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a) \(n_{CH_4}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)
\(n_{CO_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
PTHH: CH4 + 2O2 --to--> CO2 + 2H2O
0,05-->0,1------->0,05
2C2H2 + 5O2 --to--> 4CO2 + 2H2O
0,125<--0,3125<----0,25
=> \(\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,05}{0,05+0,125}.100\%=28,57\%\\\%V_{C_2H_2}=\dfrac{0,125}{0,05+0,125}.100\%=71,43\%\end{matrix}\right.\)
\(\left\{{}\begin{matrix}\%m_{CH_4}=\dfrac{0,05.16}{0,05.16+0,125.26}.100\%=19,753\%\\\%m_{C_2H_2}=\dfrac{0,125.26}{0,05.16+0,125.26}.100\%=80,247\%\end{matrix}\right.\)
b) \(n_{O_2}=0,1+0,3125=0,4125\left(mol\right)\)
=> \(V_{O_2}=0,4125.22,4=9,24\left(l\right)\)
=> Vkk = 9,24.5 = 46,2 (l)
Giả sử các khí được đo ở điều kiện sao cho 1 mol khí chiếm thể tích 1 lít
Gọi số mol CH4, C2H6 là a, b (mol)
=> \(a+b=\dfrac{25}{1}=25\left(mol\right)\) (1)
\(n_{O_2}=\dfrac{95}{1}=95\left(mol\right)\)
PTHH: CH4 + 2O2 --to--> CO2 + 2H2O
a---->2a---------->a
2C2H6 + 7O2 --to--> 4CO2 + 6H2O
b------>3,5b-------->2b
=> \(\left\{{}\begin{matrix}n_{O_2\left(dư\right)}=95-2a-3,5b\left(mol\right)\\n_{CO_2}=a+2b\left(mol\right)\end{matrix}\right.\)
=> \(95-a-1,5b=\dfrac{60}{1}=60\)
=> a + 1,5b = 35 (2)
(1)(2) => a = 5; b = 20
=> \(\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{5}{25}.100\%=20\%\\\%V_{C_2H_6}=\dfrac{20}{25}.100\%=80\%\end{matrix}\right.\)
\(\overline{M}_A=\dfrac{5.16+20.30}{5+20}=27,2\left(g/mol\right)\)
\(\overline{M}_B=20,5.2=41\left(g/mol\right)\)
=> \(d_{A/B}=\dfrac{27,2}{41}\approx0,663\)
\(n_{CH_4} = a(mol) ; n_{H_2} = b(mol) ; n_{CO} = c(mol)\\ \Rightarrow a + b + c = \dfrac{8,96}{22,4} = 0,4(1)\\ TN1 :\\ CH_4 + 2O_2 \xrightarrow{t^o} CO_2 + 2H_2O\\ 2H_2 + O_2 \xrightarrow{t^o} 2H_2O\\ 2CO + O_2 \xrightarrow{t^o} 2CO_2\\ n_{O_2} = 2a + 0,5b + 0,5c = \dfrac{7,84}{22,4} = 0,35(2)\\ TN2:\\ CuO + H_2 \xrightarrow{t^o} Cu + H_2O\\ \)
\(n_{CuO} = \dfrac{48}{80} = 0,6(mol) CuO + CO \xrightarrow{t^o} Cu + CO_2\\ \dfrac{m_{hh}}{n_{CuO}}=\dfrac{16a + 2b + 28c}{b + c} = \dfrac{14,8}{0,6}(3)\\ (1)(2)(3) \Rightarrow a = 0,1 ; b = 0,1 ; c = 0,2\\ \%V_{CH_4} = \%V_{H_2} = \dfrac{0,1}{0,4}.100\% = 25\%\\ \%V_{CO} = \dfrac{0,2}{0,4}.100\% = 50\%\)
a, \(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)
\(C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\)
\(2C_2H_2+5O_2\underrightarrow{t^o}4CO_2+2H_2O\)
b, Sửa đề: 17,9 (l) → 17,92 (l)
Ta có: \(n_{CO_2}=\dfrac{17,92}{22,4}=0,8\left(mol\right)=n_C\)
\(n_{H_2O}=\dfrac{18}{18}=1\left(mol\right)\Rightarrow n_H=1.2=2\left(mol\right)\)
⇒ mA = mC + mH = 0,8.12 + 2.1 = 11,6 (g)
Theo ĐLBT KL, có: mA + mO2 = mCO2 + mH2O
⇒ mO2 = 0,8.44 + 18 - 11,6 = 41,6 (g)
\(\Rightarrow n_{O_2}=\dfrac{41,6}{32}=1,3\left(mol\right)\Rightarrow V_{O_2}=1,3.22,4=29,12\left(l\right)\)