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\(n_{hh}=\dfrac{13,44}{22,4}=0,6mol\)
\(\overline{M_x}=24.2=48\)
\(\left\{{}\begin{matrix}SO_2:64\\O_2:32\end{matrix}\right.\) 48 = \(\dfrac{16}{16}=1\)
\(\Rightarrow n_{SO_2=}n_{O_2}=0,3mol\)
1. \(m_{hh}=0,3.64+0,3.32=28,8g\)
2. \(\%V_{SO_2}=\dfrac{0,3.22,4}{13,44}.100\%=50\%\)
\(\Rightarrow\%V_{O_2}=50\%\)
3. \(m_{SO_2}=0,3.64=19,2g\)
\(m_{O_2}=0,3.32=9,6g\)
1, a, + 8.2=16 => CH4
+ 8,5 . 2 = 17 => NH3
+ 16 . 2 =32 => O2
+ 22 . 2 = 44 => CO2
b, + 0,138 . 29 \(\approx4\) => He
+ 1,172 . 29 \(\approx34\) => H2S
+ 2,448 . 29 \(\approx71\Rightarrow Cl_2\)
+ 0,965 . 29 \(\approx28\) => N
\(n_{O_2}=2a\left(mol\right),n_{N_2}=3a\left(mol\right),n_{SO_2}=4a\left(mol\right)\)
\(n_{hh}=2a+3a+4a=9a\left(mol\right)\)
\(\Rightarrow9a=\dfrac{5.4\cdot10^{23}}{6\cdot10^{23}}=0.9\)
\(\Rightarrow a=9\)
\(V_{hh}=0.9\cdot22.4=20.16\left(l\right)\)
\(m_{hh}=0.2\cdot32+0.3\cdot28+0.4\cdot64=40.4\left(g\right)\)
Z gồm CO2 và O2 dư
$C + O_2 \xrightarrow{t^o} CO_2$
$n_{CO_2} =n_{O_2\ pư} = n_C = \dfrac{1,128}{12} = 0,094(mol)$
Gọi $n_{O_2} = 2a \to n_{không\ khí} = 3a(mol)$
Trong Y :
$n_{O_2} = 2a + 3a.20\% = 2,6a(mol)$
$n_{N_2} = 3a.80\% = 2,4a(mol)$
Trong Z :
$n_{CO_2} = 0,094(mol)$
$n_{N_2} = 2,4a(mol)$
$n_{O_2\ dư} = n_{O_2} - n_{O_2\ pư} = 2,6a - 0,094(mol)$
m CO2 =0,094.44 = 4,136(gam)
=> m Z = 4,136 : 27,5% = 15,04(gam)
SUy ra :
4,136 + 2,4a.28 + (2,6a - 0,094).32 = 15,04
=> a = 0,0925
=> n O2 = 0,0925.2 = 0,185(mol)
m X = 43,5 : 46,4% = 93,75(gam)
Bảo toàn khối lượng : m = 93,75 + 0,185.32 = 99,67(gam)
\(a.\)
\(n_{hh}=0.2+0.15+0.1=0.45\left(mol\right)\)
\(V_X=0.45\cdot22.4=10.08\left(l\right)\)
\(b.\)
\(m_X=0.2\cdot28+0.15\cdot71+0.1\cdot32=19.45\left(g\right)\)
\(c.\)
\(\overline{M}_X=\dfrac{19.45}{0.45}=43.22\left(g\text{/}mol\right)\)
\(d.\)
\(d_{X\text{/}kk}=\dfrac{43.22}{29}=1.4\)
Nặng hơn không khí 1.4 lần
Gọi \(\left\{{}\begin{matrix}n_{Cl_2}=a\left(mol\right)\\n_{O_2}=b\left(mol\right)\end{matrix}\right.\)
Theo đề bài, ta có:
\(\dfrac{71a+32b}{a+b}=14.4=56\left(g\text{/}mol\right)\)
\(\Leftrightarrow\dfrac{a}{b}=\dfrac{8}{5}\\ \Rightarrow\%V_{O_2}=\%n_{O_2}=\dfrac{5}{5+8}.100\%=38,46\%\)