Fe_2O_3}=\dfrac{m}{M}=\dfrac{3,2}{160}=0,02mol\)
\(Fe_2O_3+3H_2\rightarrow\left(t^o\right)2Fe+3H_2O\)
0,02 0,06 0,04 ( mol )
\(V_{H_2}=n.22,4=0,06.22,4=1,334l\)
\(m_{Fe}=n.M=0,04.56=2,24g\)
nFe2O3 = 3,2/160 = 0,02 (mol)
PTHH: Fe2O3 + 3H2 -> (t°) 2Fe + 3H2O
Mol: 0,02 ---> 0,06 ---> 0,04
VH2 = 0,06 . 22,4 = 1,344 (l)
mFe = 0,04 . 56 = 2,24 (g)
CuO+H2-to>Cu+H2O
0,09----0,09---0,09
n CuO=\(\dfrac{7,2}{80}\)=0,09 mol
=>m Cu=0,09.64=5,76g
=>VH2=0,09.22,4=2,016l
\(n_{CuO}=\dfrac{7,2}{80}=0,09mol\)
\(CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\)
0,09 0,09 0,09 ( mol )
\(m_{Cu}=0,09.64=5,76g\)
\(V_{H_2}=0,09.22,4=2,016l\)
PT: CuO + H2 ---> Cu + H2O
a. Ta có: \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
Theo PT: nCu = \(n_{H_2}=0,3\left(mol\right)\)
=> mCu = 0,3 . 64 = 19,2(g)
Theo PT: \(n_{H_2O}=n_{Cu}=0,3\left(mol\right)\)
=> \(m_{H_2O}=0,3.18=5,4\left(g\right)\)
b. Theo PT: nCuO = nCu = 0,3(mol)
=> mCuO = 0,3 . 80 = 24(g)
a)PTHH: CuO+H2=>Cu+H2O
b) nCu=0,05g
PTHH: CuO+H2=>Cu+H2O
0,05<-0,05<-0,05->0,05
=> VH2 =0,05.22,4=1,12 lit