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\(a.Zn+CuSO_4->ZnSO_4+Cu\)
b. m Zn giảm vì sau phản ứng tạo Cu (M = 64), M(Cu) < M(Zn) = 65 nên khối lượng lá Zn tăng.
\(m_{Zn\left(Pư\right)}=65x\left(g\right)\\ m_{Cu}=64x\left(g\right)\\c.\Delta m_{rắn}=25-24,96=65x-64x\\ x=0,04mol\\ m_{Zn\left(Pư\right)}=65x=2,6g< 25g\Rightarrow Zn:hết\\d. n_{CuSO_4}=160x=6,4g\)
\(n_{Zn\left(pứ\right)}=1,3-0,65=0,65g\)
\(n_{Zn}=\dfrac{0,65}{65}=0,01mol\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,01 0,02 0,01 0,01 ( mol )
\(V_{H_2}=0,01.24=0,24l\)
\(m_{HCl}=\dfrac{0,02.36,5}{7,3\%}=10g\)
\(m_{ZnCl_2}=0,01.136=1,36g\)
\(m_{ddspứ}=1,3+10-0,01.2=11,28g\)
\(C\%_{ZnCl_2}=\dfrac{1,36}{11,28}.100=12,05\%\)
\(a.Cu+2AgNO_3->Cu\left(NO_3\right)_2+2Ag\)
b. m Cu tăng vì sau phản ứng tạo Ag (M = 108), M(Ag) > M(Cu) = 64 nên khối lượng thanh đồng tăng.
\(m_{Cu\left(PƯ\right)}=64x\left(g\right)\\ m_{Ag}=108.2x=216x\left(g\right)\\ c.\Delta m_{rắn}=13,6-6=216x-64x\\ x=0,05mol\\ m_{Cu\left(PƯ\right)}=64x=3,2g\\ d.Cu:dư\\ n_{AgNO_3}=2x=0,1mol\\ m_{AgNO_3}=170\cdot0,1=17g\)
mZn giảm 6,5 g=>có 6,5 g Zn đã p/ứ
nZn=6,5/65=0,1(mol)
pt: 2HCl+Zn--->ZnCl2+H2
0,2______0,1____0,1____0,1
VH2=0,1.22,4=2,24(l)
mHCl=0,2.36,5=7,3(g)
dd chứa ZnCl2
mZnCl2=0,1.136=13,6(g)
\(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right);n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\\a, Zn+2HCl\rightarrow ZnCl_2+H_2\\ b,V\text{ì}:\dfrac{0,2}{1}>\dfrac{0,1}{1}\Rightarrow Zn\text{dư}\\ \Rightarrow n_{Zn\left(p.\text{ứ}\right)}=n_{ZnCl_2}=n_{H_2}=0,1\left(mol\right)\\b, m_{Zn\left(p.\text{ứ}\right)}=0,1.65=6,5\left(g\right)\\ n_{HCl}=0,1.2=0,2\left(mol\right)\\ m_{HCl}=0,2.36,5=7,3\left(g\right)\\ d,m_{ZnCl_2}=136.0,1=13,6\left(g\right)\)
a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
b, \(n_{HCl}=0,2.1=0,2\left(mol\right)\)
Theo PT: \(n_{Zn}=\dfrac{1}{2}n_{HCl}=0,1\left(mol\right)\Rightarrow m_{Zn}=0,1.65=6,5\left(g\right)\)
c, \(n_{H_2}=\dfrac{1}{2}n_{HCl}=0,1\left(mol\right)\Rightarrow V_{H_2}=0,1.22,4=2,24\left(l\right)\)
a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
b, Ta có: \(n_{Zn}=\dfrac{32,5}{65}=0,5\left(mol\right)\)
Theo PT: \(n_{H_2}=n_{Zn}=0,5\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,5.22,4=11,2\left(l\right)\)
c, Theo PT: \(n_{ZnCl_2}=n_{Zn}=0,5\left(mol\right)\)
\(\Rightarrow m_{ZnCl_2}=0,5.136=68\left(g\right)\)
Gọi \(n_{Zn\left(pư\right)}=a\left(mol\right)\)
PTHH: Zn + CuCl2 ---> Cu + ZnCl2
a a a
mgiảm = mZn (tan ra) - mCu (bám vào) = 65a - 64a = 0,0075
=> a = 0,0075 (mol)
=> mZn (pư) = 0,0075.65 = 0,4875 (g)
\(C_{MCuCl_2}=\dfrac{0,0075}{0,02}=0,375M\)
C% thì thiếu dCuCl2 nha
Gợi ý: \(C\%=C_M.\dfrac{M}{10.D}\left(D:\dfrac{g}{cm^3}hay\dfrac{g}{ml}\right)\)
Gọi \(n_{Zn}=x\left(mol\right)\Rightarrow n_{Cu}=x\left(mol\right)\)
Khối lượng giảm 0,0075g.
\(\Rightarrow m_{Zn}-m_{Cu}=0,0075\Rightarrow65x-64x=0,0075g\)
\(\Rightarrow x=0,0075\)
\(Zn+CuCl_2\underrightarrow{t^o}ZnCl_2+Cu\)
0,0075 0,0075
\(m_{Zn}=0,0075\cdot65=0,4875g\)
\(C_{M_{CuCl_2}}=\dfrac{0,0075}{0,02}=0,375M\)