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\(n_{CO2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
PTHH : \(CaO+2HCl\rightarrow CaCl_2+H_2O\) (1)
\(CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2\) (2)
a) Theo Pt : \(n_{CO2}=n_{CaCO3}=0,1\left(mol\right)\)
\(m_{CaCO3}=0,1100=10\left(g\right)\)
\(m_{CaO}=12,8-10=2,8\left(g\right)\)
b) Chắc tính V của dd HCl đã dùng
(1) \(n_{CaO}=\dfrac{2,8}{56}=0,05\left(mol\right)\) , \(n_{HCl}=2n_{CaO}=0,1\left(mol\right)\)
(2) \(n_{HCl}=2n_{CaCO3}=0,2\left(mol\right)\)
\(\Rightarrow V_{ddHCl}=\dfrac{0,1+0,2}{1}=0,3\left(l\right)=300\left(ml\right)\)
\(n_{HCl}=0,1.3=0,3\left(mol\right)\\ CaO+2HCl\xrightarrow[]{}CaCl_2+H_2O\\ CaCO_3+2HCl\xrightarrow[]{}CaCl_2+H_2O+CO_2\\ n_{CaO}=a;n_{CaCO_3}=b\\ \Rightarrow\left\{{}\begin{matrix}2a+2b=0,3\\56a+100b=11,7\end{matrix}\right.\\ \Rightarrow a=b=0,075\left(mol\right)\\ n_{CaCl_2}=n_{CaO}=n_{CaCO_3}=0,075mol\\ m_{CaCl_2}=\left(0,075+0,075\right).111=16,65\left(g\right)\)
PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(ZnO+2HCl\rightarrow ZnCl_2+H_2O\)
Ta có: \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
Theo PT: \(n_{Zn}=n_{H_2}=0,2\left(mol\right)\)
\(\Rightarrow m_{Zn}=0,2.65=13\left(g\right)\)
\(m_{ZnO}=21,1-13=8,1\left(g\right)\)
Có: \(n_{ZnO}=\dfrac{8,1}{81}=0,1\left(mol\right)\)
Theo PT: \(n_{HCl}=2n_{Zn}+2n_{ZnO}=0,6\left(mol\right)\)
\(\Rightarrow m_{HCl}=0,6.36,5=21,9\left(g\right)\Rightarrow C\%_{ddHCl}=\dfrac{21,9}{200}.100\%=10,95\%\)
Theo PT: \(n_{ZnCl_2}=n_{Zn}+n_{ZnO}=0,3\left(mol\right)\)
\(\Rightarrow m_{ZnCl_2}=0,3.136=40,8\left(g\right)\)
Bạn tham khảo nhé!
CcccccccccccccccccccccCcccccccccccccccccccccCcccccccccccccccccccccCcccccccccccccccccccccCcccccccccccccccccccccCcccccccccccccccccccccCcccccccccccccccccccccCcccccccccccccccccccccCcccccccccccccccccccccCcccccccccccccccccccccCcccccccccccccccccccccCcccccccccccccccccccccCccccccccccccccccccccc
\(n_{CO2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
a) Pt : \(BaCO_3+2HCl\rightarrow BaCl_2+CO_2+H_2O|\)
1 2 1 1 1
a 0,2 1a
\(CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O|\)
1 2 1 1 1
b 0,2 1b
b) Gọi a là số mol của BaCO3
b là số mol của CaCO3
\(m_{BaCO3}+m_{CaCO3}=29,7\left(g\right)\)
⇒ \(n_{BaCO3}.M_{BaCO3}+n_{CaCO3}.M_{BaCO3}=29,7g\)
⇒ 197a + 100b = 29,7g (1)
Theo phương trình : 1a + 1b = 0,2(2)
Từ (1),(2),ta có hệ phương trình :
197a + 100b = 29,7g
1a + 1b = 0,2
⇒ \(\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\)
\(m_{BaCO3}=0,1.197=19,7\left(g\right)\)
\(m_{CaCO3}=0,1.100=10\left(g\right)\)
0/0BaCO3 = \(\dfrac{19,7.100}{29,7}=66,33\)0/0
0/0CaCO3 = \(\dfrac{10.100}{29,7}=33,67\)0/0
c) \(n_{HCl\left(tổng\right)}=0,2+0,2=0,4\left(mol\right)\)
\(m_{HCl}=0,4.36,5=14,6\left(g\right)\)
\(m_{ddHCl}=\dfrac{14,6.100}{20}=73\left(g\right)\)
Chúc bạn học tốt
nO2=0,085(mol) => nO= 0,17(mol)
m hỗn hợp KL=3,36(g)
nO(trong H2O) = nO(trong O2) = 0,17
=> nH2O = 0,17
=> nH(trong HCl) = nH(trong H2O) = 2nH2O= 0,34
=> nHCl=0,34
=> nCl= 0,34
m muối khan= mKL + mCl = 3,36 + 0,34 x 35,5 = 15,43
