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câu 1
a) CuO+H2SO4-->CuSO4 + H2O
\(m_{h2so4}=196.5\%=9.6\left(g\right)\)
\(n_{h2so4}=\dfrac{9.8}{98}=0.1\left(mol\right)\)
\(n_{CuO}=n_{h2SO4}=0.1\left(mol\right)\)
\(m_{CuO}=80\cdot0,1=8\left(g\right)\)
b)
\(m_{CuSO4}=160\cdot0,1=16\left(g\right)\)
\(m_{ddCuSO4}=8+196=204\left(g\right)\)
\(C\%_{MgSO4}=\dfrac{16}{204}\cdot100\%=7,84\%\)
c)\(n_{MgO}=n_{H2SO4}=0.1\left(mol\right)\)
\(m_{MgO}=n\cdot M=0.1\cdot40=4\left(g\right)\)
a, \(CuO+2HCl\rightarrow CuCl_2+H_2O\)
b, \(n_{HCl}=0,2.0,5=0,1\left(mol\right)\)
Theo PT: \(n_{CuO}=n_{CuCl_2}=\dfrac{1}{2}n_{HCl}=0,05\left(mol\right)\)
\(\Rightarrow m_{CuO}=0,05.80=4\left(g\right)\)
c, \(C_{M_{CuCl_2}}=\dfrac{0,05}{0,2}=0,25\left(M\right)\)
\(n_{HCl}=0,2.0,5=0,1\left(mol\right)\)
PTHH :
\(CuO+2HCl\rightarrow CuCl_2+H_2O\)
0,05 0,1 0,05
\(b,m_{CuO}=0,05.80=4\left(g\right)\)
\(c,C_{M\left(CuCl_2\right)}=\dfrac{0,05}{0,2}=0,25\left(M\right)\)
nHCl=0,3.2=0,6(mol)
a) PTHH: CuO +2 HCl -> CuCl2 + H2O
0,3_______________0,6___0,3(mol)
b) mCuO=0,3.80=24(g)
c) VddCuCl2=VddHCl=0,3(l)
=>CMddCuCl2=0,3/0,3=1(M)
d) m(muối)=0,3.135=40,5(g)
nAl= 0,5(mol)
a) PTHH: 2 Al + 6 HCl -> 2 AlCl3 + 3 H2
nHCl= 6/2 . 0,5= 1,5(mol)
=>mHCl= 1,5.36,5=54,75(mol)
=> mddHCl= (54,75.100)/18,25=300(g)
b) nH2= 3/2. 0,5=0,75(mol)
=>V(H2,đktc)=0,75.22,4=16,8(l)
c) nAlCl3= nAl= 0,5(mol) -> mAlCl3=0,5. 133,5=66,75(g)
mddAlCl3=mAl+ mddHCl - mH2= 13,5 + 300-0,75.2=312(g)
=> \(C\%ddAlCl3=\dfrac{66,75}{312}.100\approx21,394\%\)
\(n_{CuO}=\dfrac{32}{80}=0,4(mol)\\ CuO+2HCl\to CuCl_2+H_2\\ \Rightarrow n_{HCl}=0,8(mol);n_{CuCl_2}=n_{H_2}=0,4(mol)\\ a,m_{dd_{HCl}}=\dfrac{0,8.36,5}{20\%}=146(g)\\ b,m_{CuCl_2}=0,4.135=54(g)\\ c,C\%_{CuCl_2}=\dfrac{54}{32+146-0,4.2}.100\%=30,47\%\)
\(CuO + 2HCl \rightarrow CuCl_2 + H_2O\)
\(n_{CuO}= \dfrac{32}{80}= 0,4 mol\)
Theo PTHH:
\(n_{HCl}= 2n_{CuO}= 0,8 mol\)
\(\Rightarrow m_{HCl}= 0,8 . 36,5=29,2 g\)
\(\rightarrow m_{dd HCl}= \dfrac{29,2 . 100%}{20%}= 146 g\)
b) Muối tạo thành là CuCl2
Theo PTHH:
\(n_{CuCl_2}= n_{CuO}= 0,4 mol\)
\(\Rightarrow m_{CuCl_2}= 0,4 . 135= 54g\)
c)
\(m_{dd sau pư}= m_{CuO} + m_{dd HCl}= 32 + 146=178 g\)
C%= \(\dfrac{54}{178} . 100\)%= 30,337 %
Tương tự bài 1, ta có:
m 4 o x i t + m H 2 S O 4 = m m u o i + m H 2 O s a n p h a m
⇔ m m u o i = m 4 o x i t + m H 2 S O 4 - m H 2 O s a n p h a m
⇔ m m u o i = 3,61+0,4.0,15.98-0,4.0,15.18
⇔ m m u o i = 8,41g
⇒ Chọn A.