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nCH4 = 4,48/22,4 = 0,2 (mol)
PTHH: CH4 + 2O2 -> (t°) CO2 + 2H2O
Mol: 0,2 ---> 0,4 ---> 0,2 ---> 0,4
VO2 = 0,4 . 22,4 = 8,96 (l)
VCO2 = 0,2 . 22,4 = 4,48 (l)
Vkk = 8,96 . 5 = 44,8 (l)
a)
\(CH_4 + 2O_2 \xrightarrow{t^o} CO_2 + 2H_2O\\ C_2H_4 + 3O_2 \xrightarrow{t^o} 2CO_2 + 2H_2O\\ CO_2 + Ca(OH)_2 \to CaCO_3 + H_2O\\ C_2H_4 + Br_2 \to C_2H_4Br_2\\ b) n_{C_2H_4} = n_{Br_2} = \dfrac{8}{160}=0,05(mol)\\ n_{CaCO_3} = n_{CO_2} = n_{CH_4} + 2n_{C_2H_4} = \dfrac{50}{100} = 0,5(mol)\\ \Rightarrow n_{CH_4} = 0,5 - 0,05.2 = 0,4(mol)\\ \%m_{CH_4}= \dfrac{0,4.16}{0,4.16 + 0,05.28}.100\% = 82,05\%\\ \%m_{C_2H_4} =100\% - 82,05\% = 17,95\%\)
\(n_{CH_4}=\dfrac{2,24}{22,4}=0,1mol\)
\(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)
0,1 0,2 0,1
\(V_{O_2}=0,2\cdot22,4=4,48l\)
\(V_{CO_2}=0,1\cdot22,4=2,24l\)
\(n_{C_2H_2}=\dfrac{2,8}{22,4}=0,125\left(mol\right)\\ a,2C_2H_2+5O_2\rightarrow\left(t^o\right)4CO_2+2H_2O\\ b,n_{CO_2}=0,125.2=0,25\left(mol\right)\\ m_{CO_2}=0,25.44=11\left(g\right)\\ c,n_{O_2}=\dfrac{5}{2}.0,125=0,3125\left(mol\right)\\ V_{O_2\left(đktc\right)}=0,3125.22,4=7\left(l\right)\\ \Rightarrow V_{kk\left(đktc\right)}=\dfrac{100}{20}.7=35\left(l\right)\)
\(n_{O_2}=\dfrac{8}{32}=0.25\left(mol\right)\)
\(CH_4+2O_2\underrightarrow{t^0}CO_2+2H_2O\)
\(0.125....0.25....0.125\)
\(m_{CH_4}=0.125\cdot16=2\left(g\right)\)
\(V_{CO_2}=0.125\cdot22.4=2.8\left(l\right)\)
\(Ca\left(OH\right)_2+CO_2\rightarrow CaCO_3+H_2O\)
\(............0.125.....0.125\)
\(m_{CaCO_3}=0.125\cdot100=12.5\left(g\right)\)
a)
\(n_{Br_2}=\dfrac{8}{160}=0,05\left(mol\right)\)
PTHH: C2H4 + Br2 --> C2H4Br2
0,05<-0,05
=> \(n_{CH_4}=\dfrac{3,36}{22,4}-0,05=0,1\left(mol\right)\)
\(\%m_{CH_4}=\dfrac{0,1.16}{0,1.16+0,05.28}.100\%=53,33\%\)
\(\%m_{C_2H_4}=\dfrac{0,05.28}{0,1.16+0,05.28}.100\%=46,67\%\)
b)
PTHH: CH4 + 2O2 --to--> CO2 + 2H2O
0,1-->0,2
C2H4 + 3O2 --to--> 2CO2 + 2H2O
0,05--->0,15
=> \(V_{O_2}=\left(0,2+0,15\right).22,4=7,84\left(l\right)\)
Bài 2.
\(n_{C_2H_2}=\dfrac{4,48}{22,4}=0,2mol\)
\(n_{O_2}=\dfrac{6,72}{22,4}=0,3mol\)
\(2C_2H_2+5O_2\rightarrow\left(t^o\right)4CO_2+2H_2O\)
0,2 > 0,3 ( mol )
0,3 0,24 0,12 ( mol )
\(m_{CO_2}=0,24.44=10,56g\)
\(m_{H_2O}=0,12.18=2,16g\)
PTHH: 2CO + O2→2CO2
C2H4 + 3O2→ 2CO2 +2 H2O
nH2O= mM=\(\dfrac{1,8}{18}\)=0,1(mol)
nC2H4=\(\dfrac{1}{2}\).nH2O=\(\dfrac{1}{2}\).0,1=0,05(mol)
=> VC2H4=n.22,4=0,05.22,4=1,12(lít)
->VCO=4,48 − 1,12= 3,36(lít)
b) nCO2 (1)=nCO=\(\dfrac{3,36}{22,4}\)=0,15(mol)
mCO2 (1)=n.M=0,15.44=6,6(g)
nCO2 (2)=2.nC2H4=2.0,05=0,1(mol)
mCO2 (2)=n.M=0,1.44=4,4(g)
mCO2 sau pư=6,6 + 4,4= 11(g)
a, \(n_{CO_2}=\dfrac{17,6}{44}=0,4\left(mol\right)\)
CH4 + 2O2 -----to---> CO2 + 2H2O
x x
C2H4 + 3O2 -----to---> 2CO2 + 2H2O
y 2y
Ta có hệ pt: \(\left\{{}\begin{matrix}16x+28y=6\\x+2y=0,4\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,2\\y=0,1\end{matrix}\right.\)
\(\%m_{CH_4}=\dfrac{0,2.16.100\%}{6}=53,33\%;\%m_{C_2H_4}=100\%-53,33\%=46,67\%\)
b, \(\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,2.22,4.100\%}{\left(0,2+0,1\right).22,4}=66,67\%\\\%V_{C_2H_4}=100\%-66,67\%=33,33\%\end{matrix}\right.\)