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\(n_{CH_4}=\dfrac{3,2}{16}=0,2\left(mol\right)\)
PTHH: CH4 + 2O2 --to--> CO2 + 2H2O
0,2----------------->0,2--->0,4
m1 = \(m_{CO_2}+m_{H_2O}=0,2.44+0,4.18=16\left(g\right)\)
PTHH: Ca(OH)2 + CO2 --> CaCO3 + H2O
0,2------>0,2
=> \(m_2=m_{CaCO_3}=0,2.100=20\left(g\right)\)
\(n_{C_2H_4}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\\ C_2H_4+3O_2\rightarrow\left(t^o\right)2CO_2+2H_2O\\ n_{CO_2}=2.n_{C_2H_4}=2.0,5=1\left(mol\right)\\ CO_2+Ca\left(OH\right)_2\rightarrow CaCO_3+H_2O\\ n_{CaCO_3}=n_{CO_2}=1\left(mol\right)\\ m_{kết.tủa}=m_{CaCO_3}=100.1=100\left(g\right)\\ n_{O_2}=3.n_{C_2H_4}=3.0,5=1,5\left(mol\right)\\ V_{kk}=\dfrac{100}{20}.V_{O_2\left(đktc\right)}=5.\left(1,5.22,4\right)=168\left(lít\right)\)
Gọi \(\left\{{}\begin{matrix}n_{CO}=a\left(mol\right)\\n_{CH_4}=b\left(mol\right)\end{matrix}\right.\Rightarrow28a+16b=2,04\left(1\right)\)
\(n_{CaCO_3}=\dfrac{9,6}{100}=0,096\left(mol\right)\)
PTHH: \(2CO+O_2\xrightarrow[]{t^o}2CO_2\)
a------------>a
\(CH_4+2O_2\xrightarrow[]{t^o}CO_2+2H_2O\)
b---------------->b
\(Ca\left(OH\right)_2+CO_2\rightarrow CaCO_3\downarrow+H_2O\)
0,096<--0,096
`=> a + b = 0,096 (2)`
`(1), (2) => a = 0,042; b = 0,054`
\(\Rightarrow\left\{{}\begin{matrix}\%V_{CO}=\dfrac{0,042}{0,042+0,054}.100\%=43,75\%\\\%V_{CH_4}=100\%-43,75\%=56,25\%\end{matrix}\right.\)
a, \(n_{C_2H_4}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)
PT: \(C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\)
\(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_{3\downarrow}+H_2O\)
Theo PT: \(n_{CaCO_3}=n_{CO_2}=2n_{C_2H_4}=0,1\left(mol\right)\)
\(\Rightarrow m_{CaCO_3}=0,1.100=10\left(g\right)\)
b, Theo PT: \(n_{O_2}=3n_{C_2H_4}=0,15\left(mol\right)\Rightarrow V_{O_2}=0,15.22,4=3,36\left(l\right)\)
\(\Rightarrow V_{kk}=\dfrac{V_{O_2}}{20\%}=16,8\left(l\right)\)
a)\(n_{CaCO_3}=\dfrac{2}{100}=0,02mol\)
\(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_3+H_2O\)
0,02 0,02
\(CH_4+2O_2\rightarrow CO_2+2H_2O\)
0,02 0,02
\(V_{CH_4}=0,02\cdot22,4=0,448l\)
b) \(V_{CH_4}=90\%V_{tựnhiên}\)
\(\Rightarrow V_{tựnhiên}=\dfrac{V_{CH_4}}{90\%}=\dfrac{0,448}{90\%}\approx0,5l\)