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\(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,1 0,4
0,1 0,2
0 0,2 0,1 0,1
\(a,V_{H_2}=0,1.22,4=2,24\left(l\right)\\ b,m_{dd}=6,5+0,4.36,5+50-0,1.2=70,9\left(g\right)\\ C\%_{ZnCl_2}=\dfrac{0,1.136}{70,9}.100\%=19,18\%\)
\(n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)\)
\(m_{HCl}=\dfrac{150.18,25}{100}=27,375\left(g\right)\)
\(n_{HCl}=\dfrac{27,375}{36,5}=0,75\left(mol\right)\)
PTHH :
\(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
trc p/u : 0,3 0,75
p/u: 0,3 0,6 0,3 0,3
sau p/u : 0 0,15 0,3 0,3
---> Sau p/ư HCl dư
\(a,V_{H_2}=0,3.22,4=6,72\left(l\right)\)
\(b,m_{ddHCl}=0,6.36,5=21,9\left(g\right)\)
\(c,m_{ZnCl_2}=0,3.136=40,8\left(g\right)\)
\(m_{ddZnCl_2}=19,5+150-\left(0,3.2\right)=168,9\left(g\right)\)
\(C\%=\dfrac{40,8}{168,9}.100\%\approx24,16\%\)
a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
b, \(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
\(m_{HCl}=100.14,6\%=14,6\left(g\right)\Rightarrow n_{HCl}=\dfrac{14,6}{36,5}=0,4\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,1}{1}< \dfrac{0,4}{2}\), ta được HCl dư.
Theo PT: \(n_{H_2}=n_{Zn}=0,1\left(mol\right)\Rightarrow V_{H_2}=0,1.22,4=2,24\left(l\right)\)
b, Theo PT: \(\left\{{}\begin{matrix}n_{HCl\left(pư\right)}=2n_{Zn}=0,2\left(mol\right)\\n_{ZnCl_2}=n_{Zn}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{HCl\left(dư\right)}=0,4-0,2=0,2\left(mol\right)\)
Ta có: m dd sau pư = 6,5 + 100 - 0,1.2 = 106,3 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,1.136}{106,3}.100\%\approx12,79\%\\C\%_{HCl\left(dư\right)}=\dfrac{0,2.36,5}{106,3}.100\%\approx6,87\%\end{matrix}\right.\)
a. \(Mg+2HCl\rightarrow MgCl_2+H_2\)
b. \(n_{Mg}=\dfrac{2.4}{24}=0.1mol\)
\(mct_{HCl}=\dfrac{500\times36.5}{100}=182.5g\Rightarrow n_{HCl}=\dfrac{182.5}{36.5}=5mol\)
Ta có: \(\dfrac{0.1}{1}< \dfrac{5}{2}\Rightarrow\) HCl dư
nHCl phản ứng = 0.2 mol => nHCl dư = 5 - 0.2 = 4.8 mol
mHCl dư = \(4.8\times36.5=175.2g\)
c. \(V_{H_2}=0.1\times22.4=2.24l\)
d. mdd sau phản ứng = \(2.4+500-0.1\times2=502.2g\)
\(C\%_{MgCl_2}=\dfrac{0.1\times95\times100}{502.2}=1.89\%\)
\(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\\
n_{H_2SO_4}=\dfrac{24,5}{98}=0,25\left(mol\right)\\
pthh:Fe+H_2SO_4\rightarrow FeSO_4+H_2\uparrow\)
\(LTL:\dfrac{0,2}{1}< \dfrac{0,25}{1}\)
=> H2SO4 dư
\(n_{H_2}=n_{H_2SO_4\left(p\text{ư}\right)}=n_{Fe}=0,2\left(mol\right)\\
V_{H_2}=0,2.22,4=4,48l\\
m_{H_2SO_4\left(d\right)}=\left(0,25-0,2\right).98=4,9g\)
a)
$Fe + 2HCl \to FeCl_2 + H_2$
n H2 = n Fe = 11,2/56 = 0,2(mol)
V H2 = 0,2.22,4 = 4,48(lít)
b)
n HCl = 2n Fe = 0,2.2 = 0,4(mol)
=> CM HCl = 0,4/0,4 = 1M
c)
$CuO + H_2 \xrightarrow{t^o} Cu + H_2O$
Ta thấy :
n CuO = 64/80 = 0,8 > n H2 = 0,2 nên CuO dư
Theo PTHH :
n CuO pư = n Cu = n H2 = 0,2(mol)
n Cu dư = 0,8 - 0,2 = 0,6(mol)
Vậy :
%m Cu = 0,2.64/(0,2.64 + 0,6.80) .100% = 21,05%
%m CuO = 100% -21,05% = 78,95%
Mg+2HCl->MgCl2+H2
0,1---0,2-----0,1-----0,1
n Mg=0,1 mol
=>VH2=0,1.22,4=2,24l
C% HCl dư=\(\dfrac{0,2.36,5}{100}100\)=7,3%
=>C%MgCl2=\(\dfrac{0,1.95}{2,4+100-0,1.2}100=9,29\%\)
\(n_{Mg}=\dfrac{2,4}{24}=0,1mol\)
\(Mg+2HCl\rightarrow MgCl_2+H_2\)
0,1 < 0,4 ( mol )
0,1 0,2 0,1 0,1 ( mol )
\(V_{H_2}=0,1.22,4=2,24l\)
\(C\%_{HCl}=\dfrac{0,2.36,5}{100}.100\%=7,3\%\)
\(C\%_{MgCl_2}=\dfrac{0,1.95}{2,4+100-0,1.2}.100\%=9,29\%\)