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Chất rắn không tan là Cu.
⇒ mCu = 9 (g)
PT: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
Gọi: \(\left\{{}\begin{matrix}n_{Al}=x\left(mol\right)\\n_{Fe}=y\left(mol\right)\end{matrix}\right.\) ⇒ 27x + 56y = 20 - 9 (1)
Ta có: \(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)
Theo PT: \(n_{H_2}=\dfrac{3}{2}n_{Al}+n_{Fe}=\dfrac{3}{2}x+y=0,4\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,2\left(mol\right)\\y=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Cu}=\dfrac{9}{20}.100\%=45\%\\\%m_{Al}=\dfrac{0,2.27}{20}.100\%=27\%\\\%m_{Fe}=28\%\end{matrix}\right.\)
\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PTHH:
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
0,2 0,2 0,2 0,2
\(a,\%m_{Fe}=\dfrac{0,2.56}{20}.100\%=56\%\)
\(\%m_{Cu}=100\%-56\%=44\%\)
\(b,C_{M\left(H_2SO_4\right)}=\dfrac{0,2}{0,1}=2\left(M\right)\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
\(1\) \(1\) \(1\)
\(0,2\) \(0,2\) \(0,2\)
\(n_{H_2}=\dfrac{V}{22,4}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
\(m_{Fe}=n.M=0,2.56=11,2\left(g\right)\)
\(^0/_0Fe=\dfrac{11,2}{20}.100^0/_0=56^0/_0\)
\(^0/_0Cu=100^0/_0-56^0/_0=44^0/_0\)
\(C_{M_{H_2SO_4}}=\dfrac{n}{V_{dd}}=\dfrac{0,2}{0,1}=2M\)
a, \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
b, Ta có: \(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)
Theo PT: \(n_{Al}=\dfrac{2}{3}n_{H_2}=\dfrac{4}{15}\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{\dfrac{4}{15}.27}{10}.100\%=72\%\\\%m_{Cu}=28\%\end{matrix}\right.\)
c, Theo PT: \(n_{H_2SO_4}=n_{H_2}=0,4\left(mol\right)\)
\(\Rightarrow m_{H_2SO_4}=0,4.98=39,2\left(g\right)\)
\(\Rightarrow C\%_{H_2SO_4}=\dfrac{39,2}{300}.100\%\approx13,067\%\)
a) PTHH: 2Al + 6 HCl -> 2 AlCl3 + 3 H2
x___________3x______________1,5x(mol)
Fe +2 HCl -> FeCl2 + H2
y___2y____y______y(mol)
b) Ta có: m(rắn)= mCu=0,4(g)
=> m(Al, Fe)=1,5-mCu=1,5-0,4=1,1(g)
nH2= 0,04(mol)
Ta lập hpt:
\(\left\{{}\begin{matrix}27x+56y=1,1\\1,5x+y=0,04\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,02\\y=0,01\end{matrix}\right.\)
=> mAl=27.0,02=0,54(g)
mFe=56.0,01=0,56(g)
PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
Ta có: \(n_{H_2}=\dfrac{0,896}{22,4}=0,04\left(mol\right)\)
Theo PT: \(n_{Zn}=n_{H_2}=0,04\left(mol\right)\Rightarrow m_{Zn}=0,04.65=2,6\left(g\right)\)
⇒ mCu = 9 - 2,6 = 6,4 (g)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{2,6}{9}.100\%\approx28,89\%\\\%m_{Cu}\approx71,11\%\end{matrix}\right.\)
a, Ta có: 27nAl + 56nFe = 27,8 (1)
PT: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
Theo PT: \(n_{H_2}=\dfrac{3}{2}n_{Al}+n_{Fe}=\dfrac{17,353}{24,79}=0,7\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{Al}=0,2\left(mol\right)\\n_{Fe}=0,4\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,2.27}{27,8}.100\%\approx19,42\%\\\%m_{Fe}\approx80,58\%\end{matrix}\right.\)
b, \(n_{H_2SO_4}=n_{H_2}=0,7\left(mol\right)\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,7}{0,5}=1,4\left(M\right)\)
\(n_{H_2}=\dfrac{2,24}{22,4}=0,1(mol)\\ a,PTHH:Fe+2HCl\to FeCl_2+H_2\\ b,n_{Fe}=n_{H_2}=0,1(mol)\\ \Rightarrow m_{Fe}=0,1.56=5,6(g)\\ \Rightarrow \%_{Fe}=\dfrac{5,6}{12}.100\%=46,67\%\\ \Rightarrow \%_{Cu}=100\%-46,67\%=53,33\%\\ c,n_{HCl}=2n_{H_2}=0,2(mol)\\ \Rightarrow C_{M_{HCl}}=\dfrac{0,2}{0,2}=1M\)
a)
H2SO4(loãng, dư)+CuO→ H2O+ CuSO4(1)
(mol)
H2SO4(loãng, dư)+Cu→không phản ứng
Cu+ 2H2SO4(đặc, nóng)→ CuSO4+ SO2+ 2H2O(2)
(mol) 0,15 0,3 0,15 0,15
b)
\(n_{SO_2}=\dfrac{V}{22,4}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
\(m_{Cu}=n.M=0,15.64=9,6\left(gam\right)\)
→\(m_{CuO}=m_{hh}-m_{Cu}=17,6-9,6=8\left(gam\right)\)
=>\(C\%_{Cu}=\dfrac{9,6}{17,6}.100\%=54,54\%\)
\(C\%_{CuO}=\dfrac{8}{17,6}.100\%=0,45\%\)
a)Zn +H2SO4 -> ZnSO4 +H2
Fe +H2SO4 -> FeSO4 +H2
Cu +H2SO4 -> CUSO4+H2
đặt số mol 3 KL Zn, Fe, Cu lần lượt là a, b, c (mol), ta có pt theo đề bài:
65a+56b+64c=21.6 (1)
c=3/64 (2)
a+b=6.72/22.4 (3)
Từ (1)(2)(3)==> a=0.2(mol), b=0.1(mol), c=3/64(mol)
==>%Zn=0.2 x 65 x100/21.6 = 60.185%
%Fe=0.1 x 56 x 100/21.6 = 25.925%
%Cu=100%-( 60.185% + 25.925% )= 13.89%
Cu + H2SO4 -/->
Gọi x,y là số mol lần lượt của Al và Fe
2Al+3H2SO4->Al2(SO4)3+ 3H2 (1)
Fe + H2SO4 -> FeSO4 + H2 (2) nH2 = 8.96/22.4 = 0.4(Mol)
(1) nAl = 2x(mol)-> nH2 = 3x (mol)
(2) nFe= y -> H2 = y
mAl=2x * 27 = 54(g)
mFe = y * 56 = 56y
Từ đó ta có hệ pt :
3x+y=0.4.
54x+56y=11
Bấm mt ta đc:
x= 0.1. y= 0.1
%Cu= 9/20 * 100 = 45%
%Fe = 5.6/20 * 100= 28%
%Al = 5.4/20 *100= 27%