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nO2 = 48/32 = 1,5 (mol)
PTHH: KMnO4 -t°-> K2MnO4 + MnO2 + O2
3. 1,5
H = 3/4 = 75%
\(2KMnO_4 \xrightarrow{t^o} K_2MnO_4 + MnO_2 + O_2\\ n_{O_2} = \dfrac{22,4}{22,4} = 1(mol)\\ n_{KMnO_4} = 2n_{O_2} = 2(mol)\\ \Rightarrow H = \dfrac{2.158}{200}.100\% = 158\%>100\%\)
(Sai đề)
\(a,2KMnO_4\xrightarrow{t^o}K_2MnO_4+MnO_2+O_2\\ n_{KMnO_4}=\dfrac{395}{158}=2,5(mol)\\ \Rightarrow n_{O_2}=1,25(mol)\\ \Rightarrow V_{O_2}=1,25.22,4=28(l)\\ \Rightarrow V_{O_2(tt)}=28.85\%=23,8(l)\)
\(b,n_{O_2}=\dfrac{67,2}{22,4}=3(mol)\\ 2KMnO_4\xrightarrow{t^o}K_2MnO_4+MnO_2+O_2\\ \Rightarrow n_{KMnO_4}=6(mol)\\ \Rightarrow m_{KMnO_4}=6.158=948(g)\\ \Rightarrow m_{KMnO_4(tt)}=\dfrac{948}{80\%}=1185(g)\)
\(n_{KClO_3}=\dfrac{m_{KClO_3}}{M_{KClO_3}}=\dfrac{15}{122,5}=\dfrac{6}{49}mol\)
\(n_{KClO_3}=\dfrac{6}{49}:90\%=\dfrac{20}{147}mol\)
\(2KClO_3\rightarrow\left(t^o\right)2KCl+3O_2\)
20/147 10/49 ( mol )
\(V_{O_2}=n_{O_2}.22,4=\dfrac{10}{49}.22,4=4,5714l\)
\(m_{KClO_3\left(pư\right)}=\dfrac{15.90}{100}=13,5\left(g\right)\)
=> \(n_{KClO_3\left(pư\right)}=\dfrac{13,5}{122,5}=\dfrac{27}{245}\left(mol\right)\)
PTHH: 2KClO3 --to--> 2KCl + 3O2
\(\dfrac{27}{245}\)----------------->\(\dfrac{81}{490}\)
=> \(V_{O_2}=\dfrac{81}{490}.22,4=\dfrac{648}{175}\left(l\right)\)
2KMnO4-to>K2MnO4+MnO2+O2
0,2---------------------------------------0,1 mol
n O2=\(\dfrac{2,24}{22,4}\)=0,1 mol
=>m KMnO4 tt =0,2.158=31,6g
=>H =\(\dfrac{31,6}{39,5}.100\)=80%
Ta có: \(n_{KMnO_4}=\dfrac{39,5}{158}=0,25\left(mol\right)\)
PT: \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
Theo PT: \(n_{O_2\left(LT\right)}=\dfrac{1}{2}n_{KMnO_4}=0,125\left(mol\right)\)
Mà: \(n_{O_2\left(TT\right)}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
\(\Rightarrow H\%=\dfrac{0,1}{0,125}.100\%=80\%\)
Bạn tham khảo nhé!
2K2MnO4-toK2MnO4+MnO2+O2
nKMnO4=15,8/158=0,1 mol
->nK2MnO4=nMnO2=0,05 mol
mcr=0,05.197+0,05.87=14,2g
H,=14,2/14,5=97,7%
\(n_{KMnO_4}=\dfrac{15,8}{158}=0,1mol\)
Gọi \(n_{KMnO_4}=x\)
\(2KMnO_4\rightarrow\left(t^o\right)K_2MnO_4+MnO_2+O_2\)
x 1/2 x 1/2 x ( mol )
Ta có:
\(158\left(0,1-x\right)+\dfrac{1}{2}x\left(197+87\right)=14,52\)
\(\Leftrightarrow x=0,08mol\)
\(H=\dfrac{0,08}{0,1}.100=80\%\)
PTHH: \(2KMnO_4\xrightarrow[]{t^o}K_2MnO_4+MnO_2+O_2\)
\(n_{KMnO_4}=\dfrac{m_{KMnO_4}}{M_{KMnO_4}}=\dfrac{15,8}{158}=0,1\left(mol\right)\)
a. Theo PTHH: \(n_{O_2}=\dfrac{1}{2}n_{KMnO_4}=\dfrac{1}{2}0,1=0,05\left(mol\right)\)
\(\Rightarrow V_{O_2}=n_{O_2}.22,4=0,05.22,4=1,12\left(l\right)\)
b. PTHH: \(3Fe+2O_2\xrightarrow[]{t^o}Fe_3O_4\)
\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
Ta có: \(\dfrac{1}{n_{O_2}}=\dfrac{1}{0,05}\)
\(\dfrac{1}{n_{Fe}}=\dfrac{1}{0,1}\)
\(\Rightarrow\dfrac{1}{n_{O_2}}>\dfrac{1}{n_{Fe}}\)
Vậy Fe dư
Theo PTHH: \(n_{Fe_3O_4}=\dfrac{0,1.1}{3}=\dfrac{1}{30}\left(mol\right)\)
\(\Rightarrow m_{Fe_3O_4}=n_{Fe_3O_4}.M_{Fe_3O_4}=\dfrac{1}{30}.232\approx7,73g\)
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