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\(a,2Al+3H_2SO_4\to Al_2(SO_4)_3+3H_2\\ b,n_{H_2}=\dfrac{6,72}{22,4}=0,3(mol)\\ \Rightarrow n_{Al}=0,2(mol)\\ \Rightarrow m_{Al}=0,2.27=5,4(g)\\ c,n_{H_2SO_4}=0,3(mol)\\ \Rightarrow m_{dd_{H_2SO_4}}=\dfrac{0,3.98}{9,8\%}=300(g)\\ d,n_{Al_2(SO_4)_3}=0,1(mol)\\ \Rightarrow C\%_{Al_2(SO_4)_3}=\dfrac{0,1.342}{5,4+300-0,3.2}.100\%=11,22\%\)
a)
$n_{Al} = 0,3(mol)$
$2Al + 3H_2SO_4 \to Al_2(SO_4)_3 + 3H_2$
Theo PTHH :
$n_{H_2SO_4} = \dfrac{3}{2}n_{Al} = 0,45(mol)$
$m_{dd\ H_2SO_4} = \dfrac{0,45.98}{12,25\%} = 360(gam)$
b)
$n_{H_2} = n_{H_2SO_4} = 0,45(mol)$
$V_{H_2} = 0,45.22,4 = 10,08(lít)$
c)
$n_{Al_2(SO_4)_3} = 0,15(mol)$
$m_{dd\ sau\ pư} = 8,1 + 360 - 0,45.2 = 367,2(gam)$
$C\%_{Al_2(SO_4)_3} = \dfrac{0,15.342}{367,2}.100\% = 14\%$
Đổi: 672 ml = 0,672 l
CaSO4 + H2SO4 → X
Na2CO3 + H2SO4 → Na2SO4 + CO2 + H2O (1)
\(n_{CO_2}=\dfrac{0,672}{22,4}=0,03\left(mol\right)\)
a) Theo PT1: \(n_{H_2SO_4}=n_{CO_2}=0,03\left(mol\right)\)
\(\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,03}{0,2}=0,15\left(M\right)\)
b) Theo PT: \(n_{Na_2SO_4}=n_{CO_2}=0,03\left(mol\right)\)
\(\Rightarrow m_{Na_2SO_4}=0,03\times142=4,26\left(g\right)\)
c) Theo PT1: \(n_{Na_2CO_3}=n_{CO_2}=0,03\left(mol\right)\)
\(\Rightarrow m_{Na_2CO_3}=0,03\times106=3,18\left(g\right)\)
\(\Rightarrow m_{CaSO_4}=5-3,18=1,82\left(g\right)\)
\(\Rightarrow\%m_{Na_2CO_3}=\dfrac{3,18}{5}\times100\%=63,6\%\)
\(\Rightarrow\%m_{CaSO_4}=100\%-63,6\%=36,4\%\)
a, \(Na_2SO_3+H_2SO_4\rightarrow Na_2SO_4+SO_2+H_2O\)
\(K_2SO_3+H_2SO_4\rightarrow K_2SO_4+SO_2+H_2O\)
Ta có: \(n_{SO_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
Theo PT: \(n_{H_2SO_4}=n_{SO_2}=0,3\left(mol\right)\)
\(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,3.98}{20\%}=147\left(g\right)\)
b, Ta có: 126nNa2SO3 + 158nK2SO3 = 44,2 (1)
Theo PT: \(n_{SO_2}=n_{Na_2SO_3}+n_{K_2SO_3}=0,3\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{Na_2SO_3}=0,1\left(mol\right)\\n_{K_2SO_3}=0,2\left(mol\right)\end{matrix}\right.\)
Có: m dd sau pư = 44,2 + 147 - 0,3.64 = 172 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{Na_2SO_3}=\dfrac{0,1.126}{172}.100\%\approx7,33\%\\C\%_{K_2SO_3}=\dfrac{0,2.158}{172}.100\%\approx18,37\%\end{matrix}\right.\)
c, \(n_{Ba\left(OH\right)_2}=0,5.1=0,5\left(mol\right)\)
\(\Rightarrow\dfrac{n_{SO_2}}{n_{Ba\left(OH\right)_2}}=0,6< 1\) → Pư tạo BaSO3.
PT: \(SO_2+Ba\left(OH\right)_2\rightarrow BaSO_3+H_2O\)
\(n_{BaSO_3}=n_{SO_2}=0,3\left(mol\right)\Rightarrow m_{BaSO_3}=0,3.217=65,1\left(g\right)\)
a)\(PTHH:Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
\(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)
\(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
\(n_{H_2}=\frac{2,688}{22,4}=0,12\left(mol\right)\)
\(n_{SO^{ }_4}=\frac{1}{2}n_{H_2}=0,06\left(mol\right)\)
\(m_{muối}=m_{KL}+m_{SO_4}=6,44+0,06.96=12,2\left(g\right)\)
b) \(n_{H_2SO_4}=n_{H_2}=0,12\left(mol\right)\)
\(m_{ddH_2SO_4}=\frac{0,12.98}{9,8\%}=120\left(g\right)\)
a) \(n_{Zn}=\frac{m}{M}=\frac{13}{65}=0,2\left(mol\right)\)
Phương trình hóa học phản ứng
Zn + H2SO4 ---> ZnSO4 + H2
1 : 1 : 1 : 1
0.2 0,2 0,2
mol mol mol
=> \(V_{H_2}=n.22,4=0,2.22,4=4,48\left(l\right)\)
b) \(m_{ZnSO_4}=n.M=0,2.161=32,2\left(g\right)\)
c) Ta có \(C\%=\frac{m_{ct}}{m_{dd}}.100\%=24,5\%\)
=> \(m_{ct}=\frac{C\%.m_{dd}}{100\%}=\frac{24,5\%.200}{100\%}=49\left(g\right)=m_{H_2SO_4}\)
=> \(m_{H_2O}=151\left(g\right)\)
=> \(n_{H_2SO_4}=\frac{m}{M}=\frac{49}{98}=0,5\)(mol)
Dễ thấy \(\frac{n_{Zn}}{1}< \frac{n_{H_2SO_4}}{1}\)
=> H2SO4 dư 0,5 - 0,2 = 0,3 (mol)
=> \(m_{H_2SO_4\text{ dư }}=n.M=0,3.98=29,4\left(g\right)\); \(m_{H_2SO4\text{ tham gia}}=n.M=0,2.98=19,6\)(g)
Áp dụng đinhk luật bảo toàn khối lượng
=> \(m_{H_2SO_4}+m_{Zn}=m_{ZnSO4}+m_{H_2}\)
=> \(m_{H_2}=m_{H_2SO_4}+m_{Zn}-m_{ZnSO_4}=19,6+13-32,2=0,4\left(g\right)\)
=> \(m_{saupư}=m_{ZnSO_4}+m_{H_2SO_4\text{ dư}}+m_{H_2O}-m_{H_2}=32,2+29,4+151-0,4=232,2\left(g\right)\)
=> \(C\%_{H_2SO_4}=\frac{m_{ct}}{m_{sau\text{ pư}}}.100\%=\frac{29,4}{232,2}.100\%=12,66\%\)
\(C\%_{ZnSO_4}=\frac{m_{ct}}{m_{dd}}.100\%=\frac{32,2}{232,2}.100\%=13,87\%\)
Chỉ có Zn phản ứng thôi. Cu không phản ứng, không tan.---->Chất rắn không tan là Cu
Zn+ H2SO4 ---> ZnSO4+ H2↑
0.1 0.1
nH2= 2.24: 22.4=0.1 mol
mZn= 0.1x65=6.5 g
mCu=10.5-6,5=4 g
%Zn=6.5:10.5x100%=61.9%
%Cu=4:10.5x100%=38.1%
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