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a) \(n_{Mg}=\dfrac{2,4}{24}=0,1\left(mol\right)\)
\(n_{Zn}=\dfrac{32,5}{65}=0,5\left(mol\right)\)
\(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\)
\(n_{Cu}=\dfrac{19,2}{64}=0,3\left(mol\right)\)
b)
\(m_{CO_2}=44.0,5=22\left(g\right)\)
\(m_{H_2}=1,5.2=3\left(g\right)\)
\(m_{N_2}=2.28=56\left(g\right)\)
\(m_{CuO}=3.80=240\left(g\right)\)
c) \(n_{Cl_2}=\dfrac{14,2}{71}=0,2\left(mol\right)\)
\(n_{H_2}=\dfrac{4,8}{2}=2,4\left(mol\right)\)
\(n_{O_2}=\dfrac{3,2}{32}=0,1\left(mol\right)\)
=> nhh = 0,2 + 2,4 + 0,1 = 2,7 (mol)
=> Vhh = 2,7.22,4 = 60,48(l)
\(a.n_{Mg}=\dfrac{2,4}{24}=0,1\left(mol\right)\\ n_{Zn}=\dfrac{32,5}{65}=0,5\left(mol\right)\\ n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\\ n_{Cu}=\dfrac{19,2}{64}=0,3\left(mol\right)\)
\(b.m_{CO_2}=0,5.44=22\left(g\right)\\ m_{H_2}=1,5.2=3\left(g\right)\\ m_{N_2}=2.28=56\left(g\right)\\ m_{CuO}=3.80=240\left(g\right)\)
\(c.n_{Cl_2}=\dfrac{14,2}{71}=0,2\left(mol\right)\\ n_{H_2}=\dfrac{4,8}{2}=2,4\left(mol\right)\\ n_{O_2}=\dfrac{3,2}{32}=0,1\left(mol\right)\\\Rightarrow n_{hh}=0,2+2,4+0,1=2,7\left(mol\right)\\ \Rightarrow V_{hh}=2,7.22,4=60,48\left(l\right)\)
\(a,n_{Mg}=\dfrac{2,4}{24}=0,1(mol); n_{Zn}=\dfrac{32,5}{65}=0,5(mol)\\ n_{Al}=\dfrac{2,7}{27}=0,1(mol); n_{Cu}=\dfrac{19,2}{64}=0,3(mol)\)
\(b,m_{CO_2}=0,5.44=22(g);m_{H_2}=1,5.2=3(g)\\ m_{N_2}=2.28=56(g);m_{CuO}=3.80=240(g)\)
\(c,n_{hh}=n_{Cl_2}+n_{H_2}+n_{O_2}=\dfrac{14,2}{71}+\dfrac{4,8}{2}+\dfrac{3,2}{32}=0,2+2,4+0,1=2,7(mol)\\ V_{hh}=2,7.22,4=60,48(l)\)
\(2CO + O_2 \xrightarrow{t^o} 2CO_2\\ 2H_2 + O_2 \xrightarrow{t^o} 2H_2O\\ n_{CO} = n_{CO_2} = \dfrac{8,8}{44} = 0,2(mol)\\ n_{O_2} = \dfrac{n_{CO} + n_{H_2}}{2}=\dfrac{0,2+n_{H_2}}{2} = \dfrac{9,6}{32} = 0,3(mol)\\ \Rightarrow n_{H_2} = 0,4(mol)\\ \%V_{CO} = \dfrac{0,2}{0,2 + 0,4}.100\% = 33,33\%\\ \%V_{H_2} = 100\% - 33,33\% = 66,67\%\\ \%m_{CO} = \dfrac{0,2.28}{0,2.28+0,4.2}.100\%=87,5\%\\ \%m_{H_2} = 100\% - 87,5\% = 12,5\%\)
Gọi: \(\left\{{}\begin{matrix}n_{H_2}=x\left(mol\right)\\n_{CO_2}=y\left(mol\right)\end{matrix}\right.\) \(\Rightarrow x+y=\dfrac{8,96}{22,4}=0,4\left(mol\right)\left(1\right)\)
Mà: dY/H2 = 6,25
\(\Rightarrow2x+44y=6,25.2.0,4\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,3\left(mol\right)=n_{H_2}\\y=0,1\left(mol\right)=n_{CO_2}\end{matrix}\right.\)
PT: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(Na_2CO_3+2HCl\rightarrow2NaCl+CO_2+H_2O\)
Theo PT: \(n_{Al}=\dfrac{2}{3}n_{H_2}=0,2\left(mol\right)\)
\(n_{Na_2CO_3}=n_{CO_2}=0,1\left(mol\right)\)
\(\Rightarrow m=m_{Al}+m_{Na_2CO_3}=0,2.27+0,1.106=16\left(g\right)\)
PTHH: 2CO+O2to→2CO2 (1)
4H2+O2to→2H2O (2)
b) Ta có:
ΣnO2=\(\dfrac{9,6}{32}\)=0,3(mol)
nCO2=\(\dfrac{8,8}{44}\)=0,2(mol)
⇒{nO2(1)=0,1mol
nO2(2)=0,2mol
⇒{mCO=0,1⋅28=2,8(g)
mH2=0,2⋅2=0,4(g)
⇒%mCO=\(\dfrac{2,8}{2,8+0,4}\)⋅100%=87,5%
%mH2=12,5%
\(nO_2=\dfrac{9,6}{32}=0,3\left(mol\right)\)
\(nCO_2=\dfrac{8,8}{44}=0,2\left(mol\right)\)
\(2CO+O_2\underrightarrow{t^o}2CO_2\)
2 1 2 (mol)
0,2 0,1 0,2 (mol)
\(4H_2+O_2\underrightarrow{t^o}2H_2O\)
4 1 2 (mol)
0,8 0,2 0,4 (mol)
\(mCO=0,2.28=5,6\left(g\right)\)
\(mH_2=0,8.2=0,16\left(g\right)\)
\(\%mCO=\dfrac{5,6.100}{5,6+0,16}=97,22\%\)
\(\%mH_2=100-97,22=2,78\%\)
a) Gọi số mol H2, N2 trong A là a, b
Có \(\dfrac{2a+28b}{a+b}=9,125.2=18,25\)
=> a = 0,6b
\(\left\{{}\begin{matrix}\%V_{H_2}=\dfrac{a}{a+b}.100\%=37,5\%\\\%V_{N_2}=\dfrac{b}{a+b}.100\%=62,5\%\end{matrix}\right.\)
b) \(n_A=\dfrac{14,6}{18,25}=0,8\left(mol\right)\)
c) \(n_A=\dfrac{6,2}{18,25}=\dfrac{124}{365}\left(mol\right)\)
Gọi số mol H2 cần thêm là x
Có \(\dfrac{2x+6,2}{x+\dfrac{124}{365}}=7,5.2=15\)
=> x = 0,085 (mol)
=> mH2 = 0,085.2 = 0,17(g)
16 nCO2=0,2mol
PTHH: 2CO+O2=>2CO2
0,2<--0,1<---0,2
=> mO2=0,2.32=6,4g
=> khối lượng Oxi phản ứng với H2 là :
9,6-6,4=3,2g
=> nH2O=3,2:32=0,1mol
PTHH: 2H+O2=>H2O
b)
0,2<-0,1<-0,2
=> mH2=2.0,2=0,4g
mCO =0,2.28=5,6g
=> m hh=5,6+0,4=6g
CuO+H2-to--->Cu+H2O
0,6----0,6
nCuO =48/80=0,6 (mol)
==>VH2 =0,6×22,4=13.44(l)
17.
\(n_{Fe}=\dfrac{5,6}{56}=0,1mol\)
\(m_{H_2SO_4}=200.19,6\%=39,2g\)
\(n_{H_2SO_4}=\dfrac{39,2}{98}=0,4mol\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
0,1 < 0,4 ( mol )
0,1 0,1 0,1 0,1 ( mol )
\(V_{H_2}=0,1.22,4=2,24l\)
Chất còn dư là H2SO4
\(m_{H_2SO_4\left(dư\right)}=\left(0,4-0,1\right).98=29,4g\)
\(\left\{{}\begin{matrix}m_{FeSO_4}=0,1.152=15,2g\\m_{H_2}=0,1.2=0,2g\end{matrix}\right.\)
\(m_{ddspứ}=5,6+200-0,1.2=205,4g\)
\(\left\{{}\begin{matrix}C\%_{FeSO_4}=\dfrac{15,2}{205,4}.100=7,4\%\\C\%_{H_2}=\dfrac{0,2}{205,4}.100=0,09\%\\C\%_{H_2SO_4\left(dư\right)}=\dfrac{29,4}{205,4}.100=14,31\%\end{matrix}\right.\)
Ta có: \(n_{O_2}=\dfrac{3,2}{32}=0,1\left(mol\right)\)
\(n_{CO_2}=\dfrac{8,8}{44}=0,2\left(mol\right)\)
\(\Rightarrow\overline{M}_Y=\dfrac{3,2+8,8}{0,1+0,2}=40\left(g/mol\right)\)
\(\Rightarrow d_{Y/H_2}=\dfrac{\overline{M}_Y}{M_{H_2}}=\dfrac{40}{2}=20\)