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a)
$BaCl_2 + Na_2SO_4 \to BaSO_4 + 2NaCl$
$n_{BaCl_2} = 0,01 = n_{Na_2SO_4} = 0,01 \Rightarrow $ Vừa đủ
$n_{BaSO_4} = n_{Na_2SO_4} = 0,01(mol)$
$m_{BaSO_4} = 0,01.233 = 0,233(gam)$
b)
$n_{NaCl} = 2n_{Na_2SO_4} = 0,02(mol)$
$V_{dd} = 0,1 + 0,2 = 0,3(lít)$
$C_{M_{NaCl}} = \dfrac{0,02}{0,3} = 0,067M$
c)
$[Na^+] = [Cl^-] = C_{M_{NaCl}} = 0,067M$
\(n_{BaCl_2}=0.1\cdot0.1=0.01\left(mol\right)\)
\(n_{Na_2SO_4}=0.2\cdot0.05=0.01\left(mol\right)\)
\(BaCl_2+Na_2SO_4\rightarrow BaSO_4+2NaCl\)
\(0.01..........0.01............0.01..............0.02\)
\(m_{BaSO_4}=0.01\cdot233=2.33\left(g\right)\)
\(C_{M_{NaCl}}=\dfrac{0.01}{0.1+0.2}=0.03\left(M\right)\)
\(\left[Na^+\right]=\left[Cl^-\right]=0.03\left(M\right)\)
a) Ta có: \(n_{Al\left(NO_3\right)_3}=\dfrac{4,26}{213}=0,02\left(mol\right)\) \(\Rightarrow\left\{{}\begin{matrix}n_{Al^+}=0,02\left(mol\right)\\n_{NO_3^-}=0,06\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\left[Al^+\right]=\dfrac{0,02}{0,1}=0,2\left(M\right)\\\left[NO_3^-\right]=\dfrac{0,06}{0,1}=0,6\left(M\right)\end{matrix}\right.\)
b) Ta có: \(\left[Na^+\right]=0,1+0,02\cdot2+0,3=0,304\left(M\right)\)
c) Bạn xem lại đề !!
\(n_{Cl^-}=n_{KCl}+2n_{CaCl_2}=0,15.0,1+0,15.0,1.2=0,045\left(mol\right)\\ \Rightarrow\left[Cl^-\right]=\dfrac{0,045}{0,15}=0,3M\)
\(n_{NaCl}=0,1.0,2=0,02\left(mol\right)\)
\(m_{Na_2CO_3}=0,1.0,3=0,03\left(mol\right)\)
\(\left\{{}\begin{matrix}n_{Na^+}=0,02+0,03.2=0,08\left(mol\right)\\n_{Cl^-}=0,02\left(mol\right)\\n_{CO_3^{2-}}=0,03\left(mol\right)\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}C_{M\left(Na^+\right)}=\dfrac{0,08}{0,2+0,3}=0,16M\\C_{M\left(Cl^-\right)}=\dfrac{0,02}{0,2+0,3}=0,04M\\C_{M\left(CO_3^{2-}\right)}=\dfrac{0,03}{0,2+0,3}=0,06M\end{matrix}\right.\)
\(n_{Ba\left(OH\right)_2}=0,3.0,1=0,03\left(mol\right)\\ n_{HCl}=0,2.0,15=0,03\left(mol\right)\\ Ba\left(OH\right)_2+2HCl\rightarrow BaCl_2+2H_2O\\ Vì:\dfrac{n_{Ba\left(OH\right)_2\left(đề\right)}}{n_{Ba\left(OH\right)_2\left(PTHH\right)}}=\dfrac{0,03}{1}>\dfrac{n_{HCl\left(đề\right)}}{n_{HCl\left(PTHH\right)}}=\dfrac{0,03}{2}\\ \Rightarrow Ba\left(OH\right)_2dư\\ n_{Ba\left(OH\right)_2\left(p.ứ\right)}=\dfrac{n_{HCl}}{2}=\dfrac{0,03}{2}=0,015\\ n_{Ba\left(OH\right)_2\left(dư\right)}=0,03-0,015=0,015\left(mol\right)\\ \left[OH^-\right]=2.\left[Ba\left(OH\right)_2\left(dư\right)\right]=\dfrac{0,015}{0,3+0,2}=0,03\left(M\right)\\ \Rightarrow pH=14+log\left[OH^-\right]=14+log\left[0,03\right]\approx12,477\)
Nồng độ mol/lít các ion trong dd A:
\(\left[OH^-\left(dư\right)\right]=0,06\left(M\right)\left(nt\right)\\\left[Cl^-\right]=2.\left[BaCl_2\right]=2.\left(\dfrac{0,015}{0,5}\right)=0,06\left(M\right)\\ \left[Ba^{2+}\right]=0,03+ 0,03=0,06\left(M\right)\)
dd ba(no3)2 pli ra ba2+ và 2 no3- => [ba2+]=0,1,,[no3-]=0,2
dd hno3 pli ra h+ và no3- => [h+]=0,02.....[no3-]=0,02
al2(so4)3 pli ra 2 al3+ và 3 so42- => [al3+]=0,2 [so42-]=0,3
Cậu viết rõ ra dùm mình đc ko cách tính ra cái đó luôn á
nH+=0,04 mol nOH-=0,03 mol
H+ + OH- --------> H20
0,04 0,03
0,03 0,03 0,03
0,01
a/ [H+] du=0,01/0,2=0,05 M
[SO42-]=0,01/0,2=0,05 M
[K+]=0,01/0,2=0,05 M
[Ba2+]=0,01/0,2=0,05M
b/ nH+ du=0,01/0,2=0,05 M
pH=-log(0,05)=1,3
c/ khoi luong chat ran thu duoc sau phan ung la
mcr= mSO42- + mK+ + mBa2+
=0,01.96+0,01.39+0,01.137
=2,72g
ta có : \(\Sigma n_{H^+}=n_{HCl}+2n_{H_2SO_4}=0,04\left(mol\right)\)
\(\Sigma n_{OH^-}=n_{KOH}+2n_{Ba\left(OH\right)_2}=0,03\left(mol\right)\)
\(n_{SO_4^{2-}}=0,01\left(mol\right)\) ; \(n_{Ba^{2+}}=0,01\left(mol\right)\)
a, PT : \(H^++OH^-\rightarrow H_2O\)
0,03 0,03 0,03 (mol)
\(\Rightarrow n_{H^+}dư=0,01\left(mol\right)\)
đến đây tự tính đc nha. dùng ct \(CM=\dfrac{n}{V}\)
b, \(PH=-log[H^+]=-log\left(\dfrac{0,01}{0,2}\right)\simeq1,3\)
c, \(Ba^{2+}+SO_4^{2-}\rightarrow BaSO_4\downarrow\)
0,01 0,01 0,01 (mol)\(mcr=m\downarrow+m_{K^+}=m_{BaSO_4}+m_{K+}=\left(0,01\times233\right)+\left(0,01\times39\right)=2,72\left(g\right)\)
\(n_{NaCl}=0.1\cdot0.1=0.01\left(mol\right)\)
\(n_{AgNO_3}=0.15\cdot0.1=0.015\left(mol\right)\)
\(NaCl+AgNO_3\rightarrow NaNO_3+AgCl\)
\(0.01..........0.01...............0.01\)
Dung dịch : 0.01 (mol) NaNO3 , 0.005 (mol) AgNO3
\(\left[Na^+\right]=\dfrac{0.01}{0.1+0.15}=0.04\left(M\right)\)
\(\left[Ag^+\right]=\dfrac{0.005}{0.25}=0.02\left(M\right)\)
\(\left[NO_3^-\right]=\dfrac{0.01+0.005}{0.25}=0.06\left(M\right)\)