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\(n_{H2}=\dfrac{7,84}{22,4}=0,35\left(mol\right)\)
Pt : \(Mg+2HCl\rightarrow MgCl_2+H_2|\)
1 2 1 1
a 0,4 0,2 1a
\(Fe+2HCl\rightarrow FeCl_2+H_2|\)
1 2 1 1
b 0,3 0,15 1b
a) Gọi a là số mol của Mg
b là số mol của Fe
\(m_{Mg}+m_{Fe}=13,2\left(g\right)\)
⇒ \(n_{Mg}.M_{Mg}+n_{Fe}.M_{Fe}=13,2g\)
⇒ 24a + 56b = 13,2g (1)
Theo phương trình : 1a + 1b = 0,35(2)
Từ(1),(2), ta có hệ phương trình :
24a + 56b = 13,2g
1a + 1b = 0,35
⇒ \(\left\{{}\begin{matrix}a=0,2\\b=0,15\end{matrix}\right.\)
\(m_{Mg}=0,2.24=4,8\left(g\right)\)
\(m_{Fe}=0,15.56=8,4\left(g\right)\)
0/0Mg = \(\dfrac{4,8.100}{13,2}=36,36\)0/0
0/0Fe = \(\dfrac{8,4.100}{13,2}=63,64\)0/0
b) \(n_{HCl\left(tổng\right)}=0,4+0,3=0,7\left(mol\right)\)
200ml = 0,2l
\(C_{M_{ddHCl}}=\dfrac{0,7}{0,2}=3,5\left(M\right)\)
c) \(m_{muối.clorua}=\left(0,2.95\right)+\left(0,15.127\right)=38,05\left(g\right)\)
Chúc bạn học tốt
a) \(n_{AlCl_3}=\dfrac{6,675}{133,5}=0,05\left(mol\right)\)
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
0,05<-----------0,05---->0,075
=> \(\%Al=\dfrac{0,05.27}{14,15}.100\%=9,54\%\)
=> \(\%Cu=\dfrac{14,15-0,05.27}{14,15}.100\%=90,46\%\)
b) \(V_{H_2}=0,075.22,4=1,68\left(l\right)\)
c) \(n_{Cu}=\dfrac{14,15-0,05.27}{64}=0,2\left(mol\right)\)
PTHH: 4Al + 3O2 --to--> 2Al2O3
0,05->0,0375
2Cu + O2 --to--> 2CuO
0,2-->0,1
=> \(V_{O_2}=\left(0,1+0,0375\right).22,4=3,08\left(l\right)\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\\ m_{AlCl_3}=6,675\left(mol\right)\\ n_{AlCl_3}=\dfrac{6,675}{133,5}=0,05\left(mol\right)\\ \Rightarrow n_{Al}=n_{AlCl_3}=0,05\left(mol\right)\\ \Rightarrow m_A=0,05.27=1,35\left(g\right);m_{Cu}=14,15-1,35=12,8\left(g\right)\\ \%m_{Cu}=\dfrac{12,8}{14,15}.100\approx90,459\%\\ \Rightarrow\%m_{Al}\approx9,541\%\\ b,n_{Cu}=\dfrac{12,8}{64}=0,2\left(mol\right)\\ n_{H_2}=\dfrac{3}{2}.n_{Al}=\dfrac{3}{2}.0,05=0,075\left(mol\right)\\ \Rightarrow V=V_{H_2\left(đktc\right)}=0,075.22,4=1,68\left(l\right)\\ 4Al+3O_2\rightarrow\left(t^o\right)2Al_2O_3\\ 2Cu+O_2\rightarrow\left(t^o\right)2CuO\\ n_{O_2}=\dfrac{3}{4}.n_{Al}+\dfrac{1}{2}.n_{Cu}=\dfrac{3}{4}.0,05+\dfrac{1}{2}.0,2=0,0875\left(mol\right)\)
\(\Rightarrow V_{O_2\left(đktc\right)}=0,0875.22,4=1,96\left(l\right)\)
Giả sử: \(\left\{{}\begin{matrix}n_{Mg}=x\left(mol\right)\\n_{Al}=y\left(mol\right)\end{matrix}\right.\)
⇒ 24x + 27y = 7,8 (1)
Ta có: \(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)
BT e, có: 2x + 3y = 0,8 (2)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,1\left(mol\right)\\y=0,2\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Mg}=0,1.24=2,4\left(g\right)\\m_{Al}=0,2.27=5,4\left(g\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Mg}=\dfrac{2,4}{7,8}.100\%\approx30,77\%\\\%m_{Al}\approx69,23\%\end{matrix}\right.\)
b, BTNT Mg và Al, có:
nMgCl2 = nMg = 0,1 (mol)
nAlCl3 = nAl = 0,2 (mol)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{MgCl_2}=\dfrac{0,1.95}{0,1.95+0,2.133,5}.100\%\approx26,24\%\\\%m_{AlCl_3}\approx73,76\%\end{matrix}\right.\)
Bạn tham khảo nhé!
\(a,n_{H_2}=\dfrac{2,576}{22,4}=0,115\left(mol\right)\\ Đặt:n_{Mg}=a\left(mol\right);n_{Al}=b\left(mol\right)\left(a,b>0\right)\\ Mg+2HCl\rightarrow MgCl_2+H_2\\ 2Al+6HCl\rightarrow2AlCl_3+3H_2\\ \Rightarrow\left\{{}\begin{matrix}95a+133,5b=10,475\\a+1,5b=0,115\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,04\\b=0,05\end{matrix}\right.\\ \%m_{Mg}=\dfrac{0,04.24}{0,04.24+0,05.27}.100\approx41,558\%\Rightarrow\%m_{Al}\approx58,442\%\\ b,n_{HCl}=2.n_{H_2}=2.0,115=0,23\left(mol\right)\\ \Rightarrow x=C\%_{ddHCl}=\dfrac{0,23.36,5}{100}.100=8,395\%\)
\(a)n_{Mg} = a ; n_{Al} = b \Rightarrow 24a +27b = 5,1(1)\\ Mg + 2HCl \to MgCl_2 + H_2\\ 2Al + 6HCl \to 2AlCl_3 + 3H_2\\ n_{H_2} = a + 1,5b = \dfrac{5,6}{22,4} = 0,25(2)\\ (1)(2) \Rightarrow a = 0,1 ; b = 0,1\\ \%m_{Mg} = \dfrac{0,1.24}{5,1}.100\% = 44,44\%\ ;\ \%m_{Al} = 100\% -44,44\% = 55,56\%\\ b) n_{MgCl_2} = n_{Mg} = 0,1 \Rightarrow m_{MgCl_2} = 0,1.95 = 9,5(gam)\\ n_{AlCl_3} = n_{Al} = 0,1 \Rightarrow m_{AlCl_3} = 0,1.133,5 = 13,35(gam)\\ c)n_{HCl} = 2n_{Mg} + 3n_{Al} = 0,5(mol) \Rightarrow m_{dd\ HCl} = \dfrac{0,5.36,5}{3,65\%} = 500(gam)\)
\(m_{dd\ sau\ pư} = 5,1 + 500 - 0,25.2 = 504,6(gam)\\ C\%_{MgCl_2} = \dfrac{9,5}{504,6}.100\% = 1,89\%\\ C\%_{AlCl_3} = \dfrac{13,35}{504,6}.100\% = 2,65\%\)
\(\left\{{}\begin{matrix}Fe\\Al\end{matrix}\right.+HCl->\left\{{}\begin{matrix}FeCl2\\AlCl3\end{matrix}\right.+H2\)
Ta có số mol Fe là x , Al là y (mol)
\(\left\{{}\begin{matrix}56x+27y=11\\127x+133,5y=39,4\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%mFe=\dfrac{0,1.56}{11}=50,9\%\\\%mAl=\dfrac{0,2.27}{11}=49,09\%\end{matrix}\right.\)
Bảo toàn e :
\(2.nH2=2.nFe+3.nAl\Rightarrow nH2=0,4\left(mol\right)\)
\(V=0,4.22,4=8,96\left(l\right)\)
\(nFe=nFeCl2=0,1\left(mol\right)\)
\(nAl=nAlCl3=0,2\left(mol\right)\)
\(\Rightarrow nHCl\left(pứ\right)=2.0,1+3.0,2=0,8\left(mol\right)\)
\(Cm=\dfrac{n}{V}=\dfrac{0,8}{0,2}=4\left(M\right)\)
a, Ta có: 24nMg + 56nFe = 9,2 (g) (1)
\(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
BT e, có: 2nMg + 2nFe = 2nH2 = 0,5 (2)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{Mg}=0,15\left(mol\right)\\n_{Fe}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Mg}=\dfrac{0,15.24}{9,2}.100\%\approx39,13\%\\\%m_{Fe}\approx60,87\%\end{matrix}\right.\)
b, BTNT H, có: \(n_{HCl}=2n_{H_2}=0,5\left(mol\right)\Rightarrow C_{M_{HCl}}=\dfrac{0,5}{0,2}=2,5\left(M\right)\)
\(n_{H_2SO_4}=0,5.0,2=0,1\left(mol\right)\\ n_{HCl}=0,2.2,5=0,5\left(mol\right)\\ n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\\ n_{H^+}=2n_{H_2SO_4}+n_{HCl}=0,7\left(mol\right)\)
Giả sử kim loại dư
\(\Rightarrow n_{H_2}=\dfrac{1}{2}\Sigma n_{H^+}=\dfrac{1}{2}.0,7=0,35\left(mol\right)>0,25\left(mol\right)\)
Vậy kim loại hết
Đặt \(\left\{{}\begin{matrix}n_{Mg}=x\left(mol\right)\\n_{Al}=y\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow24x+27y=5,1\left(g\right)\) (I)
BT e:
cho:
\(Mg^o\rightarrow Mg^{2+}+2e\)
x------------------>2x
\(Al^o\rightarrow Al^{3+}+3e\)
y--------------->3y
nhận:
\(2H^++2e\rightarrow H_2O\)
0,5<--0,25
Từ trên có: \(2x+3y=0,5\left(II\right)\)
Từ (I), (II) giải được \(\left\{{}\begin{matrix}x=0,1\\y=0,1\end{matrix}\right.\)
\(CM_{H^+.dư}=\dfrac{0,7-0,5}{0,2}=1M\)
\(CM_{Mg^{2+}}=CM_{Al^{3+}}=\dfrac{0,1}{0,2}=0,5M\)
\(CM_{SO_4^{2-}}=0,5M\\ CM_{Cl^-}=2,5M\)