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\(n_{Zn}=\dfrac{3,25}{65}=0,05\left(mol\right)\)
\(Zn+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2\)
0,05 0,1 0,05 0,05 ( mol )
\(V_{H_2}=0,05.22,4=1,12\left(l\right)\)
\(m_{dd_{CH_3COOH}}=\dfrac{0,1.60.100}{20}=30\left(g\right)\)
\(m_{ddspứ}=3,25+30-0,05.2=33,15\left(g\right)\)
\(C\%_{\left(CH_3COO\right)_2Zn}=\dfrac{0,05.183}{33,15}.100=27,6\%\)
\(a) Zn + 2CH_3COOH \to (CH_3COO)_2Zn + H_2\\ b) n_{H_2} = n_{Zn} =\dfrac{13}{65} = 0,2(mol)\\ V_{H_2} = 0,2.22,4 = 4,48(lít)\\ c) n_{CH_3COOH} = 2n_{Zn} = 0,4(mol)\\ V_{dd\ CH_3COOH} = \dfrac{0,4}{0,6} = 0,667(lít)\)
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đổi 500ml = 0,5l
n(CH\(_3\)COOH)\(_2\)Mg= \(\dfrac{14,2}{142}\)= 0,1mol
2CH3COOH + Mg \(\rightarrow\) (CH3COO)2Mg + H2
0,2mol 0,1mol 0,1mol
a/ CCH3COOH= \(\dfrac{0,2}{0,5}\)=0,4M
b/ VH\(_2\) 0,1 . 22,4 = 2,24l
c/ nCH\(_3\)COOH= 0,2mol
CH3COOH + NaOH \(\rightarrow\) CH3COONa + H2
0,2mol 0,2mol
V\(_{dd_{NaOH}}\)= \(\dfrac{0,2}{0,5}\)= 0,4l
Gọi x,y,z lần lượt là số mol của Al,Mg,Zn
PT:
2Al + 6HCl--->2AlCl3 + 3H2
x-------3x----------------------1,5x mol
Mg + 2HCl--->MgCl2 + H2
y-----2y----------------------y mol
Zn + 2HCl--->ZnCl2 + H2
z----2z--------------------z mol
b.
Số mol H2: nH2=16,352/22,4=0,73 mol
1,5x+y+z=0,73
27x = 24y =>x=8y/9
=>7y/3 +z =0,73 (*)
27x + 24y + 65z=19,6
27x = 24y
=> 48y + 65z =19,6 (**)
Từ (*),(**)
=>y=0,27 => mMg =6,48 g
z=0,1=>mZn = 6,5 g
x=0,24=>mAl =6,48g
c.
nHCl =2nH2
=>nHCl =2.0,73=1,46 mol
=>V dd=1,46/2=0,73(l)
a, \(n_{Mg}=\dfrac{2,4}{24}=0,1\left(mol\right)\)
PT: \(Mg+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Mg+H_2\)
Theo PT: \(n_{H_2}=n_{Mg}=0,1\left(mol\right)\Rightarrow V_{H_2}=0,1.24,79=2,479\left(l\right)\)
b, \(n_{\left(CH_3OO\right)_2Mg}=n_{Mg}=0,1\left(mol\right)\)
Ta có: m dd sau pư = 2,4 + 100 - 0,1.2 = 102,2 (g)
\(\Rightarrow C\%_{\left(CH_3COO\right)_2Mg}=\dfrac{0,1.142}{102,2}.100\%\approx13,89\%\)
c, Bạn bổ sung thêm CM của NaOH nhé.
\(n_{CO_2\left(đktc\right)}=\dfrac{10,64}{22,4}=0,475\left(mol\right)\\a, K_2CO_3+2CH_3COOH\rightarrow2CH_3COOK+CO_2+H_2O\\ b,n_{K_2CO_3}=n_{CO_2}=0,475\left(mol\right)\\ \Rightarrow m_{K_2CO_3}=138.0,475=65,55\left(g\right)\\ n_{CH_3COOH}=0,475.2=0,95\left(mol\right)\\ C\%_{ddCH_3COOH}=\dfrac{0,95.60}{200}.100=28,5\%\)
a. nMg = \(\dfrac{9,6}{24}\) = 0,4 (mol)
Mg + 2CH3COOH ---> 2(CH3COO)2Mg +H2
(mol) 0,4 0,8 0,4
=> V H2 = 0,4.22,4=8,96 (l)
c. Vdd CH3COOH = \(\dfrac {0,8} {0,5}\) = 1,6 (l)
a) Mg + 2CH3COOH ------ (CH3COO)2Mg + H2