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CaCO3 \(\rightarrow\) CaO + CO2
BTKL : mCO2 = m - 0,78m = 0,22 m
Từ pt: \(\frac{mCaCO3}{mCO2}\) = \(\frac{100}{44}\) \(\rightarrow\) mCaCO3pứ = 0,5m
H= 80%
\(\rightarrow\) mCaCO3thựctế =\(\frac{0,5}{80}\).100 = 0,625m
\(\rightarrow\)a =\(\frac{0,625}{1}\) .100 = 62.5%
\(n_{CaCO_3}=\dfrac{52,65}{100}=0,5265\left(mol\right)\\ PTHH:CaCO_3\underrightarrow{t^o}CaO+CO_2\\ n_{CO_2\left(TT\right)}=0,5265.95\%=0,500175\left(mol\right)\\ n_{NaOH}=1,8.0,5=0,9\left(mol\right)\\ Vì:2>\dfrac{0,9}{0,500175}>1\)
Vậy: Thu 2 muối Na2CO3 và NaHCO3
\(2NaOH+CO_2\rightarrow Na_2CO_3+H_2O\\ 2x........x.........x\left(mol\right)\\ NaOH+CO_2\rightarrow NaHCO_3\\ y............y........y\left(mol\right)\\ \rightarrow\left\{{}\begin{matrix}x+y=0,500175\\2x+y=0,9\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,399825\\y=0,10035\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}m_{Na_2CO_3}=106.0,399825=42,38145\left(g\right)\\m_{NaHCO_3}=84.0,10035=8,4294\left(g\right)\end{matrix}\right.\)
$CaCO_3 \xrightarrow{t^o} CaO + CO_2$
$n_{CO_2} = n_{CaCO_3\ pư} = \dfrac{52,65}{100}.95\% = 0,5(mol)$
$n_{NaOH} = 0,5.1,8 = 0,9(mol)$
Ta có :
$1 < n_{NaOH} : n_{CO_2} = 0,9 : 0,5 = 1,8 < 2$
nên muối sinh ra là $NaHCO_3(a\ mol) ; Na_2CO_3(b\ mol)$
$2NaOH + CO_2 \to Na_2CO_3 + H_2O$
$NaOH + CO_2 \to NaHCO_3$
Ta có :
$a + 2b = 0,9$
$a + b = 0,5$
Suy ra a = 0,1 ; b = 0,4
$m_{Na_2CO_3} = 0,1.126 = 12,6(gam)$
$m_{NaHCO_3} = 0,4.84 = 33,6(gam)$
Ta có :
\(n_{C2H5OH}=0,58\left(mol\right)\)
\(C_2H_5OH+CuO\rightarrow CH_3CHO+Cu+H_2\)
0,58________________0,29_______________
\(CH_3CHO\rightarrow2Ag\)
0,29_______0,46
\(\rightarrow m_{Ag}=50,112\left(g\right)\)
Câu 2:
\(n_{HCl}=\frac{400.7,3\%}{36,5}=0,8\left(mol\right)\)
\(n_{MgO}=\frac{2,4}{40}=0,06\left(mol\right)\)
\(n_{MgCO3}=\frac{13,6}{84}=0,15\left(mol\right)\)
\(n_{FeCO3}=\frac{10,44}{116}=0,09\left(mol\right)\)
\(n_{MgCl2}=n_{MgCO3}+n_{MgO}=0,21\)
\(n_{FeCl2}=n_{FeCO3}=0,09\left(mol\right)\)
\(n_{HCl\left(Pư\right)}=2n_{FeCl2}+2n_{MgCl2}=0,6\left(mol\right)\)
\(\Rightarrow n_{HCl\left(dư\right)}=0,8-0,6=0,2\left(mol\right)\)
\(n_{CO2}=n_{MgCO3}+n_{FeCO3}=0,24\left(mol\right)\)
\(m_{dd\left(spu\right)}=400+12,6+10,44+2,4-0,24.44=414,88\)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{FeCl2}=\frac{0,09.127}{414,88}.100\%=2,755\%\\C\%_{MgCl2}=\frac{0,21.95}{414,88}.100\%=4,81\%\\C\%_{HCl\left(dư\right)}=\frac{0,2.36,5}{414,88}.100\%=1,76\%\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}n_{Fe\left(OH\right)2}=n_{FeCl2}=0,09\\n_{Mg\left(OH\right)2}=n_{MgCl2}=0,21\end{matrix}\right.\)
\(\Rightarrow m_{kt}=m_{Mg\left(OH\right)2}+m_{Fe\left(OH\right)2}\)
\(\Leftrightarrow m_{kt}=0,21.58+0,09.90=20,28\left(g\right)\)
Câu 1:
\(27n_{Al}+56n_{Fe}=8,715\)
\(n_{Al}-n_{Fe}=0\)
\(\Rightarrow n_{Al}=n_{Fe}=0,105\)
\(n_{Al}=n_{AlCl3}=0,105\left(mol\right)\)
\(\Rightarrow m_{muoi}=m_{AlCl3}+m_{FeCl3}\)
\(\Leftrightarrow m_{muoi}=0,105.162,5+0,105+133,5=31,08\left(g\right)\)
Câu 2: Mai mình làm cho giờ muộn rồi lười gõ telexx
Chọn D