Hãy nhập câu hỏi của bạn vào đây, nếu là tài khoản VIP, bạn sẽ được ưu tiên trả lời.
Gọi số mol Al, Mg là a, b (mol)
\(n_{H_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
a--------------->a------>1,5a
Mg + 2HCl --> MgCl2 + H2
b--------------->b---->b
=> \(\left\{{}\begin{matrix}1,5a+b=0,6\\133,5a+95b=55,2\end{matrix}\right.\)
=> a = 0,2 (mol); b = 0,3 (mol)
\(\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,2.27}{0,2.27+0,3.24}.100\%=42,857\%\\\%m_{Mg}=\dfrac{0,3.24}{0,2.27+0,3.24}.100\%=57,143\%\end{matrix}\right.\)
\(\left\{{}\begin{matrix}Al\\Mg\end{matrix}\right.+HCl->\left\{{}\begin{matrix}AlCl3\\MgCl2\end{matrix}\right.+H2\)
2Al + 3HCl -> 2AlCl3 + 3H2
0,2 0,3 0,3
Mg + 2HCl -> MgCl2 + H2
0,3 0,6 0,3
=> mHCl dùng = 0,9 . 36,5 = 32,85 (g)
=> mH2 = 0,6 . 2 = 1,2 (g)
Bảo toàn khối lượng :
=> mX = 55,2 + 1,2 - 32,85 = 23,55 (g)
Ta có :
\(\left\{{}\begin{matrix}3x+2y=1,2\left(bt-e\right)\\133,5x+95y=55,2\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,2\left(mol\right)\\y=0,3\left(mol\right)\end{matrix}\right.\)
\(\left\{{}\begin{matrix}\%mAl=\dfrac{0,2.27}{0,2.27+0,3.24}=42,85\%\\\%mMg=100\%-42,85\%=57,15\%\end{matrix}\right.\)
Gọi \(\left\{{}\begin{matrix}n_{Zn}=a\left(mol\right)\\n_{Fe}=b\left(mol\right)\\n_{Al}=c\left(mol\right)\end{matrix}\right.\) => 65a + 56b + 27c = 10,65 (1)
PTHH: Zn + 2HCl --> ZnCl2 + H2
Fe + 2HCl --> FeCl2 + H2
2Al + 6HCl --> 2AlCl3 + 3H2
=> \(n_{H_2}=a+b+1,5c=\dfrac{5,04}{22,4}=0,225\left(mol\right)\) (2)
PTHH: Zn + Cl2 --to--> ZnCl2
2Fe + 3Cl2 --to--> 2FeCl3
2Al + 3Cl2 --to--> 2AlCl3
=> \(n_{Cl_2}=a+1,5b+1,5c=\dfrac{5,6}{22,4}=0,25\left(mol\right)\) (3)
(1)(2)(3) => \(\left\{{}\begin{matrix}a=0,1\left(mol\right)\\b=0,05\left(mol\right)\\c=0,05\left(mol\right)\end{matrix}\right.\) => \(\left\{{}\begin{matrix}m_{Zn}=0,1.65=6,5\left(g\right)\\m_{Fe}=0,05.56=2,8\left(g\right)\\m_{Al}=0,05.27=1,35\left(g\right)\end{matrix}\right.\)
a) \(\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{6,5}{10,65}.100\%=61,033\%\\\%m_{Fe}=\dfrac{2,8}{10,65}.100\%=26,291\%\\\%m_{Al}=\dfrac{1,35}{10,65}.100\%=12,676\%\end{matrix}\right.\)
b) nHCl = 2a + 2b + 3c = 0,45 (mol)
=> mHCl = 0,45.36,5 = 16,425 (g)
=> \(a\%=C\%=\dfrac{16,425}{200}.100\%=8,2125\%\)
c) mdd sau pư = 10,65 + 200 - 0,225.2 = 210,2 (g)
=> \(\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,1.136}{210,2}.100\%=6,47\%\\C\%_{FeCl_2}=\dfrac{0,05.127}{210,2}.100\%=3,02\%\\C\%_{AlCl_3}=\dfrac{0,05.133,5}{210,2}.100\%=3,176\%\end{matrix}\right.\)
`2Fe + 6H_2 SO_[4(đ,n)] -> Fe_2(SO_4)_3 + 3SO_2 \uparrow + 6H_2 O`
`0,05` `0,15` `0,025` `(mol)`
`Cu + 2H_2 SO_[4(đ,n)] -> CuSO_4 + SO_2 \uparrow + 2H_2 O`
`0,225` `0,45` `0,225` `(mol)`
`n_[SO_2]=[6,72]/[22,4]=0,3(mol)`
Gọi `n_[Fe]=x` ; `n_[Cu]=y`
`=>` $\begin{cases} \dfrac{3}{2}x+y=0,3\\56x+64y=17,2 \end{cases}$
`<=>` $\begin{cases}x=0,05\\y=0,225 \end{cases}$
`@m_[Fe_2(SO_4)_3]=0,025.400=10(g)`
`@m_[CuSO_4]=0,225.160=36(g)`
`@m_[dd H_2 SO_4]=[(0,15+0,45).98]/80 .100=73,5(g)`
Sửa đề: 80% ---> 98% (80% chưa đặc nên không giải phóng SO2 được)
Gọi \(\left\{{}\begin{matrix}n_{Fe}=a\left(mol\right)\\n_{Cu}=b\left(mol\right)\end{matrix}\right.\)
\(\rightarrow56a+64b=17,2\left(1\right)\)
PTHH:
\(2Fe+6H_2SO_{4\left(đặc,nóng\right)}\rightarrow Fe_2\left(SO_4\right)_3+3SO_2\uparrow+6H_2O\)
a------>3a------------------->0,5a--------------->1,5a
\(Cu+2H_2SO_{4\left(đặc,nóng\right)}\rightarrow CuSO_4+SO_2\uparrow+2H_2O\)
b----->2b------------------->b------------->b
\(\rightarrow1,5a+b=\dfrac{6,72}{22,4}=0,3\left(2\right)\)
Từ \(\left(1\right)\left(2\right)\rightarrow\left\{{}\begin{matrix}a=0,05\left(mol\right)\\b=0,225\left(mol\right)\end{matrix}\right.\)
\(\rightarrow\left\{{}\begin{matrix}m_{Fe_2\left(SO_4\right)_3}=0,5.0,05.400=10\left(g\right)\\m_{CuSO_4}=0,225.160=36\left(g\right)\\m_{ddH_2SO_4}=\dfrac{\left(0,05.3+0,225.2\right).98}{98\%}=60\left(g\right)\end{matrix}\right.\)
Câu 1 :
\(n_{H2}=\dfrac{5,04}{22,4}=0,225\left(mol\right)\)
Pt : \(2Al+6HCl\rightarrow2AlCl_3+3H_2|\)
2 6 2 3
a 0,15 1,5a
\(Zn+2HCl\rightarrow ZnCl_2+H_2|\)
1 2 1 1
b 0,3 1b
a) Gọi a là số mol của Al
b là số mol của Zn
\(m_{Al}+m_{Zn}=11,1\left(g\right)\)
⇒ \(n_{Al}.M_{Al}+n_{Zn}.M_{Zn}=11,1g\)
⇒ 27a + 65b = 11,1g(1)
Theo phương trình : 1,5a + 1b = 0,225(2)
Từ(1),(2), ta có hệ phương trình :
27a + 65b = 11,1g
1,5a + 1b = 0,225
⇒ \(\left\{{}\begin{matrix}a=0,05\\b=0,15\end{matrix}\right.\)
\(m_{Al}=0,05.27=1,35\left(g\right)\)
\(m_{Zn}=0,15.65=9,75\left(g\right)\)
0/0Al = \(\dfrac{1,35.100}{11,1}=12,16\)0/0
0/0Zn = \(\dfrac{9,75.100}{11,1}=87,84\)0/0
b) \(n_{HCl\left(tổng\right)}=0,15+0,3=0,45\left(mol\right)\)
\(V_{ddHCl}=\dfrac{0,45}{1}=0,45\left(l\right)\)
Chúc bạn học tốt
Câu 2 :
\(n_{H2}=\dfrac{1,456}{22,4}=0,065\left(mol\right)\)
Pt : \(Fe+2HCl\rightarrow FeCl_2+H_2|\)
1 2 1 1
a 0,1 1a
\(2Al+6HCl\rightarrow2AlCl_3+3H_2|\)
2 6 2 3
b 0,03 1,5b
a) Gọi a là số mol của Fe
b là số mol của Al
\(m_{Fe}+m_{Al}=3,07\left(g\right)\)
⇒ \(n_{Fe}.M_{Fe}+n_{Al}.M_{Al}=3,07g\)
⇒ 56a + 27b = 3,07g(1)
Theo phương trình : 1a + 1,5b = 0,065(2)
Từ(1),(2),ta có hệ phương trình :
56a + 27b = 3,07g
1a + 1,5b = 0,065
⇒ \(\left\{{}\begin{matrix}a=0,05\\b=0,01\end{matrix}\right.\)
\(m_{Fe}=0,05.56=2,8\left(g\right)\)
\(m_{Al}=0,01.27=0,27\left(g\right)\)
0/0Fe = \(\dfrac{2,8.100}{3,07}=91,21\)0/0
0/0Al = \(\dfrac{0,27.100}{3,07}=8,79\)0/0
b) \(n_{HCl\left(tổng\right)}=0,1+0,03=0,13\left(mol\right)\)
\(m_{HCl}=0,13.36,5=4,745\left(g\right)\)
\(m_{ddHCl}=\dfrac{4,745.100}{10}=47.45\left(g\right)\)
Chúc bạn học tốt
Chọn A
Ta có: m h h = 9 , 2 g → 27a + 65b = 9,2 (*)
Bảo toàn số mol electron có: 3a + 2b = 0,5 (**)
Giải (*), (**): a = b = 0,1 mol.
m A l = 0 , 1 . 27 = 2 , 7 g a m
\(a)\\ Zn + 2HCl \to ZnCl_2 + H_2\\ 2Al + 6HCl \to 2AlCl_3 + 3H_2\)
\(b)\ n_{Zn} = a\ mol\ ;\ n_{Al} = b\ mol\\ \Rightarrow65a + 27b = 6,6(1)\\ n_{H_2} = a + 1,5b = \dfrac{4,704}{22,4} = 0,21(2)\\ (1)(2)\Rightarrow a = 0,06 ; b = 0,1\\ \Rightarrow m_{Zn} = 0,06.65 = 3,9\ gam\ ;\ m_{Al} = 0,1.27 = 2,7\ gam\)
\(n_{Zn}=a\left(mol\right),n_{Al}=b\left(mol\right)\)
\(m_X=65a+27b=6.6\left(g\right)\left(1\right)\)
\(n_{H_2}=\dfrac{4.704}{22.4}=0.21\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(\Rightarrow a+1.5b=0.21\left(2\right)\)
\(\left(1\right),\left(2\right):\)
\(a=0.06\)
\(b=0.1\)
\(m_{Zn}=0.06\cdot65=3.9\left(g\right)\)
\(m_{Al}=0.1\cdot27=2.7\left(g\right)\)