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nP = 6.2/31 = 0.2 (mol)
nO2 = 6.72/22.4 = 0.3 (mol)
4P + 5O2 -to-> 2P2O5
0.2___0.25_____0.1
mO2 dư = ( 0.3 - 0.25) * 32 = 1.6(g)
mP2O5 = 0.1*142 = 14.2 (g)
Ta có: \(n_P=\dfrac{6.2}{31}=0.29mol\)
\(n_{O_2}=\dfrac{6.72}{22.4}=0.3mol\)
PTHH:
\(4P+5O_2\underrightarrow{t^o}2P_2O_5\)
ta có:
\(\left\{{}\begin{matrix}\dfrac{n_{P\left(bra\right)}}{nP_{\left(pthh\right)}}=\dfrac{0.2}{4}=0.05\\\dfrac{n_{O_2\left(bra\right)}}{n_{O_2}\left(pthh\right)}=\dfrac{0.3}{5}=0.06\end{matrix}\right.\)
=> \(O_2\) dư
\(4P+5O_2\underrightarrow{t^o}2P_2O_5\)
4 ----------->2
0.2---------->0.1=nP2O5
=>\(m_{P_2O_5}=142.0.1=14.2\left(g\right)\)
\(n_P=\dfrac{12,4}{31}=0,4\left(mol\right)\)
\(n_{O_2}=\dfrac{18}{32}=0,5625\left(mol\right)\)
PTHH :
\(4P+5O_2\rightarrow\left(t^o\right)2P_2O_5\)
0,4 0,5 0,2
\(\dfrac{0,4}{4}< \dfrac{0,5625}{5}\) --> O2 dư sau phản ứng
\(m_{O_2dư}=\left(0,5625-0,5\right).32=2\left(g\right)\)
P2O5 được tạo thành.
\(m_{P_2O_5}=0,2.142=28,4\left(g\right)\)
\(n_P=\dfrac{12,4}{31}=0,4\left(mol\right)\)
\(n_{O_2}=\dfrac{18}{32}=0,5625\left(mol\right)\)
PT: \(4P+5O_2\underrightarrow{t^o}2P_2O_5\)
a, Xét tỉ lệ: \(\dfrac{0,4}{4}< \dfrac{0,5625}{5}\), ta được O2 dư.
Theo PT: \(n_{O_2\left(pư\right)}=\dfrac{5}{4}n_P=0,5\left(mol\right)\Rightarrow n_{O_2\left(dư\right)}=0,0625\left(mol\right)\)
\(\Rightarrow m_{O_2\left(dư\right)}=0,0625.32=2\left(g\right)\)
b, P2O5 được tạo thành.
Theo PT: \(n_{P_2O_5}=\dfrac{1}{2}n_P=0,2\left(mol\right)\)
\(\Rightarrow m_{P_2O_5}=0,2.142=28,4\left(g\right)\)
nP = 2,48/31 = 0,08 (mol)
PTHH: 4P + 5O2 -> (t°) 2P2O5
Mol: 0,08 ---> 0,1 ---> 0,04
mP2O5 = 0,04 . 142 = 5,68 (g)
b) nO2 = 4/32 = 0,125 (mol)
So sánh: 0,125 > 0,1 => O2 dư
nO2 (dư) = 0,125 - 0,1 = 0,025 (mol)
mO2 (dư) = 0,025 . 32 = 0,8 (g)
nP=\(\dfrac{62}{31}\)=0,2(mol)
nO2=\(\dfrac{7,84}{22,4}\)=0,35(mol)
PTHH:4P+5O2to→2P2O5
tpứ: 0,2 0,35
pứ: 0,2 0,25 0,1
spứ: 0 0,1 0,1
a)chất còn dư là oxi
mO2dư=0,1.32=3,2(g)
b)mP2O5=n.M=0,1.142=14,2(g)
\(a.n_P=0,2\left(mol\right);n_{O_2}=0,35\left(mol\right)\\ 4P+5O_2-^{t^o}\rightarrow2P_2O_5\\ LTL:\dfrac{0,2}{4}< \dfrac{0,35}{5}\\ \Rightarrow SauphảnứngO_2dư\\ n_{O_2\left(pứ\right)}=\dfrac{5}{4}n_P=0,25\left(mol\right)\\ \Rightarrow m_{P\left(dư\right)}=\left(0,35-0,25\right).32=3,2\left(g\right)\\ b.n_{P_2O_5}=\dfrac{1}{2}n_P=0,1\left(mol\right)\\ \Rightarrow m_{P_2O_5}=0,1.142=14,2\left(g\right)\)
\(n_P=\dfrac{12,4}{31}=0,4\left(mol\right)\\
pthh:4P+5O_2\underrightarrow{t^o}2P_2O_5\)
0,4 0,2
\(m_{P_2O_5}=142.0,2=28,4g\)
\(n_{O_2}=\dfrac{17}{32}=0,53\left(mol\right)\)
\(pthh:4P+5O_2\underrightarrow{t^o}2P_2O_5\\
LTL:\dfrac{0,4}{4}< \dfrac{0,53}{5}\)
=> O2 dư
\(n_{O_2\left(p\text{ư}\right)}=\dfrac{5}{4}n_P=0,5\left(mol\right)\\
m_{O_2\left(d\right)}=\left(0,53-0,5\right).32=0,96g\)
`4P + 5O_2` $\xrightarrow[]{t^o}$ `2P_2 O_5`
`0,4` `0,5` `0,2` `(mol)`
`n_P = [ 12,4 ] / 31 = 0,4 (mol)`
`a) m_[P_2 O_5] = 0,2 . 142 = 28,4 (g)`
`b) n_[O_2] = 17 / 32 = 0,53125 (mol)`
Ta có: `[ 0,4 ] / 4 < [ 0,53125 ] / 5`
`->O_2` dư
`=> m_[O_2 (dư)] = ( 0,53125 - 0,5 ) . 32 = 1(g)`
a) \(n_{Al}=\dfrac{12,15}{27}=0,45\left(mol\right)\)
\(n_{O_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
PTHH: 4Al + 3O2 --to--> 2Al2O3
Xét tỉ lệ: \(\dfrac{0,45}{4}>\dfrac{0,3}{3}\)=> Al dư, O2 hết
PTHH: 4Al + 3O2 --to--> 2Al2O3
0,4<--0,3-------->0,2
=> \(m_{Al\left(dư\right)}=\left(0,45-0,4\right).27=1,35\left(g\right)\)
b) \(m_{Al_2O_3}=0,2.102=20,4\left(g\right)\)
Câu 1
\(n_{Fe}=\dfrac{16,8}{56}=0,3mol\\ n_{O_2}=\dfrac{2,479}{24,79}=0,1mol\\ 3Fe+2O_2\xrightarrow[t^0]{}Fe_3O_4\\ \Rightarrow\dfrac{0,3}{3}>\dfrac{0,1}{2}\Rightarrow Fe.dư\\ 3Fe+2O_2\xrightarrow[t^0]{}Fe_3O_4\)
0,15 0,1 0,05
\(m_{Fe.dư}=16,8-0,15.56=8,4g\\ b.m_{Fe_3O_4}=0,05.232=11,6g\)
\(n_{O_2}=\dfrac{4,958}{24,79}=0,2\left(mol\right);n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\\ 2Zn+O_2\rightarrow\left(t^o\right)2ZnO\\ Vì:\dfrac{0,1}{2}< \dfrac{0,2}{1}\Rightarrow O_2dư\\ n_{O_2\left(dư\right)}=0,2-\dfrac{1}{2}.0,1=0,15\left(mol\right)\Rightarrow m_{O_2\left(dư\right)}=0,15.32=4,8\left(g\right)\\ b,n_{ZnO}=n_{Zn}=0,1\left(mol\right)\Rightarrow m_{ZnO}=81.0,1=8,1\left(g\right)\)
`#\text{lhg}`
`a)`
Ta có:
\(\text{n}_{\text{Zn}}=\dfrac{6,5}{65}=0,1\left(\text{mol}\right)\)
\(\text{n}_{\text{O}_2}=\dfrac{4,958}{24,79}=0,2\left(\text{mol}\right)\)
PTHH: \(\text{2Zn}+\text{O}_2\rightarrow\text{ 2ZnO}\)
Lập tỉ số: \(\dfrac{0,1}{2}:\dfrac{0,2}{1}=0,05< 0,2\)
Vậy, sau phản ứng Zn hết, O2 dư
\(\text{n}_{\text{O}_2\text{ dư}}=0,2-\dfrac{0,1}{2}=0,15\left(\text{mol}\right)\)
\(\text{m}_{\text{O}_2\text{ dư}}=0,15\cdot32=4,8\left(\text{g}\right).\)
`b)`
Theo PT: \(\text{n}_{\text{ZnO}}=\text{n}_{\text{Zn}}\Rightarrow\text{n}_{\text{ZnO}}=0,1\left(\text{mol}\right)\)
Khối lượng oxide tạo thành:
\(\text{m}_{\text{ZnO}}=n_{\text{ZnO}}\cdot\text{M}_{\text{ZnO}}=0,1\cdot\left(65+16\right)=8,1\left(\text{g}\right).\)