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a) PTHH: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
Ta có: \(n_{C_2H_4}=\dfrac{5,6}{28}=0,2\left(mol\right)=n_{C_2H_4Br_2}\) \(\Rightarrow m_{C_2H_4Br_2}=0,2\cdot188=37,6\left(g\right)\)
b) Ta có: \(n_{CH_4}=\dfrac{11,2}{22,4}-0,2=0,3\left(mol\right)\)
Bảo toàn nguyên tố: \(n_{CO_2}=n_{CH_4}+2n_{C_2H_4}=0,7\left(mol\right)\)
\(\Rightarrow V_{CO_2}=0,7\cdot22,4=15,68\left(l\right)\)
Gọi số mol CH4, C2H6 là a, b
=> a+b = \(\dfrac{5,6}{22,4}=0,25\)
Có \(\dfrac{16a+30b}{a+b}=0,6.29=17,4\)
=> a = 0,225; b = 0,025
PTHH: CH4 + 2O2 --to--> CO2 + 2H2O
____0,225->0,45------->0,225->0,45
2C2H6 + 7O2 --to--> 4CO2 + 6H2O
0,025->0,0875----->0,05-->0,075
=> VO2 = (0,45+0,0875).22,4 = 12,04 (l)
mCO2 = (0,225 + 0,05).44 = 12,1(g)
mH2O = (0,45+ 0,075).18 = 9,45(g)
Theo gt ta có: $n_{O_2}=0,6(mol);n_{hh}=0,25(mol)$
a, $CH_4+2O_2\rightarrow CO_2+2H_2O$
$C_2H_4+3O_2\rightarrow 2CO_2+2H_2O$
Gọi số mol CH4 và C2H4 lần lượt là a;b(mol)
Ta có: $a+b=0,25;2a+3b=0,6\Rightarrow a=0,15;b=0,1$
b, Suy ra $\%V_{CH_4}=60\%;\%V_{C_2H_4}=40\%$
c, Ta có: $n_{CaCO_3}=n_{CO_2}=0,15+0,1.2=0,35(mol)\Rightarrow m_{CaCO_3}=35(g)$
\(a)\\ CH_4 + 2O_2 \xrightarrow{t^o} CO_2 + 2H_2O\\ C_2H_4 + 3O_2 \xrightarrow{t^o} 2CO_2 + 2H_2O\\ b)\ V_{CH_4} = a(lít) ; V_{C_2H_4} = b(lít)\\ \Rightarrow a + b = 5,6(1)\\ V_{O_2} = 2a + 3b = 13,44(2)\\ (1)(2)\Rightarrow a = 3,36 ; b = 2,24\\ \%V_{CH_4} = \dfrac{3,36}{5,6}.100\% = 60\%\\ \%V_{C_2H_4} = 40\%\\ c) V_{CO_2} = a + 2b = 7,84(lít)\\\)
\(CO_2 + Ca(OH)_2 \to CaCO_3 + H_2O\\ n_{CaCO_3} = n_{CO_2} = \dfrac{7,84}{22,4} = 0,35(mol)\\ \Rightarrow m_{CaCO_3} = 0,35.100 = 35(gam)\)
a: \(C+O_2\rightarrow CO_2\)(ĐK: t độ)
x x x
\(S+O_2\rightarrow SO_2\)(ĐK: t độ)
y y y
b: \(n_{O_2}=\dfrac{11.2}{22.4}=0.5\left(mol\right)\)
Theo đề, ta có hệ:
12x+32y=10 và x+y=0,5
=>x=0,3 và y=0,2
\(m_C=0.3\cdot12=3.6\left(g\right)\)
\(m_S=0.2\cdot32=6.4\left(g\right)\)
c: \(n_{CO_2}=n_C=0.3\left(mol\right)\)
\(n_{SO_2}=n_S=0.2\left(mol\right)\)
\(V_{khí}=22.4\left(0.3+0.2\right)=11.2\left(lít\right)\)
\(n_{O_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
PTHH :
\(C+O_2\rightarrow\left(t^o\right)CO_2\)
x x x
\(S+O_2\rightarrow\left(t^o\right)SO_2\)
y y y
Gọi n C = x
n S = y (mol)
Ta có hệ PT :
\(\left\{{}\begin{matrix}12x+32y=10\\x+y=0,5\end{matrix}\right.\)
\(\rightarrow x=0,3;y=0,2\)
\(m_C=0,3.12=3,6\left(g\right)\)
\(m_S=0,2.32=6,4\left(g\right)\)
\(c,V_{hhk}=\left(0,3+0,2\right).22,4=11,2\left(l\right)\)
a, \(CH_4+2O_2\underrightarrow{t^o}CO_2+H_2O\)
\(2C_2H_2+5O_2\underrightarrow{t^o}4CO_2+2H_2O\)
Ta có: \(n_{CH_4}+n_{C_2H_2}=\dfrac{33,6}{22,4}=1,5\left(mol\right)\left(1\right)\)
Theo PT: \(n_{CO_2}=n_{CH_4}+2n_{C_2H_2}=\dfrac{56}{22,4}=2,5\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{CH_4}=0,5\left(mol\right)\\n_{C_2H_2}=1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,5.22,4}{33,6}.100\%\approx33,33\%\\\%V_{C_2H_2}\approx66,67\%\end{matrix}\right.\)
b, Theo PT: \(n_{O_2}=2n_{CH_4}+\dfrac{5}{2}n_{C_2H_2}=3,5\left(mol\right)\Rightarrow m_{O_2}=3,5.32=112\left(g\right)\)
ta có :
nBr2=\(\dfrac{16}{160}=0,1mol\)
C2H4+Br2->C2H4Br2
0,1------0,1
=>VC2H4=0,1.22,4=2,24l
=>VCH4=3,36l->n CH4=0,15 mol
->%VC2H4=\(\dfrac{2,24}{5,6}.100\)=40%
=>%VCH4=60%
c)
CH4+2O2-to>CO2+2H2O
0,15---------------0,15
C2H4+3O2--to>2CO2+2H2O
0,1--------------------0,2
=>m CaCO3=0,35.100=35g
\(Đặt:n_{CH_4}=a\left(mol\right);n_{C_2H_4}=b\left(mol\right)\left(a,b>0\right)\\ PTHH:CH_4+2O_2\rightarrow\left(t^o\right)CO_2+2H_2O\\ C_2H_4+3O_2\rightarrow\left(t^o\right)2CO_2+2H_2O\\ \Rightarrow\left\{{}\begin{matrix}a+b=0,25\\2a+3b=0,625\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,125\\b=0,125\end{matrix}\right.\\ a,m_{hh}=m_{CH_4}+m_{C_2H_4}=16.0,125+28.0,125=5,5\left(g\right)\\ b,V_{CO_2\left(đktc\right)}=22,4.\left(a+2b\right)=8,4\left(l\right)\)