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\(n_{Fe_2O_3}=\dfrac{8}{160}=0,05\left(mol\right)\)
PTHH: Fe2O3 + 3H2SO4 --> Fe2(SO4)3 + 3H2O
______0,05------>0,15--------->0,05
=> mH2SO4 = 0,15.98 = 14,7(g)
=> \(C\%\left(H_2SO_4\right)=\dfrac{14,7}{100}.100\%=14,7\%\)
\(C\%\left(Fe_2\left(SO_4\right)_3\right)=\dfrac{0,05.400}{8+100}.100\%=18,52\%\)
PTHH: Fe2(SO4)3 + 6NaOH --> 2Fe(OH)3\(\downarrow\) + 3Na2SO4
________0,05----------------------->0,1
=> mFe(OH)3 = 0,1.107=10,7(g)
\(n_{H_2SO_4}=\dfrac{98.5\%}{98}=0,05\left(mol\right)\\ PTHH:CuO+H_2SO_4\rightarrow CuSO_4+H_2O\\ n_{CuSO_4}=n_{CuO}=n_{H_2SO_4}=0,05\left(mol\right)\\ a,m_{CuO}=0,05.80=4\left(g\right)\\ b,m_{CuSO_4}=0,05.160=8\left(g\right)\\ m_{ddCuSO_4}=98+4=102\left(g\right)\\ C\%_{ddCuSO_4}=\dfrac{8}{102}.100\approx7,843\%\)
1)
a, \(n_{Al}=\dfrac{15,3}{102}=0,15\left(mol\right)\)
PTHH: Al2O3 + 6HCl → 2AlCl3 + 3H2O
Mol: 0,15 0,9 0,3
\(m_{ddHCl}=\dfrac{0,9.36,5.100}{20}=164,25\left(g\right)\)
b, mdd sau pứ = 15,3 + 164,25 = 179,55 (g)
c, \(C\%_{ddAlCl_3}=\dfrac{0,3.133,5.100\%}{179,55}=22,31\%\)
2)
a, \(m_{HCl}=54,75.20\%=10,95\left(g\right)\Rightarrow n_{HCl}=\dfrac{10,95}{36,5}=0,3\left(mol\right)\)
PTHH: Al2O3 + 6HCl → 2AlCl3 + 3H2O
Mol: 0,05 0,3 0,1
\(m_{Al_2O_3}=0,05.102=5,1\left(g\right)\)
b, mdd sau pứ = 5,1 + 54,75 = 59,85 (g)
\(C\%_{ddAlCl_3}=\dfrac{0,1.133,5.100\%}{59,85}=22,31\%\)
nCuO=0.2(mol)
CuO+2HCl->CuCl2+H2O
0.2 0.4 0.2
m muối=0.2*(64+71)=27(g)
m HCl=14.6(g)
CM=0.4/0.2=2(M)
\(n_{MgO}=a\left(mol\right),n_{Fe_2O_3}=b\left(mol\right)\)
\(m=40a+160b=12\left(g\right)\left(1\right)\)
\(MgO+H_2SO_4\rightarrow MgSO_4+H_2O\)
\(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)
\(m_{Muối}=120a+400y=32\left(g\right)\left(2\right)\)
\(\left(1\right),\left(2\right):a=0.1,b=0.05\)
\(\%MgO=\dfrac{0.1\cdot40}{12}\cdot100\%=33.33\%\)
\(\%Fe_2O_3=66.67\%\)
\(m_{dd}=12+200=212\left(g\right)\)
\(C\%_{MgSO_4}=\dfrac{0.1\cdot120}{212}\cdot100\%=5.66\%\)
\(C\%_{Fe_2\left(SO_4\right)_3}=\dfrac{0.05\cdot400}{212}\cdot100\%=9.42\%\)
a) nFe= 16/56 =~ 0,3 mol
mH2S04 =( C% .mdd ) /100%= ( 20.100) /100 = 20g
nH2SO4 = 20/98 =~ 0,2mol
lập pthh của pu
Fe + H2SO4 ----------> FeSO4 + H2
1mol 1mol 1mol 1mol
0,3mol 0,2mol
xét tỉ lệ nFe dư sau pư vậy tính theo mol H2SO4
nFe (pư) = (0,2 .1 )/1 =0,2mol
nFe (dư) = 0,3 -0,2 =0,1mol
mFe dư = 0,1 . 56 = 5,6 g
mFeSO4 = 0,2 .152 = 30,4 g
b) mdd sau pư = mFe + m dung môi = 16 +100=116 g
c% Fe = (5,6 / 116) .100%=~ 4,83%
c% FeSO4 =(30,4/116).100%=~ 26,21%
a) đối 200ml =0,2 lít
CMFe =n/v = 0,1 / 0,2 =0,5 mol/lít
CMFeSO4 =n/v = 0,2/0,2=1 mol /lít
Ta có: \(n_{Fe_2O_3}=\dfrac{9,6}{160}=0,06\left(mol\right)\)
a. PTHH: Fe2O3 + 3H2SO4 ---> Fe2(SO4)3 + 3H2O (1)
Theo PT(1): \(n_{H_2SO_4}=3.n_{Fe_2O_3}=3.0,06=0,18\left(mol\right)\)
=> \(m_{H_2SO_4}=0,18.98=17,64\left(g\right)\)
Ta có: \(C_{\%_{H_2SO_4}}=\dfrac{17,64}{m_{dd_{H_2SO_4}}}.100\%=9,8\%\)
=> \(m_{dd_{H_2SO_4}}=180\left(g\right)\)
b. Ta có: \(m_{dd_{Fe_2\left(SO_4\right)_3}}=9,6+180=189,6\left(g\right)\)
Theo PT(1): \(n_{Fe_2\left(SO_4\right)_3}=n_{Fe_2O_3}=0,06\left(mol\right)\)
=> \(m_{Fe_2\left(SO_4\right)_3}=0,06.400=24\left(g\right)\)
=> \(C_{\%_{Fe_2\left(SO_4\right)_3}}=\dfrac{24}{189,6}.100\%=12,66\%\)
c. PTHH: Fe2(SO4)3 + 3BaCl2 ---> 3BaSO4↓ + 2FeCl3 (2)
Theo PT(2): \(n_{BaSO_4}=3.n_{Fe_2\left(SO_4\right)_3}=3.0,06=0,18\left(mol\right)\)
=> \(m_{BaSO_4}=0,18.233=41,94\left(g\right)\)
Theo PT(2): \(n_{BaCl_2}=n_{BaSO_4}=0,18\left(mol\right)\)
=> \(m_{BaCl_2}=0,18.208=37,44\left(g\right)\)
Ta có: \(C_{\%_{BaCl_2}}=\dfrac{37,44}{m_{dd_{BaCl_2}}}.100\%=10,4\%\)
=> \(m_{dd_{BaCl_2}}=360\left(g\right)\)