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Anh bổ sung câu c)
\(C_{MddNa_2SO_4}=\dfrac{0,25}{0,09879+0,5}=0,4175\left(M\right)\)
\(n_{Na_2O}=\dfrac{15,5}{62}=0,25\left(mol\right)\\ PTHH:Na_2O+H_2O\rightarrow2NaOH\\ n_{NaOH}=2.0,25=0,5\left(mol\right)\\ a,C_{MddNaOH}=\dfrac{0,5}{0,5}=1\left(M\right)\\ b,2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\\ n_{H_2SO_4}=n_{Na_2SO_4}=\dfrac{0,5}{2}=0,25\left(mol\right)\\ m_{H_2SO_4}=0,25.98=24,5\left(g\right)\\ m_{ddH_2SO_4}=\dfrac{24,5.100}{20}=122,5\left(g\right)\\ V_{ddH_2SO_4}=\dfrac{122,5}{1,14}\approx107,456\left(ml\right)\\ c,V_{ddsau}=V_{ddNaOH}+V_{ddH_2SO_4}\approx0,5+0,107456=0,607456\left(l\right)\\C_{MddNa_2SO_4}\approx\dfrac{ 0,25}{0,607456}\approx0,411552\left(M\right)\)
\(n_{K_2O}=\dfrac{23.5}{94}=0.25\left(mol\right)\)
\(K_2O+H_2O\rightarrow2KOH\)
\(0.25...................0.5\)
\(C_{M_{KOH}}=\dfrac{0.5}{0.5}=1\left(M\right)\)
\(2KOH+H_2SO_4\rightarrow K_2SO_4+H_2O\)
\(0.5............0.25............0.25\)
\(m_{dd_{H_2SO_4}}=\dfrac{0.25\cdot98}{20\%}=122.5\left(g\right)\)
\(V_{dd_{H_2SO_4}}=\dfrac{122.5}{1.14}=107.5\left(ml\right)=0.1075\left(l\right)\)
\(C_{M_{K_2SO_4}}=\dfrac{0.25}{0.1075+0.5}=0.4\left(M\right)\)
a, PT: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
b, Ta có: \(n_{Fe}=\dfrac{19,6}{56}=0,35\left(mol\right)\)
Theo PT: \(n_{H_2}=n_{Fe}=0,35\left(mol\right)\Rightarrow V_{H_2}=0,35.22,4=7,84\left(l\right)\)
c, \(n_{H_2SO_4}=n_{Fe}=0,35\left(mol\right)\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,35}{0,2}=1,75\left(M\right)\)
d, \(n_{FeSO_4}=n_{Fe}=0,35\left(mol\right)\Rightarrow m_{FeSO_4}=0,35.152=53,2\left(g\right)\)
e, \(C_{M_{FeSO_4}}=\dfrac{0,35}{0,2}=1,75\left(M\right)\)
d, \(n_{H_2SO_4}=0,25.1,6=0,4\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{n_{Fe}}{1}< \dfrac{n_{H_2SO_4}}{1}\), ta được H2SO4 dư.
Theo PT: \(n_{H_2SO_4\left(pư\right)}=n_{Fe}=0,35\left(mol\right)\)
\(\Rightarrow n_{H_2SO_4\left(dư\right)}=0,4-0,35=0,05\left(mol\right)\)
\(\Rightarrow m_{H_2SO_4\left(dư\right)}=0,05.98=4,9\left(g\right)\)
Ta có: \(n_{Na_2O}=\dfrac{3,1}{62}=0,05\left(mol\right)\)
PTHH: Na2O + H2O ---> 2NaOH (1)
a. Theo PT(1): \(n_{NaOH}=2.n_{Na_2O}=2.0,05=0,1\left(mol\right)\)
=> \(C_{M_{NaOH}}=\dfrac{0,1}{2}=0,05M\)
b. PTHH: 2NaOH + H2SO4 ---> Na2SO4 + 2H2O
Theo PT: \(n_{H_2SO_4}=\dfrac{1}{2}.n_{NaOH}=\dfrac{1}{2}.0,1=0,05\left(mol\right)\)
=> \(m_{H_2SO_4}=0,05.98=4,9\left(g\right)\)
Ta có: \(C_{\%_{H_2SO_4}}=\dfrac{4,9}{m_{dd_{H_2SO_4}}}.100\%=20\%\)
=> \(m_{dd_{H_2SO_4}}=24,5\left(g\right)\)
a, \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
b, \(n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\)
Theo PT: \(n_{H_2SO_4}=n_{H_2}=\dfrac{3}{2}n_{Al}=0,6\left(mol\right)\)
\(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,6.98}{25\%}=235,2\left(g\right)\)
c, \(n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}n_{Al}=0,2\left(mol\right)\)
\(\Rightarrow C\%_{Al_2\left(SO_4\right)_3}=\dfrac{0,2.342}{10,8+235,2-0,6.2}.100\%\approx27,94\%\)
Na2O + H2O → 2NaOH
1 1 2
0,1 0,2
a). nNa2O=\(\dfrac{6,2}{62}\)= 0,1(mol)
CM=\(\dfrac{n}{V}\)=\(\dfrac{0,1}{4}\)= 0,025M
b). Na2O + H2SO4 → Na2SO4 + H2O
1 1 1 1
0,1 0,1
mH2SO4= n.M = 0,1 . 98 = 9,8g
⇒mddH2SO4= mct=\(\dfrac{mct.100\%}{C\%}\)= \(\dfrac{9,8.100}{20}\)= 49(g).