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a)
$n_{Al} = 0,3(mol)$
$2Al + 3H_2SO_4 \to Al_2(SO_4)_3 + 3H_2$
Theo PTHH :
$n_{H_2SO_4} = \dfrac{3}{2}n_{Al} = 0,45(mol)$
$m_{dd\ H_2SO_4} = \dfrac{0,45.98}{12,25\%} = 360(gam)$
b)
$n_{H_2} = n_{H_2SO_4} = 0,45(mol)$
$V_{H_2} = 0,45.22,4 = 10,08(lít)$
c)
$n_{Al_2(SO_4)_3} = 0,15(mol)$
$m_{dd\ sau\ pư} = 8,1 + 360 - 0,45.2 = 367,2(gam)$
$C\%_{Al_2(SO_4)_3} = \dfrac{0,15.342}{367,2}.100\% = 14\%$
\(n_{Al}=\dfrac{2,7}{27}=0,1mol\)
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
0,1 0,15 0 ,05 0,15
a)\(V=0,15\cdot22,4=3,36\left(l\right)\)
b)\(m_{H_2SO_4}=0,15\cdot98=14,7\left(g\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{14,7}{9,8}\cdot100=150\left(g\right)\)
c) \(m_{H_2}=0,15\cdot2=0,3\left(g\right)\)
\(m_{ddsau}=2,7+150-0,3=152,4\left(g\right)\)
\(m_{Al_2\left(SO_4\right)_3}=0,05\cdot342=17,1\left(g\right)\)
\(\Rightarrow C\%=\dfrac{17,1}{152,4}\cdot100=11,22\%\)
a, PT: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
b, Ta có: \(n_{Fe}=\dfrac{19,6}{56}=0,35\left(mol\right)\)
Theo PT: \(n_{H_2}=n_{Fe}=0,35\left(mol\right)\Rightarrow V_{H_2}=0,35.22,4=7,84\left(l\right)\)
c, \(n_{H_2SO_4}=n_{Fe}=0,35\left(mol\right)\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,35}{0,2}=1,75\left(M\right)\)
d, \(n_{FeSO_4}=n_{Fe}=0,35\left(mol\right)\Rightarrow m_{FeSO_4}=0,35.152=53,2\left(g\right)\)
e, \(C_{M_{FeSO_4}}=\dfrac{0,35}{0,2}=1,75\left(M\right)\)
d, \(n_{H_2SO_4}=0,25.1,6=0,4\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{n_{Fe}}{1}< \dfrac{n_{H_2SO_4}}{1}\), ta được H2SO4 dư.
Theo PT: \(n_{H_2SO_4\left(pư\right)}=n_{Fe}=0,35\left(mol\right)\)
\(\Rightarrow n_{H_2SO_4\left(dư\right)}=0,4-0,35=0,05\left(mol\right)\)
\(\Rightarrow m_{H_2SO_4\left(dư\right)}=0,05.98=4,9\left(g\right)\)
a, \(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)
b, \(n_{Mg}=\dfrac{12}{24}=0,5\left(mol\right)\)
Theo PT: \(n_{H_2}=n_{Mg}=0,5\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,5.22,4=11,2\left(l\right)\)
c, \(n_{H_2SO_4}=n_{Mg}=0,5\left(mol\right)\)
\(\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,5}{0,1}=5\left(M\right)\)
1.
\(n_{Mg}=\dfrac{m_{Mg}}{M_{Mg}}=\dfrac{12}{24}0,5mol\)
đổi \(100ml=0,1l\)
PTHH: Mg + H2SO4 \(\rightarrow\) MgSO4 + H2
TL: 1 : 1 : 1 : 1
mol: 0,5 \(\rightarrow\) 0,5 \(\rightarrow\) 0,5 \(\rightarrow\) 0,5
\(b.V_{H_2}=n_{H_2}.22,4=0,5.22,4=11,2l\)
\(c.C_{M_{ddH_2SO_4}}=n_{H_2SO_4}.V_{dd_{H_1SO_4}}=0,5.0,1=0,05M\)
\(n_{H_2}=\dfrac{2,24}{22,4}=0,1=n_{Zn}\\ n_{ZnO}=\dfrac{14,6-6,5}{81}=0,1mol\\ C\%=\dfrac{0,2\cdot136}{175,6+14,6-0,2}=14,32\%\)
Ta có: \(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
PT: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
a, \(n_{Al}=\dfrac{2}{3}n_{H_2}=\dfrac{1}{6}\left(mol\right)\Rightarrow m_{Al}=\dfrac{1}{6}.27=4,5\left(g\right)\)
b, \(n_{H_2SO_4}=n_{H_2}=0,25\left(mol\right)\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,25}{0,2}=1,25\left(M\right)\)
c, \(n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{3}n_{H_2}=\dfrac{1}{12}\left(mol\right)\)
\(\Rightarrow m_{Al_2\left(SO_4\right)_3}=\dfrac{1}{12}.342=28,5\left(g\right)\)
PTHH:
\(Zn+H_2SO_4--->ZnSO_4+H_2\)
\(Cu+H_2SO_4--\times-->\)
a. Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Theo PT: \(n_{Zn}=n_{H_2}=0,1\left(mol\right)\)
\(\Rightarrow m_{Zn}=0,1.65=6,5\left(g\right)\)
\(\Rightarrow\%_{m_{Zn}}=\dfrac{6,5}{19,3}.100\%=33,7\%\)
\(\%_{m_{Cu}}=100\%-33,7\%=66,3\%\)
b. Theo PT: \(n_{H_2SO_4}=n_{Zn}=0,1\left(mol\right)\)
Đổi 200ml = 0,2 lít
\(\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,1}{0,2}=0,5M\)
c. Ta có: \(V_{dd_{ZnSO_4}}=V_{dd_{H_2SO_4}}=0,2\left(lít\right)\)
Theo PT: \(n_{ZnSO_4}=n_{Zn}=0,1\left(mol\right)\)
\(\Rightarrow C_{M_{ZnSO_4}}=\dfrac{0,1}{0,2}=0,5M\)
2Al+3H2SO4->Al2(SO4)3+3H2
0,1----------\(\dfrac{1}{30}\)-------0,1 mol
n H2=\(\dfrac{2,24}{22,4}\)=0,1 mol
=>m Al2(SO4)3=\(\dfrac{1}{30}\).342=11,4g
=>CM H2SO4=\(\dfrac{0,1}{0,2}\)=0,5 M
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